Abstract: The performance of attapulgite-supported denitration catalyst is reviewed,and the effects of different active components,preparation methods and reaction conditions on the performance of the catalyst are discussed.In the future,research about attapulgite-supported catalyst is proposed to focus on attapulgite modification and active component screening,preparation method optimization and molding process exploration,reaction mechanism and poisoning mechanism,so as to optimize the performance of the catalyst and strive to achieve industrialization as soon as possible.
刘兴誉, 蒲欣, 贾媛媛, 张鹏, 唐中华, 刘军强, 巫树锋, 杨岳. 凹凸棒石SCR脱硝催化剂的研究进展[J]. 现代化工, 2022, 42(12): 60-63,69.
LIU Xing-yu, PU Xin, JIA Yuan-yuan, ZHANG Peng, TANG Zhong-hua, LIU Jun-qiang, WU Shu-feng, YANG Yue. Research progress on attapulgite-supported catalysts for selective catalytic reduction. Modern Chemical Industry, 2022, 42(12): 60-63,69.
[1] 沈永淦,陈小磊.天然矿物原料丛书冶金矿产原料[M].北京:化学工业出版社,2012. [2] 李金虎.凹凸棒石负载锰氧化物低温选择性催化还原NO[D].合肥:合肥工业大学,2010. [3] 万马.凹凸棒石负载锰氧化物催化剂低温SCR反应动力学研究[D].合肥:合肥工业大学,2015. [4] Zhang B,Chen D,Liu H B,et al .Selective catalytic reduction of NO with NH3 over high purity palygorskite-supported MnO2 with different crystal structures[J].Aerosol and Air Quality Research,2020,20(5):1155-1165. [5] Zuo H Q,Xu D Y,Liu W,et al .Heat-treated dolomite-palygorskite clay supported MnOx catalysts prepared by various methods for low temperature selective catalytic reduction (SCR) with NH3[J].Applied Clay Science,2018,152:276-283. [6] Zhang X L,Lv S S,Zhang C P,et al .Effect of SO2 on SCR activity of MnOx /PG catalysts at low temperature[J].Chemical Papers,2015,69(12):1548-1555. [7] 陈建猛.改性凹凸棒土协同脱硝脱汞的实验研究[D].保定:华北电力大学,2019. [8] 张连凤.CeO2对MnOx /PG催化剂低温抗硫脱硝活性影响的研究[D].合肥:合肥工业大学,2014. [9] 刘向辉,赵沛东,谭明金,等.白云石质凹凸棒土负载Fe的NH3-SCR脱硝性能研究[J].煤炭加工与综合利用,2021,(1):92-95. [10] 韩粉女.凹凸棒土为载体的SCR催化剂的制备及其脱硝脱汞性能研究[D].南京:南京理工大学,2017. [11] 张志刚,汤红运,李金虎.凹凸棒石负载MnOx 和FeOx 催化剂催化还原NO的性能[J].建材世界,2010,31(4):6-8. [12] Xiao F,Gu Y J,Tang Z.ZrO2 modified MnOx /attapulgite catalysts for NH3-SCR of NO at low temperature[J].Journal of Chemical Engineering of Japan,2015,48(6):481-487. [13] Zhou X,Huang X,Xie A,et al .V2O5-decorated Mn-Fe/attapulgite catalyst with high SO2 tolerance for SCR of NOx with NH3 at low temperature[J].Chemical Engineering Journal,2017,326:1074-1085. [14] 顾韵婕,韩粉女,唐喆,等.低温选择性催化还原脱硝催化剂CeVO4/凹凸棒土的制备和性能研究[J].化工新型材料,2015,43(3):51-53. [15] Gu Y,Han F,Cang H,et al .Synthesis and research of CeO2-V2O5/ATP for selective catalytic reduction of NOx in flue gas at low temperature[J].Procedia Environmental Sciences,2013,18:412-417. [16] Li Xiazhang,Shi Haiyang,Yan Xiangyu,et al .Rational construction of direct Z-scheme doped perovskite/palygorskite nanocatalyst for photo-SCR removal of NO:Insight into the effect of Ce incorporation[J].Journal of Catalysis,2019,369:190-200. [17] 徐东耀,但海均,左海清,等.凹凸棒土基复合脱硝催化剂制备研究[J].环境工程,2017,35(S1):233-237. [18] 罗平.稀土-凹凸棒石催化剂直接分解NO的研究[D].南昌:南昌大学,2011. [19] 贾小彬.粉煤灰-凹凸棒石负载锰氧化物催化剂低温SCR脱硝性能研究[D].合肥:合肥工业大学,2013. [20] 马永祥.粉煤灰-凹凸棒石为载体锰基催化剂低温脱硝性能研究[J].硫酸工业,2014,(6):51-56. [21] 时博文.凹凸棒石负载过渡金属氧化物低温SCR脱硝催化剂的制备与表征[D].合肥:合肥工业大学,2012. [22] Chen K G,Chen R Y,Tang Z,et al .Plasma-treated Ce/TiO2-palygorskite catalyst for the NH3-SCR of NOx [J].Journal of the Chemical Society of Pakistan,2019,41(1):90-98. [23] Xie W W,Zhang G D,Mu B,et al .The promoting effect of palygorskite on CeO2-WO3-TiO2 catalyst for the selective catalytic reduction of NOx with NH3[J].Applied Clay Science,2020,192:105641. [24] Luo S P,Zhou W T,Xie A J,et al .Effect of MnO2 polymorphs structure on the selective catalytic reduction of NOx with NH3 over TiO2-Palygorskite[J].Chemical Engineering Journal,2015,286:291-299. [25] 张恒建.柱状凹凸棒石-活性炭负载锰氧化物低温SCR脱硝催化剂性能研究[D].合肥:合肥工业大学,2014. [26] 谢爱娟,罗士平,陶宇炜,等.γ -MnO2/海泡石-凹凸棒土低温脱硝催化剂研究[J].常州大学学报:自然科学版,2018,30(4):19-27. [27] 张先龙,解城华,郭勇,等.蜂窝式MnOx /PG-CC催化剂的制备及低温选择性催化还原法脱硝性能[J].环境化学,2015,(4):614-626. [28] 陈韬宇,吴典,蒋金龙,等.V2O5-沸石-活性炭-凹土脱硝催化剂的研制及脱硝性能[J].淮阴工学院学报,2014,23(5):6-11. [29] 杜卫刚,蒋金龙,石莹莹,等.CuO-沸石-活性炭-凹土复合脱硝催化剂的制备[J].非金属矿,2014,37(5):57-60. [30] Lu Y,Cang H,Han F,et al .Synthesis and characterization of vanadia-doped iron-oxide pillared attapulgite clay for the selective catalytic reduction of nitrogen oxides[J].Asian Journal of Chemistry,2012,24(12):5759-5762