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摘要
利用两步法成功制备了核壳结构的四氧化三铁/聚合(3,4-二氧乙基噻吩)(Fe3O4/PEDOT)复合材料,并考察了稳定剂PVP、温度和反应时间对其形貌的影响。利用XRD、EDX和红外光谱等方法对其进行表征,同时还研究了该复合材料的电、磁以及吸波性能等。结果表明,当复合材料涂层厚度为4 mm时,最大反射损耗为-12 dB,复合材料的矫顽力为94.2 Oe,饱和磁化强度为64.6 emu/g,剩磁为7.3 emu/g。
Abstract
Ferric oxide/poly(3,4-ethylendioxythiophene (Fe3O4/PEDOT) composites with a core-shell structure are successfully synthesized through two-step method.The influences of reaction conditions (stabilizing agent,reaction temperature and time) on the morphologies of the composites are studied,and the composites' morphology and structure are characterized by XRD,EDX and FT-IR,and their electrical,magnetic and microwave-absorbing properties are also explored.It is shown when the coating thickness of the composites is 4 mm,the maximum reflection loss is -12 dB,and the composites' coercivity,saturation magnetization and remanence are 94.2 Oe,64.6 emu·g-1 and 7.3 emu·g-1,respectively.
关键词
Fe3O4/PEDOT
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磁性能
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吸波性能
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导电性能
Key words
Fe3O4/PEDOT
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magnetic properties
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microwave absorbing properties
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electrical conductivity
Author summay
倪训伟(1981-),男,硕士,工程师,研究方向为导电聚合物及其磁性材料复合物的制备与检测,通迅联系人,tcyznxw@163.com。
Fe3O4/PEDOT复合材料的制备和多种性能研究[J].
现代化工, 2021, 41(5): 197-202 DOI:10.16606/j.cnki.issn0253-4320.2021.05.040