g-C3N4纳米片的制备及光催化抗菌性能研究

马占强, 郭坤, 宋鹏, 石兆勇, 侯典云

现代化工 ›› 2017, Vol. 37 ›› Issue (11) : 97 -101.

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现代化工 ›› 2017, Vol. 37 ›› Issue (11) : 97-101. DOI: 10.16606/j.cnki.issn0253-4320.2017.11.022
科研与开发

g-C3N4纳米片的制备及光催化抗菌性能研究

    马占强, 郭坤, 宋鹏, 石兆勇, 侯典云
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Preparation of g-C3N4 nanosheet and its photocatalytic antibacterial performance

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摘要

采用液相超声法成功地将体相g-C3N4剥离为g-C3N4纳米片。通过XRD、FT-IR、TEM、BET和瞬态光电流对样品的性质进行表征,并研究g-C3N4纳米片光催化杀灭大肠杆菌(E. coli)和金黄色葡萄球菌(S. aureus)的活性。结果表明,将体相g-C3N4剥离为g-C3N4纳米片并没有改变分子结构,但g-C3N4纳米片光催化杀灭E. coliS. aureus的活性均优于体相g-C3N4。g-C3N4纳米片的超薄二维结构具有大的比表面积,是体相g-C3N4的6.97倍,同时有效地促进了光生电子和空穴的分离,两方面的协同作用下,g-C3N4纳米片表现出优异的光催化抗菌活性。

Abstract

The g-C3N4 nanosheets are successfully stripped from bulk g-C3N4 by liquid ultrasonic method. The sample sheets are characterized by XRD, FT-IR, TEM, BET and transient photocurrent. The photocatalytic activities of g-C3N4 nanosheets are evaluated through killing E. coli and S. aureus. The results indicate that the prepared g-C3N4 nanosheets have the same molecular structure as bulk g-C3N4, but exhibit superior photocatalytic antibacterial performance to the bulk. Due to ultra-thin two-dimensional structure, the g-C3N4 nanosheets have large specific surface area, 6.97 times that of bulk g-C3N4, while this structure can effectively promote the separation between photogenerated electrons and holes. Under the synergistic effect of the large specific surface area and efficient separation of photogenerated electrons, g-C3N4 nanosheets show the excellent photocatalytic antibacterial activity.

关键词

g-C3N4纳米片 / S. aureus / E. coli / 抗菌 / 光催化

Key words

g-C3N4 nanosheeet / S. aureus / E. coli / antibacterial / photocatalysis

Author summay

马占强(1978-),男,博士,副教授,研究方向为生物修复和微生物资源利用,mzqnxy@163.com。

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g-C3N4纳米片的制备及光催化抗菌性能研究[J]. 现代化工, 2017, 37(11): 97-101 DOI:10.16606/j.cnki.issn0253-4320.2017.11.022

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