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摘要
研究了膨润土负载Fe0作为催化剂的非均相芬顿体系对含菊酯类农药废水的处理效果。通过单因素实验探究了pH、双氧水的投加量、催化剂的投加量、反应时间、反应温度5个因素对处理效果的影响;并通过设计正交实验探究最佳反应条件。结果表明最佳处理条件为:pH=3、双氧水投加量为0.3 mL、催化剂投加量为0.5 g、反应温度为30℃、反应时间为60 min,对高效氯氟氰菊酯模拟废水中CODCr的去除率达到64.28%。在此最优条件下对催化剂进行回收实验,结果表明,催化剂的可回收利用性良好,重复使用2次后的去除效果仍保持在59%左右。
Abstract
A heterogeneous Fenton system using bentonite-supported Fe0 as catalyst is synthesized for the treatment of the simulated wastewater containing lambda-cyhalothrin.The influences of pH value,dosage of hydrogen peroxide,catalyst dosage,reaction time and reaction temperature on the treatment efficiency are studied by means of single factor experiments.The optimum conditions determined by designed orthogonal experiments are as follows:pH value is 3,the dosage of hydrogen peroxide is 0.3 mL,catalyst dosage is 0.5 g,reaction temperature is 30℃ and reaction time is 60 min.The removal rate of CODCr from simulated wastewater containing lambda-cyhalothrin can achieve 64.28% under optimum conditions.Recovery experiments of catalysts performed under these optimum conditions illustrate that the prepared catalyst has a good recyclability,the CODCr removal rate over it can still remain around 59% after be 2 times of repeated uses.
关键词
膨润土
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高效氯氟氰菊酯
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非均相芬顿法
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纳米零价铁
Key words
bentonite
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lambda-cyhalothrin
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heterogeneous Fenton method
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nanoscale zero valent iron
Author summay
陈维雨思(1992-),女,硕士生,研究方向为水处理,471033028@qq.com
膨润土负载Fe0处理高效氟氯氰菊酯模拟废水[J].
现代化工, 2018, 38(3): 161-164,166 DOI:10.16606/j.cnki.issn0253-4320.2018.03.035