Preparation of metal salts modified attapulgite and its application for catalytic production of furfural and 5-hydroxymethyl furfural from bamboo powder
BI Hao-ran1,2, ZHANG Yu1,2, HUANG Ling-ling1,2, LIU Yu-huan1,2, FU Gui-ming1,2, PENG Hong1,2
1. Engineering Research Center for Biomass Conversion of Ministry of Education, Nanchang University, Nanchang 330047, China; 2. State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047, China
Abstract: Furfural (FF) and 5-hydroxymethyl furfural (HMF) are prepared from bamboo powder pretreated with 1-butyl-3-methylimidazole acetate (BmimAc) ionic liquid under microwave heating in water/methyl isobutyl ketone (MIBK) two-phase medium.The catalytic activities of eight kinds of metal salts,including ZnCl2,FeCl2,SnCl2,CrCl3,FeCl3,AlCl3,Fe2(SO4)3,and Al2(SO4)3,are compared and evaluated.The metal salt with the strongest catalytic activity is loaded onto attapulgite (ATP) to obtain a solid acidic catalyst,which is then characterized and its catalytic performance is evaluated.It is shown that the highest yields of FF (78.96%) and HMF (35.04%) are obtained when FeCl3 is used as the catalyst under the same reaction conditions.Compared with ATP,the specific surface area,pore size,and acidic strength of ATP-S-Fe obtained through modification of ATP by FeCl3 and H2SO4 together increase.Under the same reaction conditions,the catalytic activities of ATP-S and ATP-S-Fe are almost equivalent,and both slightly weaker than that of 1 wt% H2SO4.
毕浩然, 张宇, 黄玲玲, 刘玉环, 付桂明, 彭红. 金属盐改性凹土的制备及催化竹粉制备糠醛和5-羟甲基糠醛的研究[J]. 现代化工, 2022, 42(10): 108-113.
BI Hao-ran, ZHANG Yu, HUANG Ling-ling, LIU Yu-huan, FU Gui-ming, PENG Hong. Preparation of metal salts modified attapulgite and its application for catalytic production of furfural and 5-hydroxymethyl furfural from bamboo powder. Modern Chemical Industry, 2022, 42(10): 108-113.
[1] Singh N,Singhania R R,Nigam P S, et al .Global status of lignocellulosic biorefinery:Challenges and perspectives[J].Bioresource Technology,2022,344:126415. [2] Saravanan A,Senthil Kumar P,Jeevanantham S, et al .Recent advances and sustainable development of biofuels production from lignocellulosic biomass[J].Bioresource Technology,2022,344:126203. [3] Yook S D,Kim G,Gong G, et al .High-yield lipid production from lignocellulosic biomass using engineered xylose-utilizing Yarrowia lipolytica [J].GCB-Bioenergy,2020,12:670-679. [4] Guo W,Zhang Z,Hacking J, et al .Selective fructose dehydration to 5-hydroxymethylfurfural from a fructose-glucose mixture over a sulfuric acid catalyst in a biphasic system:Experimental study and kinetic modelling[J].Chemical Engineering Journal,2021,409:128182. [5] Lopes M,Dussan K,Leahy J J.Enhancing the conversion of D-xylose into furfural at low temperatures using chloride salts as co-catalysts:Catalytic combination of AlCl3 and formic acid[J].Chemical Engineering Journal,2017,323:278-286. [6] Zhang T W,Li W Z,Xiao H N, et al .Recent progress in direct production of furfural from lignocellulosic residues and hemicelluloses[J].Bioresource Technology,2022,354:127126. [7] Tempelman C H L,Oozeerally R,Degirmenci V, et al .Heterogeneous catalysts for the conversion of glucose into 5-hydroxymethyl furfural[J].Catalysts,2021,11(7):861. [8] Saenluang K,Thivasasith A,Dugkhuntod P, et al .In situ synthesis of Sn-Beta zeolite nanocrystals for glucose to hydroxymethyl furfural (HMF)[J].Catalysts,2020,10:1249. [9] 石莹莹.凹凸棒土基复合光催化剂的制备及其对水中四环素去除性能的研究[D].南京:南京大学,2017. [10] 唐玉婷,丁思淳,韩承霖.腐殖酸负载对凹凸棒土吸附Zn(Ⅱ)的影响[J].华南理工大学学报,2022,50(4):110-118. [11] Lyu X,Botte G G.Investigation of factors that inhibit furfural production using metal chloride catalysts[J].Chemical Engineering Journal,2021,403:126271. [12] Gagne O C,Hawthorne F C.Empirical Lewis acid strengths for 135 cations bonded to oxygen[J].Acta Crystallographica Section B:Structural Science Crystal Engineering and Materials,2017,73(5):956-961. [13] 唐玉婷,丁思淳,韩承霖.腐殖酸负载对凹凸棒土吸附Zn(Ⅱ)的影响[J].华南理工大学学报,2022,50(4):110-118. [14] 李迎春,董良飞,仝驰,等.稀土改性凹凸棒土对低浓度磷的吸附性能[J].环境工程学报,2021,15(10):3214-3222. [15] Tian H,Shao Y,Liang C, et al .Sulfated attapulgite for catalyzing the conversion of furfuryl alcohol to ethyl levulinate:Impacts of sulfonation on structural transformation and evolution of acidic sites on the catalyst[J].Renewable Energy,2020,162:1576-1586. [16] Wang Y S,Liang D F,Wang C S, et al .Influence of calcination temperature of Ni/Attapulgite on hydrogen production by steam reforming ethanol[J].Renewable Energy,2020,160:597-611. [17] 刘昊天,蔡子楠,贾天飞,等.单活性中心氧化还原体系引发N-异丙基丙烯酰胺在凹凸棒土表面的高效接枝聚合[J].高分子材料科学与工程,2020,36(1):20-26. [18] 陈茂,张鑫,谢伟,等.生物炭/凹凸棒土的制备及对磺胺嘧啶的吸附[J].化工进展,2002,41(5):2623-2635. [19] 喻红梅,华平,李建华,等.磁性固体酸催化剂Fe3O4/C-SO3H制备及表征[J].日用化学工业,2022,52(4):396-403. [20] 夏强,向小倩,廖小刚,等.可磁分离回收多孔CoFe2O4的制备及其催化过一硫酸盐降解亚甲基蓝溶液的性能[J].材料工程,2022,50(6):107-116. [21] 王芳芳,张金銮,朱兆连,等.有序介孔碳负载纳米CuO</i>x 强化吸附2,4-二氯苯酚[J].南京工业大学学报,2022,44(3):328-334. [22] Zhang L,Zhang D S,Zhang J P, et al .Design of meso-TiO2@MnO</i>x -CeO</i>x /CNTs with a core-shell structure as DeNO</i>x catalysts:Promotion of activity,stability and SO2-tolerance[J].Nanoscale,2013,5(20):9821-9829.