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现代化工  2022, Vol. 42 Issue (12): 108-113    DOI: 10.16606/j.cnki.issn0253-4320.2022.12.021
  科研与开发 本期目录 | 过刊浏览 | 高级检索 |
基于腐殖酸基储能材料制备的污泥资源化利用研究
贾潇田, 李颖, 张星楠, 李昕飞, 郭穆骞, 杨利霞
中北大学环境与安全工程学院, 山西 太原 030051
Research on utilization of sludge through preparation of humic acid-based energy storage materials
JIA Xiao-tian, LI Ying, ZHANG Xing-nan, LI Xin-fei, GUO Mu-qian, YANG Li-xia
School of Environment and Safety Engineering, North University of China, Taiyuan 030051, China
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摘要 以污泥、污泥源腐殖酸为前驱物,通过活化处理及热还原法制备碳材料。利用SEM、BET、Raman和FT-IR对材料进行结构分析,并利用CV、GCD和EIS等研究其电化学性能。结果表明,KOH作活化剂可以有效改善材料电化学性能,腐殖酸与KOH的活化比为1∶1时材料表现出较高比表面积(174 6 m2/g)和孔容(1.074 5 cm3/g)。该材料在三电极系统中比电容达186.7 F/g,等效内阻仅0.488 Ω,倍率性能良好。以污泥源腐殖酸为前驱物可制得成本低廉的储能材料,为污泥中潜在资源的开发及利用提供了新途径;其良好的电化学性能拓宽了超级电容器中电极材料的应用领域。
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贾潇田
李颖
张星楠
李昕飞
郭穆骞
杨利霞
关键词:  污泥  腐殖酸  超级电容器  储能材料  电化学性能    
Abstract: Sludge and sludge-derived humic acid are used as precursors to prepare carbon material by an activation thermal reduction treatment method.The structure of the material is analyzed by means of SEM,BET,Raman and FT-IR,and the electrochemical properties are investigated by means of CV,GCD and EIS.It is shown that KOH as an activator can effectively improve the electrochemical performance of the material.The prepared carbon material exhibits higher specific surface area (1,746 m2·g-1) and pore volume (1.0745 cm3·g-1) when the activation ratio of humic acid and KOH is 1∶1.It has a specific capacitance of 186.7 F·g-1 in a three-electrode system,an equivalent internal resistance of only 0.488 Ω,and good rate performance.It is indicated that low-cost energy storage material can be prepared by using sludge-derived humic acid as the precursor,which provides a new way for the development and utilization of potential resources in sludge.The good electrochemical properties of the material broaden the application field of electrode materials in supercapacitors.
Key words:  sludge    humic acid    supercapacitor    energy storage materials    electrochemical performance
收稿日期:  2022-07-21      修回日期:  2022-10-01           出版日期:  2022-12-20
ZTFLH:  X703  
基金资助: 山西省自然科学研究面上项目(20210302123071);国家重点研发计划项目(2018YFC1801104,2018YFC1801105)
通讯作者:  李颖(1984-),女,博士,讲师,硕士生导师,研究方向为固体废物资源化利用,通讯联系人,liyingban@163.com。    E-mail:  liyingban@163.com
作者简介:  贾潇田(1997-),女,硕士研究生,研究方向为固体废物资源化利用,1095174461@qq.com
引用本文:    
贾潇田, 李颖, 张星楠, 李昕飞, 郭穆骞, 杨利霞. 基于腐殖酸基储能材料制备的污泥资源化利用研究[J]. 现代化工, 2022, 42(12): 108-113.
JIA Xiao-tian, LI Ying, ZHANG Xing-nan, LI Xin-fei, GUO Mu-qian, YANG Li-xia. Research on utilization of sludge through preparation of humic acid-based energy storage materials. Modern Chemical Industry, 2022, 42(12): 108-113.
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https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2022.12.021  或          https://www.xdhg.com.cn/CN/Y2022/V42/I12/108
[1] Liu H B,Wang L,Zhang X D,et al .A viable approach for commercial VFAs production from sludge:Liquid fermentation in anaerobic dynamic membrane reactor[J].Journal of Hazardous Materials,2018,365(11):912-920.
[2] 戴晓虎.我国污泥处理处置现状及发展趋势[J].科学,2020,72(6):30-33.
[3] Fernandes T V,Lier J V,Zeeman G.Humic acid-like and fulvic acid-like inhibition on the hydrolysis of cellulose and tributyrin[J].Bioenergy Research,2015,8(2):821-831.
[4] Zhang X,He B L,Zhao Y Y,et al .A porous ceramic membrane tailored high-temperature supercapacitor[J].Journal of Power Sources,2018,379:60-67.
[5] Yang Y J,Wang B,Guo X J,et al .Investigating adsorption performance of heavy metals onto humic acid from sludge using Fourier-transform infrared combined with two-dimensional correlation spectroscopy[J].Environmental Science and Pollution Research International,2019,26(10):9846-9850.
[6] Zhao P Y,Yu B J,Sun S,et al .High-performance anode of sodium ion battery from polyacrylonitrile/humic acid composite electrospun carbon fibers[J].Electrochimica Acta,2017,232:348-356.
[7] Yin J,Zhang D Y,Zhao J Q,et al .Meso-and micro-porous composite carbons derived from humic acid for supercapacitors[J].Electrochimica Acta,2014,136:504-512.
[8] 马玉柱.腐殖酸基球形多孔碳的制备及其电化学性能的研究[D].天津:天津大学,2017.
