Please wait a minute...
 
最新公告: 重要提醒:骗子冒充编辑部要求加作者微信,谨防上当!   关于暑假、寒假期间版面费发票及期刊样刊延迟邮寄的通知    
现代化工  2021, Vol. 41 Issue (10): 157-161,167    DOI: 10.16606/j.cnki.issn0253-4320.2021.10.032
  科研与开发 本期目录 | 过刊浏览 | 高级检索 |
TiO2/ZnO/木质素全波段紫外屏蔽剂的制备及其防晒性能研究
季金金1, 左士祥1, 刘文杰2, 李霞章1, 吴凤芹1, 姚超1
1. 常州大学石油化工学院, 江苏 常州 213164;
2. 常州大学盱眙凹土研发中心, 江苏 盱眙 211700
Preparation of TiO2/ZnO/lignin full-band ultraviolet shielding agent and study on its sunscreen performance
JI Jin-jin1, ZUO Shi-xiang1, LIU Wen-jie2, LI Xia-zhang1, WU Feng-qin1, YAO Chao1
1. School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China;
2. Xuyi R&D Center of Attapulgite Applied Technology, Changzhou University, Xuyi 211700, China
下载:  PDF (3689KB) 
输出:  BibTeX | EndNote (RIS)      
摘要 以TiO2/ZnO为核体,在其表面包覆木质素,制备TiO2/ZnO/木质素全波段紫外屏蔽材料。通过UV-Vis、TG、XRD、FT-IR、TEM和光催化性能测试等对材料进行结构和性能分析。结果表明,木质素能够有效降低锌-钛复合材料的光催化活性,且最佳包覆量为15%。将TiO2/ZnO/木质素复合材料与市售TiO2/ZnO以相同活性组分添加至防晒配方中,考察配方稳定性、防晒性能等。结果表明,TiO2/ZnO/木质素复合材料具有更优异的紫外屏蔽能力和稳定性。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
季金金
左士祥
刘文杰
李霞章
吴凤芹
姚超
关键词:  二氧化钛  氧化锌  木质素  包覆  紫外屏蔽    
Abstract: TiO2/ZnO/lignin full-band ultraviolet shielding material is prepared by coating lignin on the surface of TiO2/ZnO core body.UV-Vis, TG, XRD, FT-IR, TEM and photocatalytic activity test are utilized to characterize the structure and properties of the prepared composite material.It is shown that lignin can effectively reduce the photocatalytic activity of zinc-titanium composites, and the optimal coating amount is 15%.TiO2/ZnO/lignin composite material and a commercially available TiO2/ZnO are respectively added into the sunscreen formula with the same active components to investigate the formulation stability and sunscreen performance of the formula.The results show that the prepared TiO2/ZnO/lignin composite material has better stability and ultraviolet shielding ability.
Key words:  TiO2    ZnO    lignin    coated    ultraviolet shielding
收稿日期:  2020-11-18      修回日期:  2021-08-10           出版日期:  2021-10-20
ZTFLH:  TQ658.2  
基金资助: 江苏省研究生科研与实践创新计划项目(SJCX20-0969);江苏省重点研发计划(BE2018100)
通讯作者:  姚超(1969-),男,博士,教授,主要从事超细功能材料可控制备和表面修饰方面的研究,通讯联系人,yaochao420@163.com。    E-mail:  yaochao420@163.com
作者简介:  季金金(1995-),女,硕士研究生,主要从事紫外屏蔽材料的研究,1491258134@qq.com
引用本文:    
季金金, 左士祥, 刘文杰, 李霞章, 吴凤芹, 姚超. TiO2/ZnO/木质素全波段紫外屏蔽剂的制备及其防晒性能研究[J]. 现代化工, 2021, 41(10): 157-161,167.
JI Jin-jin, ZUO Shi-xiang, LIU Wen-jie, LI Xia-zhang, WU Feng-qin, YAO Chao. Preparation of TiO2/ZnO/lignin full-band ultraviolet shielding agent and study on its sunscreen performance. Modern Chemical Industry, 2021, 41(10): 157-161,167.
链接本文:  
https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2021.10.032  或          https://www.xdhg.com.cn/CN/Y2021/V41/I10/157
[1] Slaper H,Velders G J,Daniel J S,et al.Estimates of ozone depletion and skin cancer incidence to examine the vienna convention achievements[J].Nature,1996,384:256-258.
