烟气低浓度氮氧化物前置臭氧氧化工艺研究

李晓静, 陆继东, 张忠培, 董美蓉, 黄健伟, 张杰

现代化工 ›› 2019, Vol. 39 ›› Issue (1) : 217 -221.

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现代化工 ›› 2019, Vol. 39 ›› Issue (1) : 217-221. DOI: 10.16606/j.cnki.issn0253-4320.2019.01.047
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烟气低浓度氮氧化物前置臭氧氧化工艺研究

    李晓静, 陆继东, 张忠培, 董美蓉, 黄健伟, 张杰
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Study on pre-oxidation process for low concentration nitrogen oxide in flue gas

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摘要

采用数值模拟方法,结合标准k-ε模型、组分输运模型和层流有限速率模型,以某特定结构的臭氧投加设备为研究对象,对影响臭氧氧化工艺过程的相关因素进行深入分析。研究结果表明,NO的氧化效率随着烟气中O3/NO摩尔比的增加而升高,但增加速率逐渐降低;当O3/NO摩尔比为1、烟气温度为100~250℃时,NO的氧化效率随着温度的升高而降低;烟气中SO2浓度对NO的氧化效率没有明显的影响。

Abstract

Taking the ozone injector with a specific structure as study object,the factors that affect the ozone oxidation process are analyzed deeply by means of numerical simulation method combining with standard k-ε model,species transport model and laminar finite-rate model.Analysis result shows that the oxidation efficiency of NO raises with the increasing molar ratio of O3/NO in flue gas,but the growth rate decreases gradually.The oxidation efficiency of NO will decrease with the increasing temperature when the temperature of flue gas locates in the range of 100-250℃ and the molar ratio of O3/NO is set as 1.Meanwhile,the existence of SO2 in flue gas has no obvious impact on oxidation efficiency of NO.

关键词

臭氧氧化 / 数值模拟 / 臭氧投加设备 / 氧化效率 / 氮氧化物

Key words

oxidation by ozone / numerical simulation / ozone injector / oxidation efficiency / nitrogen oxides

Author summay

李晓静(1994-),女,硕士生。

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烟气低浓度氮氧化物前置臭氧氧化工艺研究[J]. 现代化工, 2019, 39(1): 217-221 DOI:10.16606/j.cnki.issn0253-4320.2019.01.047

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