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现代化工  2021, Vol. 41 Issue (S1): 95-99    DOI: 10.16606/j.cnki.issn0253-4320.2021.S.019
  技术进展 本期目录 | 过刊浏览 | 高级检索 |
丁二烯选择性加氢催化剂研究进展
马好文1,2, 杨春亮3, 马萍1, 陈明林1, 冯辉霞2, 展学成1, 谢元1
1. 中国石油石油化工研究院兰州化工研究中心, 甘肃 兰州 730060;
2. 兰州理工大学石油化工学院, 甘肃 兰州 730050;
3. 宁波金发新材料有限公司, 浙江 宁波 315000
Research progress in catalysts for selective hydrogenation of butadiene
MA Hao-wen1,2, YANG Chun-liang3, MA Ping1, CHEN Ming-lin1, FENG Hui-xia2, ZHAN Xue-cheng1, XIE Yuan1
1. Lanzhou Petrochemical Research Center, PetroChina Petrochemical Research Institute, Lanzhou 730060, China;
2. College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050, China;
3. Ningbo Kingfa New Material Co., Ltd., Ningbo 315000, China
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摘要 随着炼化一体化以及煤化工的快速发展,碳四(C4)副产资源大幅增长,而丁二烯选择性加氢技术是实现C4馏分高值利用的关键;然而,在丁二烯选择性加氢反应生成1-丁烯的过程中,还会伴随2-丁烯、丁烷等副产物生成。因此,开发高活性、高选择性的催化剂是本领域最重要的研究内容。介绍了近年来丁二烯选择性加氢催化剂的设计、制备以及应用情况,总结了一些改进催化剂性能的策略,并对过渡金属基丁二烯选择性加氢催化剂的前景进行了展望。
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马好文
杨春亮
马萍
陈明林
冯辉霞
展学成
谢元
关键词:  碳四馏分  丁二烯  选择加氢  Pd基催化剂  Ni基催化剂    
Abstract: With the integration of refining and chemical industries and the rapid development of coal chemical industry, the amount of C4 by-product resources has grown substantially.Selective butadiene hydrogenation technology is the key to realize the appreciation and utilization of C4 fractions.However, the selective hydrogenation of butadiene to produce 1-butene will also accompany with the formation of by-products such as 2-butene and butane.Therefore, the development of catalysts with high activity and selectivity is the most important research content in this field.The design, preparation and application of the catalysts for selective butadiene hydrogenation in recent years are introduced.Several strategies for optimizing catalyst performance are summarized, and the application prospects of transition metal-based catalysts for selective butadiene hydrogenation are discussed.
Key words:  C4 fractions    butadiene    selective hydrogenation    Pd-based catalysts    Ni-based catalysts
收稿日期:  2021-03-03      修回日期:  2021-06-07           出版日期:  2021-10-30
ZTFLH:  TQ426.9  
通讯作者:  冯辉霞(1966-),女,博士,教授,博士生导师,研究方向为化学功能材料,通讯联系人,fenghx@lut.cn。    E-mail:  fenghx@lut.cn
作者简介:  马好文(1984-),男,博士生,高级工程师,研究方向为化工加氢催化剂,mahaowen@petrochina.com.cn
引用本文:    
马好文, 杨春亮, 马萍, 陈明林, 冯辉霞, 展学成, 谢元. 丁二烯选择性加氢催化剂研究进展[J]. 现代化工, 2021, 41(S1): 95-99.
MA Hao-wen, YANG Chun-liang, MA Ping, CHEN Ming-lin, FENG Hui-xia, ZHAN Xue-cheng, XIE Yuan. Research progress in catalysts for selective hydrogenation of butadiene. Modern Chemical Industry, 2021, 41(S1): 95-99.
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https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2021.S.019  或          https://www.xdhg.com.cn/CN/Y2021/V41/IS1/95
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