含磺酸基氟碳共聚物油田酸化缓速剂的合成与性能评价

王立静, 马清杰, 王磊, 冯新根

现代化工 ›› 2021, Vol. 41 ›› Issue (5) : 132 -136,142.

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现代化工 ›› 2021, Vol. 41 ›› Issue (5) : 132-136,142. DOI: 10.16606/j.cnki.issn0253-4320.2021.05.027
科研与开发

含磺酸基氟碳共聚物油田酸化缓速剂的合成与性能评价

    王立静, 马清杰, 王磊, 冯新根
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Synthesis and performance evaluation of a sulfonic group-containing fluorocarbon copolymer as acid retarded agent in oilfield

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摘要

为了优化酸液体系缓速性能、增加酸化渗透距离、提高油田生产效率,以丙烯酰胺(AM)、2-丙烯酰胺-2-甲基丙磺酸(AMPS)、甲基丙烯酰胺丙基二甲基全氟丁基乙基碘化铵(FBA)为单体,通过单因素分析法确定了新型含氟共聚物缓速剂的最佳合成条件为:n(AM):n(AMPS):n(FBA)为56.3:7.2:1.4、引发剂质量分数为0.35%、反应温度为50℃、pH为6.0、单体质量分数为20%、反应时间为6 h。通过酸岩反应测试,在90℃条件下,与空白盐酸相比,平均酸岩反应速率从3.97×10-3 g/(cm2·s)降低到5.81×10-4 g/(cm2·s),且与耐酸减阻剂配伍性良好;在140℃条件下,动态平均酸岩反应速率为2.46×10-4 g/(cm2·s)。

Abstract

In order to optimize the retarding performance of acidizing fluid system,increase the acidification penetration distance and improve oilfield production efficiency,a novel sulfonic group-containing fluorocarbon copolymer,which is used for acid retarding agent in oilfields,is prepared by using acrylamide (AM),2-(acrylamide)-propyl sulfonic acid (AMPS),methyl acrylamide propyl dimethyl perfluorobutyl ethyl ammonium iodide (FBA) as monomers.Through single factor analysis method,the optimum synthesis conditions are obtained as follows:n(AM):n(AMPS):n(FBA) is 56.3:7.2:1.4,the mass fraction of initiator is 0.35%,reaction temperature maintains at 50℃,pH=6.0,the mass fraction of monomers is 20% and reaction lasts for 6 h.Acid rock reaction is tested.Compared with blank hydrochloric acid at 90℃,the average acid rock reaction speed can be effectively reduced from 3.97×10-3 g/(cm2·s) to 5.81×10-4 g/(cm2·s) by the retardant.The synthetic retardant has good compatibility with acid resistant drag reduction agent,and it still has good retarding performance at 140℃,with an average acid rock reaction speed of 2.46×10-4 g/(cm2·s).

关键词

氟碳 / 缓速剂 / 酸岩反应 / 共聚物

Key words

fluorocarbon / retarding agent / acid rock reaction / copolymer

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含磺酸基氟碳共聚物油田酸化缓速剂的合成与性能评价[J]. 现代化工, 2021, 41(5): 132-136,142 DOI:10.16606/j.cnki.issn0253-4320.2021.05.027

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