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现代化工  2022, Vol. 42 Issue (9): 134-140    DOI: 10.16606/j.cnki.issn0253-4320.2022.09.027
  科研与开发 本期目录 | 过刊浏览 | 高级检索 |
SiO2气凝胶负载过渡金属氧化物催化分解N2O的研究
王逸飞1, 王亚涛2, 王新承1, 马小丰2, 李翠清1, 王虹1, 宋永吉1
1. 北京石油化工学院新材料与化工学院, 燃料清洁化及高效催化减排技术北京市重点实验室, 北京 102617;
2. 唐山开滦化工科技有限公司煤化工研发中心, 河北 唐山 063006
Study on catalytic decomposition of N2O by SiO2 aerogel supported transition metal oxides
WANG Yi-fei1, WANG Ya-tao2, WANG Xin-cheng1, MA Xiao-feng2, LI Cui-qing1, WANG Hong1, SONG Yong-ji1
1. Beijing Key Laboratory of Fuels Cleaning and Advanced Catalytic Emission Reduction Technology, College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China;
2. Coal Chemical R&D Center, Tangshan Kailuan Chemical Technology Co., Ltd., Tangshan 063006, China
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摘要 以二氧化硅气凝胶为载体,采用等体积浸渍法制备了一系列不同负载量的过渡金属氧化物M/SiO2-ag(M=Ni、Co、Cu、Fe、Mn、Zn)催化剂,利用XRD、BET、H2-TPR等对催化剂进行表征,研究了SiO2气凝胶负载过渡金属氧化物分解N2O的催化性能。结果表明,负载NiO的样品具有最高的催化分解活性,当NiO负载量为27%时催化活性最佳,可在451℃完全转化N2O;在455℃下对Ni27/SiO2-ag进行100 h寿命实验,催化活性未下降,表明Ni27/SiO2-ag具有较好的热稳定性。
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王逸飞
王亚涛
王新承
马小丰
李翠清
王虹
宋永吉
关键词:  氧化亚氮  催化分解  过渡金属氧化物  SiO2气凝胶  催化剂    
Abstract: Using SiO2 aerogel as the carrier,a series of transition metal oxides catalysts,M/SiO2-ag (M=Ni,Co,Cu,Fe,Mn,Zn),with different loadings are prepared via an equal volume impregnation method.The prepared catalysts are analyzed by means of XRD,BET and H2-TPR.Their catalytic performance for the decomposition of N2O is studied.Among them,the sample loaded with NiO has the highest catalytic decomposition activity.The catalyst has the best catalytic activity when the loading amount of NiO is 27%,over which N2O can completely be converted at 451℃.The catalytic activity of Ni27/SiO2-ag does not drop after 100 h of life test at 455℃,indicating that Ni27/SiO2-ag has a good thermal stability.
Key words:  nitrous oxide    catalytic decomposition    transition metal oxides    SiO2 aerogel    catalyst
收稿日期:  2021-10-15      修回日期:  2022-07-04           出版日期:  2022-09-20
ZTFLH:  TQ426  
基金资助: 国家自然科学基金项目(20176012,21076025)
通讯作者:  宋永吉(1963-),男,博士,教授,研究方向为工业催化减排及催化燃烧技术的应用,通讯联系人,songyongji@bipt.edu.cn    E-mail:  songyongji@bipt.edu.cn
作者简介:  王逸飞(1993-),男,硕士研究生,研究方向为工业催化减排,wyfcupb@163.com
引用本文:    
王逸飞, 王亚涛, 王新承, 马小丰, 李翠清, 王虹, 宋永吉. SiO2气凝胶负载过渡金属氧化物催化分解N2O的研究[J]. 现代化工, 2022, 42(9): 134-140.
WANG Yi-fei, WANG Ya-tao, WANG Xin-cheng, MA Xiao-feng, LI Cui-qing, WANG Hong, SONG Yong-ji. Study on catalytic decomposition of N2O by SiO2 aerogel supported transition metal oxides. Modern Chemical Industry, 2022, 42(9): 134-140.
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https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2022.09.027  或          https://www.xdhg.com.cn/CN/Y2022/V42/I9/134
[1] 孙巾茹,夏蕾,李靖宇,等.晶化温度对Co3O4催化分解N2O的性能影响[J].现代化工,2019,39(4):89-93.
[2] 刘久欣,王新承,李翠清,等.直接催化分解氧化亚氮的金属氧化物催化剂研究进展[J].化工环保,2021,41(3):263-272.
[3] Parks J E.Less costly catalysts for controlling engine emissions[J].Science,2010,327(5973):1584-1585.
[4] Kramlich J C,Linak W P.Nitrous oxide behavior in the atmosphere,and in combustion and industrial systems[J].Progress in Energy and Combustion Science,1994,20(2):149-202.
