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摘要
采用共沉淀法制备SiC改性5% Co-2.5% Ce/Al2O3催化剂,研究了不同SiC负载量改性催化剂的吸波升温性能和催化氧化甲苯性能。结果表明,随着SiC负载量的增加,催化剂吸波升温性能逐渐增强。SiC最佳负载量为5%时,催化剂催化氧化甲苯性能最佳,催化剂具有较大的比表面积和适宜的微孔结构。甲苯催化氧化活性评价结果表明,5% Co-2.5% Ce/5% SiC-Al2O3催化剂对不同甲苯浓度具有较强适应性,对中低浓度的甲苯降解效果显著。空速低于15 000 h-1时催化剂能发挥高效催化作用,微波功率在120~385 W有利于甲苯的催化氧化。
Abstract
SiC modified 5% Co-25% Ce/Al2O3 catalyst is prepared via co-precipitation method,and the performances of the catalyst with different SiC loading amount in microwave-absorbing temperature-rising and catalytic oxidation of toluene are studied.The results show that with higher SiC loading amount,the catalyst has a higher wave-absorbing temperature-rising performance.The catalyst with 5% of SiC has a large specific surface area and suitable microporous structure,and presents the best performance in catalyzing oxidation of toluene.The evaluation results show that 5% Co-2.5% Ce/5% SiC-Al2O3 catalyst has a strong adaptability to different concentrations of toluene,and has a significant degradation effect on medium and low concentrations of toluene.The catalyst can play an efficient catalytic role when the air velocity is less than 15 000 h-1.Microwave power at 120 W to 385 W is conducive to the catalytic oxidation of toluene.
关键词
微波诱导
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甲苯
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催化氧化
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SiC改性催化剂
Key words
microwave induction
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toluene
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catalytic oxidation
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SiC modified catalyst
Author summay
李潇祎(1997-),女,硕士研究生,研究方向为大气污染控制工程,18768911395@163.com
微波诱导SiC改性Co-Ce/Al2O3催化剂催化氧化甲苯性能的研究[J].
现代化工, 2022, 42(1): 116-120 DOI:10.16606/j.cnki.issn0253-4320.2022.01.024