Study on cycloaddition reaction between CO2 and epoxides over hierarchical porous Mg-MOF under mild conditions
HU Chun-hui, WU Jing-jing, LIU Xue-ting
Anhui Provincial Key Laboratory of Controllable Chemical & Material Chemical Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China
Abstract: Mg-TATAB,a novel kind of hierarchical porous metal organic frameworks (MOFs),is synthesized through solvent thermal method with magnesium ion (Mg2+) as metal center and 4,4',4″-((1,3,5-triazine-2,4,6-triyl)tris(azanediyl))tribenzoic acid (H3TATAB),a nitrogen-rich polycarboxylic group ligand,as linker.The structure of Mg-TATAB is characterized by means of XRD,SEM,XPS,FTIR and BET,etc.The cycloaddition reaction between epoxide and CO2 is effectively performed under mild conditions such as ambient pressure,cocatalyst free and solvent free.Results show that Mg-TATAB shows a high catalytic activity and selectivity for this cycloaddition reaction.In addition,the selectivity of catalyst decreases slightly after it has been reused.
胡春慧, 吴晶晶, 刘雪霆. 温和条件下多级孔Mg-MOF催化CO2与环氧化物的环加成反应研究[J]. 现代化工, 2022, 42(8): 89-95.
HU Chun-hui, WU Jing-jing, LIU Xue-ting. Study on cycloaddition reaction between CO2 and epoxides over hierarchical porous Mg-MOF under mild conditions. Modern Chemical Industry, 2022, 42(8): 89-95.
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