Advances in alkali-resistant spirocyclic N-heterocyclic quaternary ammonium based anion exchange membrane materials
WANG Xin1,2, LIU Shi-bin1, LIU Lei3, LI Nan-wen2
1. College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024, China; 2. Institute of Coal Chemistry of Chinese Academy of Sciences, Taiyuan 030001, China; 3. College of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000, China
Abstract: This article reviews the research advances in spirocyclic N-heterocyclic anion exchange membrane materials in recent years,including the preparation method and classification of membrane materials,degradation mechanism and hydrogen-oxygen fuel cell performance.The development trend of the materials is analyzed and prospected.
王薪, 刘世斌, 刘磊, 李南文. 耐碱的螺环型N-杂环季铵盐阴离子交换膜材料的研究进展[J]. 现代化工, 2022, 42(4): 23-27.
WANG Xin, LIU Shi-bin, LIU Lei, LI Nan-wen. Advances in alkali-resistant spirocyclic N-heterocyclic quaternary ammonium based anion exchange membrane materials. Modern Chemical Industry, 2022, 42(4): 23-27.
[1] Varcoe J R,Atanssov P,Dekel D R,et al.Anion-exchange membranes in electrochemical energy systems[J].Energy & Environmental Science,2014,7(10):3135-3191. [2] 薛博欣.耐碱型有机阳离子的分子结构设计及阴离子交换膜制备[D].合肥:中国科学技术大学,2020. [3] 薛博欣,郑吉富,张所波.耐碱的胍盐阴离子交换膜研究进展[J].科学通报,2019,64(2):134-144. [4] Lai A N,Zhou K,Zhou Y Z,et al.Anion exchange membranes based on carbazole-containing polyolefin for direct methanol fuel cells[J].Journal of Membrane Science,2016,497:99-107. [5] Mohanty A D,Bae C.Mechanistic analysis of ammonium cation stability for alkaline exchange membrane fuel cells[J].Journal of Materials Chemistry A,2014,2:17314-17320. [6] Arges C G,Ramani V.Two-dimensional NMR spectroscopy reveals cation-triggered backbone degradation in polysulfone-based anion exchange membranes[J].Proceedings of the National Academy of Sciences,2013,110(7):2490-2495. [7] Marino M G,Kreuer K D.Alkaline stability of quaternary ammonium cations for alkaline fuel cell membranes and ionic liquids[J].ChemSusChem,2015,8:513-523. [8] 刘磊,褚晓萌,李南文.碱性燃料电池用聚烯烃类阴离子交换膜的研究进展[J].科学通报,2019,64(2):123-133. [9] Pham T H,Jannasch P.Aromatic polymers incorporating bis-N-spirocyclic quaternary ammonium moieties for anion-exchange membranes[J].ACS Macro Letters,2015,4:1370-1375. [10] Gu F,Dong H,Li Y,et al.Exchange membranes:Experimental studies and theoretical calculations[J].Macromolecules,2014,47:208-216. [11] Mohanty A D,Tignor S E,Krause J A,et al.Systematic alkaline stability study of polymer backbones for anion exchange membrane applications[J].Macromolecules,2016,49:3361-3372. [12] Pham T H,Jannasch P.N-Spirocyclic quaternary ammonium ionenes for anion-exchange membranes[J].Journal of the American Chemical Society,2017,139:2888-2891. [13] Zhang X,Chu X,Zhang M,et al.Molecularly designed,solvent processable tetraalkylammonium-functionalized fluoropolyolefin for durable anion exchange membrane fuel cells[J].Journal of Membrane Science,2019,574:212-221. [14] Hibbs M R,Fujimoto C H,Cornelius C J.Synthesis and characterization of poly (phenylene)-based anion exchange membranes for alkaline fuel cells[J].Macromolecules,2009,42:8316-8321. [15] Dang H S,Jannasch P.High-performing hydroxide exchange membranes with flexible tetra-piperidinium side chains linked by alkyl spacers[J].ACS Applied Energy Materials,2018,1:2222-2231. [16] Chen N,Long C,Li Y,et al.Ultra-stable and high ion-conducting polyelectrolyte based on six-membered N-Spirocyclic ammonium for hydroxide exchange membrane fuel cell applications[J].ACS Applied Materials & Interfaces,2018,10:15720-15732. [17] Chu X,Liu L,Huang Y,et al.Practical implementation of bis-six-membered N-cyclic quaternary ammonium cations in advanced anion exchange membranes for fuel cells:Synthesis and durability[J].Journal of Membrane Science,2019,578:239-250. [18] Wang X,Sheng W,Shen Y H,et al.N-cyclic quaternary ammonium-functionalized anion exchange membrane with improved alkaline stability enabled by aryl-ether free polymer backbones for alkaline fuel cells[J].Journal of Membrane Science,2019,587:117135. [19] Mohanty A D,Chang Y R,Yu S K,et al.Stable elastomeric anion exchange membranes based on quaternary ammonium-tethered polystyrene-b-poly(ethylene-co-butylene)-b-polystyrene triblock copolymers[J].Macromolecules,2015,48(19):7085-7095. [20] Liu L,Chu X M,Liao J Y,et al.Tuning the properties of poly (2,6-dimethyl-1,4-phenylene oxide) anion exchange membranes and their performance in H2/O2 fuel cells[J].Energy Environment Science,2018,11:435-446. [21] Park H J,Chu X M,Kim S P,et al.Effect of N-cyclic cationic groups in poly(phenylene oxide)-based catalyst ionomer membranes for anion exchange membrane fuel cells[J].Journal of Membrane Science,2020,608:118183. [22] Omasta T J,Park A M,Lamanna J M,et al.Beyond catalysis and membranes:Visualizing and solving the challenge of electrode water accumulation and flooding in AEMFCs[J].Energy & Environmental Science,2018,11:551-558. [23] Lin C,Wang X,Hu E,et al.Quaternized triblock polymer anion exchange membranes with enhanced alkaline stability[J].Journal of Membrane Science,2017,541:358-366.