Please wait a minute...
 
最新公告: 重要提醒:骗子冒充编辑部要求加作者微信,谨防上当!   关于暑假、寒假期间版面费发票及期刊样刊延迟邮寄的通知    
现代化工  2022, Vol. 42 Issue (7): 110-113,119    DOI: 10.16606/j.cnki.issn0253-4320.2022.07.022
  科研与开发 本期目录 | 过刊浏览 | 高级检索 |
生物基2,3-丁二醇选择性脱氢制备3-羟基丁酮反应工艺研究
周峰1, 马会霞1, 欧阳素芳2, 张淑梅1, 姜睿1, 乔凯1
1. 中国石油化工股份有限公司大连石油化工研究院, 辽宁 大连 116045;
2. 中国石油化工股份有限公司, 北京 100728
Study on selective dehydrogenation of bio-based 2,3-butanediol to 3-hydroxybutanone
ZHOU Feng1, MA Hui-xia1, OUYANG Su-fang2, ZHANG Shu-mei1, JIANG Rui1, QIAO Kai1
1. Sinopec Dalian Research Institute of Petroleum and Petrochemicals, Dalian 116045, China;
2. China Petroleum & Chemical Corporation, Beijing 100728, China
下载:  PDF (1508KB) 
输出:  BibTeX | EndNote (RIS)      
摘要 采用自主知识产权并已工业化的铜基脱氢催化剂研究了2,3-丁二醇(BDO)选择性脱氢生产3-羟基丁酮(3H2B)反应工艺,分别考察了温度、空速、氢醇摩尔比等条件对反应的影响。结果表明,在临氢工况下,反应压力为常压~0.2 MPa、温度为250~270℃、氢醇摩尔比为3∶1、LHSV在2.0~9.0 h-1时,2,3-丁二醇转化率≥56%,3H2B选择性≥97%;在非临氢工况下,反应压力为常压~0.2 MPa、温度为250~270℃、LHSV在2.0~5.0 h-1时,BDO转化率≥60%,3H2B选择性≥96.0%。催化剂经1600h稳定性实验后,催化性能保持稳定,BDO转化率≥65%,3H2B选择性≥96%。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
周峰
马会霞
欧阳素芳
张淑梅
姜睿
乔凯
关键词:  2,3-丁二醇  生物基  选择性脱氢  3-羟基丁酮  乙偶姻    
Abstract: A commercial copper-based dehydrogenation catalyst with independent intellectual property rights is used to study the selective dehydrogenation of 2,3-butanediol (BDO) to produce 3-hydroxybutanone (3H2B).The effects of temperature,space velocity and the molar ratio of hydrogen to BDO respectively on the reaction are investigated.The results show that the conversion rate of BDO is not less than 56% and the selectivity of 3H2B is not less than 97% when the reaction is performed under the condition of hydrogen exposure,the pressure is 0.2 MPa,the temperature is 250-270℃,the molar ratio of H2 to BDO is 3:1,and LHSV is 2.0-9.0 h-1.The conversion rate of BDO is not less than 60% and the selectivity of 3H2B is not less than 96.0% when the reaction is performed under the condition of without hydrogen exposure,the pressure is 0.2 MPa,the temperature is 250-270℃,and LHSV is 2.0-5.0 h-1.After experiencing 1 600 hours of stability test,the catalytic performance of the catalyst remains stable,the BDO conversion rate is not less than 65%,and the 3H2B selectivity is not less than 96%.
Key words:  2,3-butanediol    bio-based    selective dehydrogenation    3-hydroxybutanone    acetoin
收稿日期:  2022-03-07      修回日期:  2022-05-07           出版日期:  2022-07-20
ZTFLH:  TQ426.94  
基金资助: 国家自然科学基金项目(22078311)
通讯作者:  马会霞(1987-),女,硕士,副研究员,研究方向为生物质资源化利用,通讯联系人,mahuixia.fshy@sinopec.com。    E-mail:  mahuixia.fshy@sinopec.com。
作者简介:  周峰(1982-),男,博士,高级工程师,研究方向为生物质资源化利用,zhoufeng.fshy@sinopec.com
引用本文:    
周峰, 马会霞, 欧阳素芳, 张淑梅, 姜睿, 乔凯. 生物基2,3-丁二醇选择性脱氢制备3-羟基丁酮反应工艺研究[J]. 现代化工, 2022, 42(7): 110-113,119.
ZHOU Feng, MA Hui-xia, OUYANG Su-fang, ZHANG Shu-mei, JIANG Rui, QIAO Kai. Study on selective dehydrogenation of bio-based 2,3-butanediol to 3-hydroxybutanone. Modern Chemical Industry, 2022, 42(7): 110-113,119.
链接本文:  
https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2022.07.022  或          https://www.xdhg.com.cn/CN/Y2022/V42/I7/110
[1] Azadi P,Carrasquilloflores R,Pagántorres Y J,et al.Catalytic conversion of biomass using solvents derived from lignin[J].Green Chem,2012,14(6):1573-1576.
[2] Liu Hui,Cheng Tao,Xian Mo,et al.Fatty acid from the renewable sources:A promising feedstock for the production of biofuels and biobased chemicals[J].Biotechnol Adv,2014,32(2):382-389.