[2] Xie S,Zhao J,Zhang B,et al.Grapheneoxid etransparent hybird film and its ultraviolet shielding property[J].ACS Appiled Materials & Interfaces,2015,7(32):17558-17564.
[3] Zaccariello G,Back M,Zanello M,et al.Formation and controlled growth of bismuth titanate phases into mesoporous silica nanoparticles:An efficient self-sealing nanosystem for UV filtering in cosmetic formulation[J].ACS Appiled Materials & Interfaces,2017,9:1913-1921.
[4] Huang J Y,Lis H,Ge M Z,et al.Robust superhydrophobic TiO2@fabrics for UV shielding,self-cleaning and oil-water separation[J].Journal of Materials Chemistry A,2015,3(6):2825-2832.
[5] Gondikas A P,Kammer F,Reed R B,et al.Release of TiO2 nanoparticles from sunscreens inton surface waters:A one-year survey at the old danube recreational lake[J].Environmrntal Science & Technology,2014,48(10):5415-5422.
[6] Bartholomey E,House S,Oritiz F.A banlanced approach for formulating sunscreen products using zinc oxide[J].Sofw Journal,2016,142:3.
[7] Lu P J,Cheng W L,Huang S C,et al.Characterizing titanium dioxide and zinc oxide nanoparticles in sunscreen spray[J].International Journal of Cosmetic Science,2015,37(6):620-626.
[8] Sander C S,Chang H,Salzmann S,et al.Photoaging is associated with protein oxidation in human skin in vivo[J].Journal of Investigative Dermatology,2002,118(4):618-625.
[9] Wamer W G,Yina J J,Weia R R.Oxidative damage to nucleic acids photosensitized by titanium dioxide[J].Free Radical Biology and Medicine,1997,23(6):851-858.
[10] Jaroenworaluck A,Sunsaneeyametha W,Kosachan N,et al.Characteristics of silica-coated TiO2 and its UV absorption for sunscreen cosmetic applications[J].Surface and Interface Analysis,2006,38:473-477.
[11] Zhang Y S,Liu Y M,Chen G,et al.Evolution mechanism of alumina nanofilms on rutile TiO2 starting from sodium metaaluminate and the pigmentary properties[J].Powder Technology,2009,192:171-177.
[12] Qian Y,Qiu X Q,Zhu S P.Lignin:A nature-inspired sun blocker for broad-spectrum sunscreens[J].Green Chemistry,2015,17:320-324.
[13] Dean J C,Navotnaya P,Parobek A P,et al.Ultraviolet spectroscopy of fundamental lignin subunits:Guaiacol,4-methylguaiacol,syringol,and 4-methylsyringol[J].The Journal of Chemical Physics,2013,139:144-313.
[14] Li Y Y,Yang D J,Lu S.Encapsulating TiO2 in lignin-based colloidal spheres for high sunscreen performance and weak photocatalytic activity[J].ACS Appiled Materials & Interfaces,2019,7(6):6234-6242.
[15] Pan X J.Kadla J F,Ehara K,et al.Organosolv ethanol lignin from hybrid poplar as a radical scavenger:Relationship between lignin structure,extraction conditions,and antioxidant activity[J].Journal of Agricultural and Food Chemistry,2006,54(16):5806-5813.
[16] Qian Y,Qiu X Q,Zhu S P.Sunscreen performance of lignin from different technical resources and their general synergistic effect with synthetic sunscreens[J].ACS Sustainable Chemistry & Engineering,2016,4:4029-4035.
[17] Romos P G,Flores E,Sanchez L A,et al.Enhanced photoelectrochemical performance and photocatalytic activity of ZnO/TiO2 nanostructures fabricated by an electrostatically modified electrospinning[J].Applied Surface Science,2017,426:844-851.
[18] Faurschou A,Wulf H C.The relation between sun protection factor and amount of sunscreen appiled in vivo[J].British Journal of Dermatology,2007,156(4):716-719.
[19] Yang J S,Liao W P,Wu J J.Morphology and interfacial energetics controls for hierarchical anatase/rutile TiO2 nanostruc tured array for efficient photoelectrochemical water splitting[J].ACS Applied Materials & Interfaces,2013,5(15):7425-7431.