[5] Sui C,Zhang T R,Dong Y L,et al.Interaction between Ru and Co3O4 for promoted catalytic decomposition of N2O over the Rux-Co3O4 catalysts[J].Molecular Catalysis,2017,435:174-181.
[6] 张远洋,郭亚琼,李娜,等.N2O回收利用及减排技术研究进展[J].化工环保,2018,38(5):499-504.
[7] Reimer R A,Slaten C S,Seapan M,et al.Abatement of N2O emissions produced in the adipic acid industry[J].Environmental Progress,1994,13(2):134-137.
[8] Russo N,Fino D,Saracco G,et al.N2O catalytic decomposition over various spinel-type oxides[J].Catalysis Today,2007,119(1-4):228-232.
[9] 仇杨君,黄思齐,庞子涛,等.CuYO/γ-Al2O3催化剂催化分解N2O性能[J].环境化学,2018,37(7):1591-1598.
[10] 李成业.Ni元素对Pt-TiO2催化剂上N2O生成机理的影响研究[D].杭州:浙江大学,2020.
[11] Ghasemi A H,Naeimi H.Design,preparation and characterization of aerogel NiO-CuO-CoO/SiO2 nanocomposite as a reusable catalyst for C-N cross-coupling reaction[J].New Journal of Chemistry,2020,44(13):5056-5063.
[12] Zhang Z M,Zuo X H,Ruan M,et al.Study on technical parameters for synthesis of multi-walled carbon nanotubes over the NiO/SiO2 aerogel[J].Journal of Huangshi Institute of Technology,2008,24(5):34-36.
[13] 赵永祥,武志刚,许临萍,等.NiO/SiO2气凝胶催化剂性能研究Ⅰ.镍含量的影响[J].燃料化学学报,2001,29(1):178-181.
[14] Kapteijn F,Rodriguez-Mirasol J,Moulijn J A.Heterogeneous catalytic decomposition of nitrous oxide[J].Applied Catalysis B Environmental,1996,9(1-4):25-64.
[15] Ohnishi C,Asano K,Iwamoto S,et al.Alkali-doped Co3O4 catalysts for direct decomposition of N2O in the presence of oxygen[J].Catalysis Today,2007,120(2):145-150.
[16] 曹雨来.氧化亚氮催化分解催化剂的制备及中试实验研究[D].北京:北京石油化工学院,2017.
[17] 仇杨君.催化分解N2O催化剂制备及中试条件研究[D].北京:北京石油化工学院,2018.
[18] Jia H J,Liu S,Mao Z Y,et al.Preparation and properties of the Al2O3-SiO2 aerogel/alumina framework composite[J].Ceramics International,2020,47(1):1466-1471.
[19] Sui L L,Yu T T,Zhao D,et al.In situ deposited hierarchical CuO/NiO nanowall arrays film sensor with enhanced gas sensing performance to H2S[J].Journal of Hazardous Materials,2020,385:121570.
[20] Rubab R,Ali S,Rehman A U,et al.Templated synthesis of NiO/SiO2 nanocomposite for dye removal applications:Adsorption kinetics and thermodynamic properties[J].Colloids and Surfaces A Physicochemical and Engineering Aspects,2021,615:126253.
[21] Erdem S,Erdem B,ÖksüzoAǧlu R M,et al.Effect of calcination temperature on the structural and magnetic properties of Ni/SBA-15 nanocomposite[J].Journal of Porous Materials,2015,22:689-698.
[22] Zeng B,Hou B,Jia L T,et al.The intrinsic effects of shell thickness on the Fischer-Tropsch synthesis over core-shell structured catalysts[J].Catalysis Science & Technology,2013,3(12):3250.
[23] 李章良,张国鑫,潘文斌.Cu/Zn非均相Fenton催化剂的制备及其对环丙沙星的降解效果[J].环境工程学报,2021,15(3):806-816.
[24] 黄思齐,王新承,于泳,等.负载型铜铁催化剂直接催化分解N2O的研究[J].现代化工,2019,39(8):124-128,133.
[25] Chen J,Na Y,Wang R,et al.Hydrogenation of chloronitrobenzene to chloroaniline over Ni/TiO2 catalysts prepared by sol-gel method[J].Chemical Engineering Journal,2009,148(1):164-172.
[26] Liu C X,Gong L,Dai R Y,et al.Mesoporous Mn promoted Co3O4 oxides as an efficient and stable catalyst for low temperature oxidation of CO[J].Solid State Sciences,2017,71:69-74.
[27] 宁军霞,杨金香,贺艳斌,等.硅源对Cu/SiO2催化剂催化对羟基苯乙酸乙酯加氢性能的影响[J].化学与生物工程,2017,34(3):24-26.
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