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摘要
采用硅钼蓝-紫外可见分光光度法测定里松温泉源头水中硅的质量浓度。实验结果表明:体系中硅钼蓝的λmax=814 nm,硅质量浓度在0~0.019 63 μg/mL范围内与吸光度具有良好的线性关系,其线性方程为y=0.212 5+1.197 2x,相关系数为0.999 6,回收率为96.47%~105.0%,RSD为0.358%~1.191%。该方法操作简便、精密度好、准确率高,可用于温泉水中硅质量浓度的测定。
Abstract
The content of silicon in the source water of Lisong hot spring is detected by silicon molybdenum blue UV-visible spectrophotometry method.It is indicated by experimental results that λmax of silicon molybdenum blue in the system is 814 nm and the mass concentration of silicon within the scope of 0-0.019 63 μg·mL-1 has good linear relationship with absorbance.The linear equation is y=0.212 5+1.197 2x and the correlation coefficient is 0.999 6.The recovery rate is in the range of 96.47%-105.0% and the RSD is in the range of 0.358%-1.191%.This method is easy to operate and has high precision and accuracy,which can be used for the determination of silicon content in hot spring water.
关键词
硅钼蓝
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硅
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里松温泉水
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紫外可见分光光度法
Key words
silicon molybdenum blue
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silicon
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Lisong hot spring water
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UV-visible spectrophotometry
Author summay
陈秋娟(1983-),女,硕士研究生,讲师,研究方向为天然产物提取、纯化与分析,2002090099@163.com
硅钼蓝-紫外可见分光光度法测定里松温泉水中硅的含量[J].
现代化工, 2017, 37(12): 210-214 DOI:10.16606/j.cnki.issn0253-4320.2017.12.051