[20] Lu F J,Chu L H,Gau R J.Free radical scavenging properties of lignin[J].Nutrition and Cancer,1998,30:31-38.
[21] Crouvisier-Urion K,Bodart P R,Winckler P,et al.Biobased composite films from chitosan and lignin:Antioxidant activity related to structure and moisture[J].ACS Sustainable Chemistry & Engineering,2016,4(14):6371-6381.
[22] 李振环,白雅丽.TiO2/ZnO复合纳米粒子的制备及其紫外屏蔽性能[J].天津工业大学学报,2017,36(5):49-53.
[1] 杨晓艳, 张金源, 李惠娟, 李榕, 杨东海, 梁坤. 酚醛树脂改性磁载TiO2复合材料的制备及太阳光催化性能的研究[J]. 现代化工, 2021, 41(9): 118-122,128.
[2] 王怡真, 韩洪晶, 吴晓辉, 关金双, 王程昊, 张梅. 固体碱氧化物催化解聚木质素磺酸钙制取酚类化合物的研究[J]. 现代化工, 2021, 41(8): 122-127.
[3] 周灿凯, 朱华丽, 刘俊, 唐焯林, 袁梦明, 陈召勇. 一步合成ZrO2表面包覆F、Al共掺尖晶石锰酸锂及其性能研究[J]. 现代化工, 2021, 41(7): 138-143.
[4] 张铭传, 程嘉霖, 卢锋奇. Na3CrV (PO4)3@C钠离子电池正极材料的制备及其性能研究[J]. 现代化工, 2021, 41(7): 191-196,204.
[5] 苏娜, 鲍晨宇, 高荣杰. MOFs/TiO2纳米复合材料的制备及其应用研究进展[J]. 现代化工, 2021, 41(6): 32-36.
[6] 杨轶博, 张思懿, 王轲, 张舰翔, 周学荣, 李翔, 盛强. 包覆型Hβ和MCM-41复合分子筛作载体制备Pt加氢脱硫催化剂的研究[J]. 现代化工, 2021, 41(6): 101-105.
[7] 崔涵, 罗通, 吕高金, 蒋水星, 李昌涛, 寇光智, 杨桂花. 木质素/天然多糖复合材料的应用研究进展[J]. 现代化工, 2021, 41(5): 35-39.
[8] 铁云飞, 龚福忠, 刘茂举, 廖孙启. TiO2/C/BP复合负极材料的制备及其储锂性能研究[J]. 现代化工, 2021, 41(5): 103-107,113.
[9] 秦海洋, 郑永杰, 田景芝, 刘雯雯, 赵云鹏, 郑禾山, 李硕. Bi2O3-TiO2/污泥活性炭复合催化剂的制备及其可见光催化性能研究[J]. 现代化工, 2021, 41(3): 154-158.
[10] 阿迪力江·居来提, 何明宇, 于欣月, 匡雨梦, 买买提江·依米提, 唐鹏, 王秋伟. 超声波辅助离子液体法提取棉杆木质素及其应用[J]. 现代化工, 2021, 41(10): 96-100.
[11] 樊璐璐, 刘玉香, 范晓军, 袁进. 木质素及其模型化合物生产愈创木酚的研究进展[J]. 现代化工, 2021, 41(1): 49-52.
[12] 周志国. 高电子传输和催化活性PbO2电极的制备及其对苯达松的氧化降解研究[J]. 现代化工, 2021, 41(1): 138-142,148.
[13] 陈垒, 高晓强, 孙东海, 郭宏达. 铌包覆改性对磷酸铁锂材料电化学性能的影响[J]. 现代化工, 2021, 41(1): 165-168.
[14] 徐亚津, 陶宁, 冯宇辰, 吕建华, 刘继东. HY/MCM-41包覆型复合分子筛的合成及其在二甲酚加氢脱甲基反应中的催化性能研究[J]. 现代化工, 2021, 41(1): 179-184,190.
[15] 吴淑新, 刘剑侠, 邵重斌, 周立生, 李旸, 李冬. 复合填料对不饱和聚酯包覆层烧蚀性能的影响[J]. 现代化工, 2020, 40(9): 172-175,179.
No Suggested Reading articles found!
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
京ICP备09035943号-37
版权所有 © 《现代化工》编辑部
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn