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摘要
通过静电纺丝制备出碳纤维,然后高温退火处理获得氮掺杂多孔碳纤维,并将其作为硫的宿主材料,最终得到N-CNFs/S正极材料。利用XRD、TG、TEM等对N-CNFs/S复合电极材料的结构和形貌进行表征。N-CNFs/S作为正极材料组装的锂硫电池的电化学性能测试结果表明,在167 mA/g和836 mA/g的电流密度下,N-CNFs/S复合电极材料循环250圈和500圈后容量分别高达836 mA·h/g和631 mA·h/g;同时,N-CNFs/S复合电极材料还表现出良好的倍率性能。
Abstract
Carbon fibers are prepared through electrospinning,and then treated by high-temperature annealing to obtain nitrogen-doped porous carbon fibers,which are used as sulfur host materials,and finally N-CNFs/S cathode materials are obtained.The target product is characterized,and the structure and morphology of N-CNFs/S composite electrode material are studied.Lithium sulfur battery assembled with N-CNFs/S as cathode material exhibits good electrochemical performance.At current densities of 167 mA·g-1 and 836 mA·g-1,the capacity of N-CNFs/S composite electrode material can be as high as 836 mAh·g-1 and 631 mAh·g-1 after 250 cycles and 500 cycles,respectively.Meanwhile,N-CNFs/S composite electrode material also shows good rate performance.
关键词
静电纺丝
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锂硫电池
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正极
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氮掺杂
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多孔碳纤维
Key words
electrospinning
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lithium-sulfur battery
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cathode
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nitrogen doping
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porous carbon fiber
Author summay
杨玉艳(1983-),女,工程硕士,讲师,主要从事新能源及应用研究,thry2020@163.com
锂硫电池正极用氮掺杂的多孔碳纤维载体材料的研究[J].
现代化工, 2021, 41(6): 167-171 DOI:10.16606/j.cnki.issn0253-4320.2021.06.034