[3] Song D.Kinetic model development for dehydration of 2,3-butanediol to 1,3-butadiene and methyl ethyl ketone over an amorphous calcium phosphate catalyst[J].Ind Eng Chem Res,2016,55(45):11664-11671.
[4] GB 2760-2014,食品安全国家标准,食品添加剂使用标准[S].北京:中国标准出版社,2014-12-04.
[5] Duan H,Sun D,Yamada Y,et al.Dehydration of 2,3-butanediol into 3-buten-2-ol catalyzed by ZrO2[J].Catal Commun,2014,48:1-4.
[6] Zhang L,Singh R,Sivakumar D,et al.Artifcial synthetic pathway for acetoin,2,3-butanediol,and 2-butanol production from ethanol using cell free multi-enzyme catalysis[J].Green Chemistry,2018,20(1):230-242.
[7] Faveri D D,Torre P,Molinari F,et al.Carbon material balances and bioenergetics of 2,3-butanediol bio-oxidation by Acetobacter hansenii[J].Enzyme Microb Technol,2003,33(5):708-719.
[8] Romano A,Gandolf R,Nitti P.Acetic acid bacteria as enantioselective biocatalysts[J].J Mol Catal B,2002,17(6):235-240.
[9] Xiao Z,Xu P.Acetoin metabolism in bacteria[J].Critical Reviews in Microbiology,2007,33(2):127-140.
[10] Gu Y,Duan X,Yang L,et al.Direct C-H cyanoalkylation of heteroaromatic n-oxides and quinones via C-C bond cleavage of cyclobutanone oximes[J].Org Lett,2017,19(21):5908-5911.
[11] Jónsdóttir R,Ólafsdóttir G,Chanie E,et al.Volatile compounds suitable for rapid detection as quality indicators of cold smoked salmon (salmo salar)[J].Food Chemistry,2008,19(1):184-195.
[12] David C,Robacker CR,He X.Volatiles production and attractiveness to the mexican fruit fly ofenterobacter agglomeranaisolated from apple maggot and mexican fruit fies[J].Journal of Chemical Ecology,2004,30(7):1329-1347.
[13] 王之建,贾卫民,李喜彦.乙醛催化制备乙偶姻[C].2004年中国香料香精学术研讨会论文集,2004:157-159.
[14] 冯涛,姜霆,黄娣,等.CuO/凹凸棒土负载型催化剂的合成及其催化2,3-丁二醇的脱氢反应[J].2017,46(8):979-984.
[15] 倪萍.2,3-丁二醇选择性脱氢高效Cu基催化剂研究[D].扬州:扬州大学,2019.
[16] Zhang B,Zhou F,Ma H,et al.Dehydrogenation of 2,3-butanediol to 3-hydroxybutanone over CuZnAl catalysts:Effect of lithium cation as promoter[J].Topics in Catalysis,2020,63:866-874.
[17] 苏杰,乔凯,周峰,等.一种仲丁醇脱氢催化剂及其制备方法:CN105709752[P].2018-06-19.
[1] 刘茁, 陈启杰, 陈广, 王凤, 雷广艳, 魏雅琴. 生物基阻燃剂在纤维素基材料中的应用研究进展[J]. 现代化工, 2022, 42(5): 50-54.
[2] 张朝群, 李世哲, 王也铭, 黄丹. 生物基异山梨醇型环氧固化剂的制备及性能研究[J]. 现代化工, 2022, 42(4): 202-205,211.
[3] 王成, 万婷婷, 徐日炜. 生物基环保PVC增塑剂研究进展[J]. 现代化工, 2021, 41(8): 72-79.
[4] 踪张扬, 陈启杰, 王建辉, 魏雅琴, 何飞. 生物基胶囊壳的研究进展[J]. 现代化工, 2021, 41(4): 22-25.
[5] 荣智, 陈启杰, 赵雅兰, 郑小玲, 杨水英. 生物基绿色阻燃剂的研究进展[J]. 现代化工, 2020, 40(7): 50-54.
[6] 朱欢银, 张才亮, 冯连芳, 顾雪萍. 生物基1,3-丙二醇中微量杂质的气相色谱-质谱分析法[J]. 现代化工, 2020, 40(1): 220-224,229.
[7] 严群, 张越, 汪宏, 卢艳秋. 煤渣及生物基质渗滤系统强化脱氮研究[J]. 现代化工, 2017, 37(5): 150-153.
[8] 谢振华, 金立维. 环氧脂肪酸甲酯增塑剂对乙酰木粉基复合材料性能的影响[J]. 现代化工, 2014, 34(6): 92-96.
[9] 王万卷, 余巧玲, 何国山, 潘永红, 叶元坚. 生物基塑料分析鉴定方法综述[J]. 现代化工, 2014, 34(12): 154-157.
[10] 纪晓俊,黄和,杜军,任潇,李霜. 3-羟基丁酮的合成及应用进展[J]. , 2008, 28(4): 0-0.
No Suggested Reading articles found!
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
京ICP备09035943号-37
版权所有 © 《现代化工》编辑部
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn