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摘要
以全氟聚醚(PFPE)、烷氧基改性含氟聚硅氧烷(FVT)为原料,通过脱醇反应合成了环保型氟醚树脂fv-PFPE,将fv-PFPE和KH560-SiO2混合得到环保型防指纹剂,并采用喷涂技术制备防指纹涂层。利用FT-IR、1HNMR、XPS对氟醚树脂结构及涂层表面组成进行表征,考察了催化剂质量分数对固化时间的影响。结果表明,当fv-PFPE质量分数为0.8%时,涂层的接触角达到最大值(132±2)°。
Abstract
fv-PFPE,an environmental friendly fluoroether resin,is synthesized from perfluoropolyether (PFPE) and alkoxy modified fluorine-containing polysiloxane (FVT) through dealcoholization reaction.Environmental friendly anti-fingerprint agent is obtained by mixing fv-PFPE with KH560-SiO2,and anti-fingerprint coating is prepared by spraying technology.FT-IR,1HNMR and XPS are employed to characterize the structure of fluoroether resin and the composition of coating surface,and the influence of the mass fraction of catalyst on curing time of coating is investigated.Results show that the contact angle of the coating reaches 132±2°,being the maximum value when the content of fv-PFPE is 0.8%.
关键词
氟硅树脂
/
疏水
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防指纹
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全氟聚醚
Key words
fluorosilicone resin
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hydrophobic
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anti-fingerprint
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perfluoropolyether
Author summay
焦岚姣(1997-),女,硕士研究生,研究方向为氟硅树脂,405637146@qq.com
新型环保氟醚防指纹涂层的构建及性能研究[J].
现代化工, 2021, 41(2): 130-134 DOI:10.16606/j.cnki.issn0253-4320.2021.02.025