碳二前加氢催化剂PEC-21长周期运行性能分析

梁玉龙, 刘轶凡, 张展, 车春霞, 温翯, 张峰, 苟尕莲, 韩伟

现代化工 ›› 2020, Vol. 40 ›› Issue (10) : 216 -220.

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现代化工 ›› 2020, Vol. 40 ›› Issue (10) : 216-220. DOI: 10.16606/j.cnki.issn0253-4320.2020.10.045
工业技术

碳二前加氢催化剂PEC-21长周期运行性能分析

    梁玉龙, 刘轶凡, 张展, 车春霞, 温翯, 张峰, 苟尕莲, 韩伟
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Analysis on long-term operation performance of PEC-21 catalyst for front-end hydrogenation of acetylene

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摘要

考察了中石油自主开发的碳二前加氢催化剂PEC-21在大庆石化270 kt装置一段反应器35个月的运行情况,并与同周期进口催化剂运行性能进行了对比。工业应用结果表明,PEC-21催化剂35个月平均乙炔转化率56.7%,乙烯选择性94.4%,提温幅度仅19℃,比同周期进口剂低7.5℃。在CO含量200~1 200 μL/L,进料量63.6~78.5 t/h的波动工况下显示出良好的长周期运行稳定性。

Abstract

The catalyst for front-end hydrogenation of acetylene independently developed by PetroChina Company Limited has been operated continuously for 35 months in the 270 kt/a plant of PetroChina Daqing Petrochemical Company,which is compared with the performance of imported catalysts in the same cycle.Industrial application results show that PEC-21 catalyst has given an average acetylene conversion rate of 56.7% in 35 months,an ethylene selectivity of 94.4%,and a temperature increase of only 19℃,which is 7.5℃ lower than that of the imported catalyst in the same cycle.Under the fluctuating operating conditions with a CO content of 200-1 200 μL·L-1 and a feeding speed of 63.6-78.5 t·h-1,it shows good long-term running stability.

关键词

碳二前加氢 / 乙炔选择加氢 / 工业试验 / 加氢催化剂

Key words

front-end hydrogenation of C2 / selective hydrogenation of acetylene / industrial test / hydrogenation catalyst

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碳二前加氢催化剂PEC-21长周期运行性能分析[J]. 现代化工, 2020, 40(10): 216-220 DOI:10.16606/j.cnki.issn0253-4320.2020.10.045

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