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摘要
以焦炉煤气为原料气,在实验室中对络合铁催化剂进行适应性研究,分析了络合铁催化及脱除H2S机理。并在焦化企业脱硫装置进行了工业试用,考察了pH、氧化还原电位、再生空气量对脱硫过程的影响,结果表明,在使用了络合铁催化剂后,焦炉煤气中硫化氢含量从2.0~4.0 g/m3降到20 mg/m3以下,脱硫装置运行稳定,无脱硫废液排出。
Abstract
Using coke oven gas as feedstock gas,the adaptability of complex iron catalysts is studied in laboratory.Catalytic mechanism of complex iron catalyst and H2S removal mechanism over it are analyzed.Its industrial trial is conducted in a desulfurization unit of a coking enterprise.The influences of PH,redox potential,and air volume for regeneration on the desulfurization process are investigated.It is shown that the content of H2S in coke oven gas drops from 2.0-4.0 g·m-3 to below 20 mg·m-3 after the use of complex iron catalyst,the desulfurization unit runs stably and there is no discharge of desulfurization waste liquid.
关键词
焦炉煤气
/
脱硫溶液
/
脱硫
/
络合铁
Key words
coke oven gas
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desulfurization solution
/
desulfurization
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chelated iron
新型络合铁催化剂在焦炉煤气净化中的研究[J].
现代化工, 2021, 41(7): 225-227 DOI:10.16606/j.cnki.issn0253-4320.2021.07.045