乙二醇脱盐的离子交换树脂电再生实验研究

贺三, 张小卓, 梁羽, 袁宗明

现代化工 ›› 2020, Vol. 40 ›› Issue (11) : 178 -181.

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现代化工 ›› 2020, Vol. 40 ›› Issue (11) : 178-181. DOI: 10.16606/j.cnki.issn0253-4320.2020.11.037
科研与开发

乙二醇脱盐的离子交换树脂电再生实验研究

    贺三, 张小卓, 梁羽, 袁宗明
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Experimental study on electrical regeneration of ion exchange resin for desalination of monoethylene glycol

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摘要

为简化深水气田乙二醇回收系统,使离子交换技术代替现有乙二醇脱盐工艺,提出了一种离子交换树脂电再生方法。通过布置在树脂床两侧的电极提供电场,在水流中发生电极反应与水解离,产生的H+和OH-使饱和树脂再生。与现有的电再生方法相比,该方法再生条件较简单,对于空间、淡水十分有限的海上平台更具适用性。实验结果表明,在74 V内对混床电再生1 h后,可脱除5.46 BV模拟乙二醇富液中31.26%的NaCl,离子交换树脂得到有效再生。重复脱盐-再生实验15个周期后,树脂性能仍保持良好。

Abstract

In order to simplify the monoethylene glycol reclamation/regeneration system in deep water gas field and make it more feasible for ion exchange to replace the existing monoethylene glycol desalination process,an electrical regeneration method for ion exchange resin is proposed.Electric field is provided by the electrodes installed on both sides of the resin bed.Electrode reaction and water dissociation occur in the water flow,and the H+ and OH- generated make the exhausted resin regenerate.Compared with the existing electrical regeneration method,this method needs simpler regeneration conditions and is more applicable to offshore platforms with limited space and fresh water resource.Experimental results show that 31.26% of NaCl in 5.46 BV simulated monoethylene glycol rich solution can be removed after the mixed bed has been electrically regenerated within 74 V for 1 hour,and the spent ion exchange resin can be effectively regenerated.The resin remains good performance after 15 cycles of repeated desalination-regeneration experiments.

关键词

离子交换 / 深水天然气开发 / 脱盐 / 乙二醇 / 电再生

Key words

ion exchange / deep water natural gas development / desalination / monoethylene glycol / electrical regeneration

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乙二醇脱盐的离子交换树脂电再生实验研究[J]. 现代化工, 2020, 40(11): 178-181 DOI:10.16606/j.cnki.issn0253-4320.2020.11.037

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