Fe3O4纳米粉体掺杂PTCDI复合材料的制备与光催化研究

金英伟, 彭蕾, 李平灯, 杨玉莹, 程波, 郑琦, 户业丽, 丁强

现代化工 ›› 2021, Vol. 41 ›› Issue (6) : 106 -109.

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现代化工 ›› 2021, Vol. 41 ›› Issue (6) : 106-109. DOI: 10.16606/j.cnki.issn0253-4320.2021.06.022
科研与开发

Fe3O4纳米粉体掺杂PTCDI复合材料的制备与光催化研究

    金英伟, 彭蕾, 李平灯, 杨玉莹, 程波, 郑琦, 户业丽, 丁强
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Preparation of Fe3O4-PTCDI heterojunction material and its photocatalytic performance

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摘要

制备了一种具有磁响应的有机纳米半导体复合光催化材料,并将其用于吸附及光催化降解有机物。利用SEM、TEM、FT-IR及DRS对产物的形貌结构及光吸收性能进行了表征。可见光条件下吸附降解有机染料实验结果表明,Fe3O4-PTCDI纳米复合材料具有较好的吸附及光催化活性;经过4 h的紫外光或6 h的吸附及可见光光催化降解,亚甲基蓝的去除效率分别为76.4%及72.2%。6次光催化重复利用实验结果表明,其有机染料的去除效率未出现明显下降。

Abstract

An organic nano semiconductor composite photocatalytic material with magnetic response is prepared and applied in photocatalytic adsorption and degradation of organic dye (methylene blue).The morphology,structure and optical absorption properties of the as-prepared product are characterized by scanning electron microscopy (SEM),transmission electron microscopy (TEM),infrared spectroscopy (FT-IR) and ultraviolet-visible spectroscopy.It is found through the adsorption and photocatalytic degradation experiments of organic dye under visible light that Fe3O4-PTCDI nanocomposites exhibit good adsorption and photocatalytic activity.The removal efficiencies of methylene blue over Fe3O4-PTCDI nanocomposites reach 76.4% and 72.2%,respectively after adsorption and photocatalytic degradation under ultraviolet and visible light,respectively.After six runs of cycling experiments,the removal efficiency decreases slightly.In addition,as a photocatalyst,Fe3O4-PTCDI nanocomposites exhibit relatively high magnetic responsiveness.

关键词

四氧化三铁(Fe3O4) / 光催化吸附有机半导体 / 苝四甲酰二亚胺(PTCDI)

Key words

Fe3O4(Fe3O4) / photocatalytic adsorption of organic semiconductors / perylene tetraformyl diimide (PTCDI)

Author summay

金英伟(1995-),男,硕士研究生,研究方向为环境毒理、化学吸附及多孔材料吸附与表征

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Fe3O4纳米粉体掺杂PTCDI复合材料的制备与光催化研究[J]. 现代化工, 2021, 41(6): 106-109 DOI:10.16606/j.cnki.issn0253-4320.2021.06.022

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