杂质对湿法磷酸氨化料浆絮凝沉降的影响

王佩, 邓伏礼, 龙秉文, 丁一刚

现代化工 ›› 2017, Vol. 37 ›› Issue (7) : 121 -123,125.

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现代化工 ›› 2017, Vol. 37 ›› Issue (7) : 121-123,125. DOI: 10.16606/j.cnki.issn0253-4320.2017.07.028
科研与开发

杂质对湿法磷酸氨化料浆絮凝沉降的影响

    王佩, 邓伏礼, 龙秉文, 丁一刚
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Impact of impurities on flocculation settlement of ammoniated slurry in wet-process phosphoric acid

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摘要

用化学试剂模拟湿法磷酸,将湿法磷酸中Fe3+、Mg2+、Al3+、SO42-杂质的质量分数定在某一固定值,而在一定范围内改变其中1种待考察杂质的质量分数,对其氨化料浆进行絮凝沉降。研究结果表明,Fe3+、Al3+质量分数对氨化料浆絮凝沉降的影响有相似的规律,随着Fe3+、Al3+质量分数的增加,絮凝沉降速率均是先变快后变慢,超过一定范围后,料浆几乎不沉降。Mg2+质量分数在一定范围内随着镁离子质量分数的增大,絮凝沉降变化不大。SO42-的质量分数越高,絮凝沉降速率越小。

Abstract

The wet-process phosphoric acid is stimulated with pure chemical reagents.The concentrations of impurities such as Fe3+,Mg2+,Al3+ and SO42- in the simulating wet-process phosphoric acid are fixed while concentration of the impurity to be studied is varied in a certain range,and then effects of impurities on the flocculation settlement efficiency in the ammoniated slurry of the simulating wet-process phosphoric acid are studied.Results show that concentration of Fe3+ and Al3+ have the similar effect.With the increase of content of Fe3+ or Al3+,the flocculent settling rate becomes faster at first,then slows down.When the content of Fe3+ or Al3+ exceeds a range,the slurry is hardly settling.With the increase of content of Mg2+ in a certain range,the flocculent settling rate has little change.With the increase of content of SO42-,the settling rate becomes slower.

关键词

湿法磷酸 / 沉降 / 絮凝 / 氨化料浆

Key words

wet-process phosphoric acid,ammoniated slurry / settling / flocculation

Author summay

王佩(1992-),女,硕士研究生,研究方向为磷资源的综合利用,412718256@qq.com

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杂质对湿法磷酸氨化料浆絮凝沉降的影响[J]. 现代化工, 2017, 37(7): 121-123,125 DOI:10.16606/j.cnki.issn0253-4320.2017.07.028

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