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摘要
在USC裂解炉上进行了不同乙烯原料、裂解炉出口温度、炉管构型的工业裂解标定试验,结果表明,循环乙烷易脱氢生成大量的乙烯(56.35%),丙烯、丁二烯、裂解液相产物收率极低,液化气通过断链反应可生成乙烯、丙烯、丁二烯以及少量的裂解液相产物,石脑油&拔头油裂解乙烯收率低,但裂解液相产物(高附加值)收率较高;乙烷裂解炉出口温度宜控制在858℃左右;与U型炉管相比,乙烷在M型炉管裂解乙烷转化率、乙烯收率、丙烯收率、三烯收率高。
Abstract
A series of industrial pyrolysis calibration tests with different raw materials for ethylene, outlet temperatures and furnace tube configurations are carried out in a USC cracker.It is found that circulated ethane is easily dehydrogenated to produce a large amount of ethylene (56.35%), while the yields of propylene, butadiene and pyrolysis liquid phase are very low.Liquefied petroleum gas can generate ethylene, propylene, butadiene and a small amount of pyrolysis liquid phase products through the chain scission reaction.The pyrolysis of naphtha mixed with Topped oil can give a low yield of ethylene through but a high yield of high-valuable liquid phase.The outlet temperature at ethane cracker is suggested to be controlled at around 858℃.Comparing with pyrolysis in a U-shape furnace tube, ethane pyrolysis in a M-shape furnace tube can obtain higher ethane conversion rate, ethylene yield, propylene yield and the total yield of ethylene, propylene and butadiene.
关键词
裂解炉
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裂解性能
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循环乙烷
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炉管构型
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出口温度
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工业裂解标定
Key words
cracker
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cracking property
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circulating ethane
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furnace tube configuration
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outlet temperature
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industrial pyrolysis calibration
USC裂解炉出口温度、炉管构型对循环乙烷裂解性能的影响[J].
现代化工, 2018, 38(10): 209-212 DOI:10.16606/j.cnki.issn0253-4320.2018.10.047