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摘要
以六水合硝酸锌[Zn(NO3)2·(H2O)6]、六水合硝酸钕[Nd(NO3)3·6H2O]和五水合硝酸铒[Er(NO3)3·5H2O]为掺杂改性材料,采用溶胶-凝胶法制备锐钛矿型Nd-Er/ZnO-TiO2复合光催化材料。利用XRD、BET、SEM、UV-Vis对所制光催化材料进行表征。以2,4-DCP为目标降解物,在高压汞灯与长弧氙灯照射下,验证所制复合光催化材料的光催化活性。光催化剂1% Nd-1% Er/5% ZnO-TiO2光催化效能最高。在紫外光下照射2 h,对2,4-DCP降解率为94.26%;在可见光下照射 6 h,对2,4-DCP降解率为64.7%。
Abstract
Nd-Er/ZnO-,TiO2,an anatase-type composite photocatalytic material is synthesized by sol-gel method through using Zn(NO3)2·(H2O)6,Nd(NO3)3·6H2O and Er(NO3)3·5H2O as doping modification materials and is characterized by means of X-ray diffraction (XRD),surface area analyzer (BET),scanning electron microscope (SEM) and UV diffuse reflectance analyzer (UV-Vis).With 2,4-dichlorophenol (2,4-DCP) as target degradation material,the photocatalytic activity of the synthesized composite photocatalytic materials is verified under irradiation of high voltage mercury lamp and long arc xenon lamp.It is found that 1%Nd-1%Er/5%ZnO-TiO2 exhibits the highest photocatalytic efficiency and can make the degradation rate of 2,4-DCP reach 94.26% under ultraviolet light irradiation for 2 h and 64.7% under visible light irradiation for 6 h.
关键词
光催化
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稀土共掺杂
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复合半导体
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2,4-DCP
Key words
photocatalysis
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rare earth co-doped
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compound semiconductor
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2,4-dichlorophenol
Author summay
陈昕海(1990-),男,硕士研究生,研究方向为污染控制理论与技术,839508227@qq.com。
Nd-Er/ZnO-TiO2光催化剂对2,4-DCP的光催化降解研究[J].
现代化工, 2018, 38(8): 152-156 DOI:10.16606/j.cnki.issn0253-4320.2018.08.033