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现代化工  2022, Vol. 42 Issue (7): 75-78,83    DOI: 10.16606/j.cnki.issn0253-4320.2022.07.016
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碳基载体石油馏分加氢脱硫催化剂研究进展
耿新国, 杨卫亚, 隋宝宽, 王刚
中国石油化工股份有限公司大连石油化工研究院, 辽宁 大连 116045
Carbon-supported catalysts for hydrodesulfurization of petroleum fractions:A review
GENG Xin-guo, YANG Wei-ya, SUI Bao-kuan, WANG Gang
Dalian Research Institute of Petroleum and Petrochemicals, Sinopec Corp., Dalian 116045, China
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摘要 总结了以活性炭、碳纳米管、介孔碳、石墨烯等碳基材料为载体的加氢脱硫催化剂的研究进展。与常规Al2O3基载体催化剂相比,碳基载体催化剂比表面积大,活性金属的分散性好,活性金属-碳表面间的相互作用弱,有利于形成高活性的Ⅱ类活性相。以二苯并噻吩及4,6-二甲基二苯并噻吩等含硫有机物为处理对象,碳基载体加氢脱硫催化剂总体上具有比Al2O3基载体催化剂更高的加氢脱硫催化活性。为满足碳基载体加氢脱硫催化剂的工业应用要求,需要降低制备成本,并针对催化体系的特点进行孔结构优化及表面改性,同时,还需要加强对碳基加氢催化剂加氢脱硫反应机理和动力学方面的研究,以促进催化剂与工艺技术的进步。
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耿新国
杨卫亚
隋宝宽
王刚
关键词:  碳材料  氧化铝  载体  加氢脱硫  催化剂    
Abstract: This review focuses on the research advances in hydrodesulfurization catalysts supported on carbon-based materials such as activated carbon,carbon nanotubes,mesoporous carbon and graphene.Compared with conventional Al2O3-supported catalysts,carbon-supported catalysts have large specific surface area,good dispersion of active metals and weak interaction between active metal and carbon surface,which is conducive to the formation of type Ⅱ active phases with high activity.Taking dibenzothiophene,4,6-dimethyldibenzothiophene and other sulfur-containing organic compounds as the treatment objects,carbon-supported hydrodesulfurization catalysts generally have higher hydrodesulfurization catalytic performance than those catalysts supported on Al2O3.In order to meet the demand of industrial applications,the preparation cost of carbon-supported hydrodesulfurization catalysts needs to be reduced.And the pore structures and surface properties of carbon-supported hydrodesulfurization catalysts should be optimized and modified according to the needs of catalytic system.Furthermore,it is necessary to strengthen the research on the mechanism and kinetics of hydrodesulfurization reaction,to promote the progress in hydrodesulfurization catalyst and process technology.
Key words:  carbon material    alumina    support    hydrodesulfurization    catalyst
收稿日期:  2022-02-10      修回日期:  2022-05-05           出版日期:  2022-07-20
ZTFLH:  TQ426.94  
基金资助: 中国石化资助项目(119014-3-3)
通讯作者:  杨卫亚(1976-),男,硕士,研究员,研究方向为催化新材料开发,通讯联系人,yangweiya.fshy@sinopec.com。    E-mail:  yangweiya.fshy@sinopec.com。
作者简介:  耿新国(1978-),男,硕士,高级工程师,研究方向为炼油加氢工艺,gengxinguo.fshy@sinopec.com
引用本文:    
耿新国, 杨卫亚, 隋宝宽, 王刚. 碳基载体石油馏分加氢脱硫催化剂研究进展[J]. 现代化工, 2022, 42(7): 75-78,83.
GENG Xin-guo, YANG Wei-ya, SUI Bao-kuan, WANG Gang. Carbon-supported catalysts for hydrodesulfurization of petroleum fractions:A review. Modern Chemical Industry, 2022, 42(7): 75-78,83.
链接本文:  
https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2022.07.016  或          https://www.xdhg.com.cn/CN/Y2022/V42/I7/75
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