从铑膦络合物前体、配体和反应条件等方面考察了均相铑催化剂用于1-辛烯氢甲酰化反应的性质和规律，其中铑膦络合物前体包括三（三苯基膦）羰基氢化铑[RhH （CO）（PPh₃）₃]、三（三苯基膦）氯铑[RhCl （PPh₃）₃]和羰基乙酰丙酮（三苯基膦）铑[Rh （CO）（PPh₃）（acac）]，配体包括三苯基膦（TPP）和三苯基氧膦（TPPO）。实验结果表明，在2 MPa、90℃的实验条件下，RhH （CO）（PPh₃）₃与PPh₃组合时的反应活性及选择性明显高于其他组合，且在反应压力为2 MPa时RhH （CO）（PPh₃）₃/TPP体系的最佳反应温度为90℃。当反应压力在1~4 MPa时，随着压力的增加，反应活性增加。当Rh浓度固定时，随着TPP用量的增加烯烃转化率略有增加，而正壬醛的选择性明显增加。通过³¹P核磁共振技术对反应前后催化剂进行表征，结果表明，温度越高，催化剂体系中的膦配体越易被氧化，影响催化活性。

The hydroformylation of 1-octene over homogeneous Rh-catalyst is investigated in terms of rhodium phosphine complex precursors,ligand effect and reaction conditions,wherein the precursors include carbonyl tris(triphenylphosphine) rhodium(I) hydride (RhH(CO)(PPh₃)₃),chloro tris(triphenylphosphine) rhodium(I) (RhCl(PPh₃)₃) and rhodium (triphenylphosphine) carbonyl acetylacetonate (Rh(CO)(PPh₃)(acac)),and the ligands include triphenylphosphine (TPP) and triphenylphosphine oxide (TPPO).The results show that the reaction activity and selectivity of RhH(CO)(PPh₃)₃/TPP are better than others at 2 MPa,90℃,and the optimum reaction temperature of RhH(CO)(PPh₃)₃/TPP is 90℃ at 2 MPa.When the reaction pressure is within 1-4 MPa,the increase of pressure will increase its reaction activity.The change of catalyst before and after reaction is characterized by means of ³¹P(¹H)NMR spectroscopy.The characterization results suggest that the higher the temperature,the easier to be oxidized the phosphine ligands.