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摘要
选用丙烯酰胺(AM)、甲基丙烯酰氧乙基三甲基氯化铵(DMC)、烯丙基聚乙二醇(APEG)以及十六烷基二甲基烯丙基氯化铵(DMAAC-16)4种单体,通过单因素法对合成条件进行优化,得到一种共聚物缓速剂。实验结果表明,该缓速剂具有良好的降低酸岩反应速率的效果;在90℃、含有5 000 mg/L NaCl的条件下仍然具有良好的缓速效果;CaCl2对于该缓速剂具有一定的促进作用。
Abstract
Aiming at solving the problems of retarded acid in the current acidification,a copolymer based acid retarder is synthesized by using acrylamide (AM),[2-(methacryloyloxy) ethyl]-trimethylammonium chloride (DMC),allyl polyethylene glycol (APEG) and hexadecyl trimethyl allylammonium chloride (DMAAC-16) as monomers through optimization of synthesis conditions by single-factor experiment method.The result shows that this acid retarder has outstanding effect on reducing the reaction rate between acid and rock,has still a good retarding effect at 90℃ with the condition containing 5 000 mg·L-1 NaCl.The presence of CaCl2 has a positive effect on this retarder.
关键词
共聚物
/
吸附
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缓速剂
/
酸化
Key words
copolymer
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adsorption
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retarder
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acidizing
阳离子聚合物型酸液缓速剂的合成与性能评价[J].
现代化工, 2018, 38(1): 102-106 DOI:10.16606/j.cnki.issn0253-4320.2018.01.023