[9] Zhao X Y,Huang S S,Cao J P,et al .Hyper coal-derived porous carbons with alkaline hydroxides and carbonate activation for electric double-layer capacitors[J].Fuel Processing Technology,2014,125:251-257.
[10] 刘迎宾,黄光许,李媛媛,等.煤系腐植酸基层次孔炭的制备及电化学性能[J].洁净煤技术,2019,25(1):148-153.
[11] Huang G X,Geng Q H,Kang W W,et al .Hierarchical porous carbon with optimized mesopore structure and nitrogen doping for supercapacitor electrodes[J].Microporous and Mesoporous Materials,2019,288:109576.
[12] Divya M L,Natarajan S,Lee Y S,et al .Biomass-derived carbon:A value-added journey towards constructing high-energy supercapacitors in an asymmetric fashion[J].ChemSusChem,2019,12:4353-4382.
[13] Yu Z,Meng X,Liu N W,et al .A novel disposal approach of deactivated resin catalyst for methyl tert-butyl ether synthesis:Preparation of low-cost activated carbons with remarkable performance on dibenzothiophene adsorption[J].Fuel,2017,207(1):47-55.
[14] Zhou Y,Ma R G,Candelaria S L,et al .Phosphorus/sulfur Co-doped porous carbon with enhanced specific capacitance for supercapacitor and improved catalytic activity for oxygen reduction reaction[J].Journal of Power Sources,2016,314(5):39-48.
[15] Li L J,Wang X Y,Wang S J,et al .Activated carbon prepared from lignite as supercapacitor electrode materials[J].Electroanalysis,2016,28(1):243-248.
[16] 刘云.氮掺杂碳材料的制备及在超级电容器中的应用研究[D].无锡:江南大学,2019.
[17] Zhu X Q,Zhang L M,Lou G B,et al .Sustainable activated carbons from dead ginkgo leaves for supercapacitor electrode active materials[J].Chem Eng Sci,2018,181:36-45.
[18] Qu W H,Guo Y B,Shen W Z,et al .Using asphaltene supermolecules derived from coal for the preparation of efficient carbon electrodes for Supercapacitors[J].The Journal of Physical Chemistry C,2016,120(28):15105-15113.
[19] Xing B L,Yuan R F,Zhang C X,et al .Facile synthesis of graphene nanosheets from humic acid for supercapacitors[J].Fuel Processing Technology,2017,165:112-122.
[20] Johra F T,Jung W G.Hydrothermally reduced graphene oxide as a supercapacitor[J].Applied Surface Science,2015,357:1911-1914.
[21] Zheng D F,Jia M Q,Xu B,et al .The simple preparation of a hierarchical porous carbon with high surface area for high performance supercapacitors[J].New Carbon Materials,2013,28(2):151-155.
[22] Nguyen Q N K,Yang W D,Chung Z J.Glacial acetic acid catalysed carbon aerogels as electrode material in the electrical double-layer capacitor[J].Materials Research Innovations,2015,19(10):172-175.
[23] Fu R W,Li Z H,Liang Y R,et al .Hierarchical porous carbons:Design,preparation,and performance in energy storage[J].New Carbon Materials,2011,26(3):171-179.
[24] 张曼.杂原子掺杂生物质活性炭材料的制备及其超级电容器和氧还原性能的研究[D].北京:北京化工大学,2017.
[25] Xu J,Zhou X Y,Chen M Z,et al .Preparing hierarchical porous carbon aerogels based on enzymatic hydrolysis lignin through ambient drying for supercapacitor electrodes[J].Microporous and mesoporous materials:The offical journal of the International Zeolite Association,2018,265:258-265.
[26] Yang L,Chen S,Ding Y,et al .Hierarchical network architectures of carbon fiber paper supported cobalt oxide nanonet for high-capacity pseudocapacitors[J].Nano Letters,2012,12(1):321-325.
[27] Chien H C,Cheng W Y,Wang Y H,et al .Ultrahigh specific capacitances for supercapacitors achieved by nickel cobaltite/carbon aerogel composites[J].Advanced Functional Materials,2012,22(23):5038-5043.
[28] Luo H M,Yang Y F,Chen Y Z.Structure and electrochemical performance of highly porous carbons by single-step potassium humatecarbonization for application in supercapacitors[J].Journal of Applied Electrochemistry,2016,46(1):113-121.
[29] Gao M R,Xu Y F,Jiang J,et al .ChemInform abstract:Nanostructured metal chalcogenides:Synthesis,modification,and applications in energy conversion and storage devices[J].ChemInform,2013,42:2987-3017.
[30] Liu B,Liu B Y,Wang Q F,et al .New energy storage option:Toward ZnCo2O4 nanorods/nickel foam architectures for high-performance supercapacitors[J].ACS Applied Materials and Interfaces,2013,5(20):10011-10017.
[31] 王新宇,孙晓峰,张治安,等.活化剂种类对活性炭结构及性能的影响[J].中南大学学报:自然科学版,2011,42(4):865-870.
[32] Ajay K M,Dinesh M N.Performance studies of bamboo based nano activated carbon electrode material for supercapacitor applications[J].Materials Today:Proceedings,2020,46(10):4510-4514.
[33] 佚名.物理化学两步活化法制备煤基活性炭电极材料[J].中国矿业大学学报,2017,46(4):889-893.
[34] 吴翠.改性稻壳活性炭材料对超级电容器电化学性能的影响[D].杭州:浙江工业大学,2016.
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