Preparation of TiO2/ZnO/lignin full-band ultraviolet shielding agent and study on its sunscreen performance
JI Jin-jin1, ZUO Shi-xiang1, LIU Wen-jie2, LI Xia-zhang1, WU Feng-qin1, YAO Chao1
1. School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China; 2. Xuyi R&D Center of Attapulgite Applied Technology, Changzhou University, Xuyi 211700, China
Abstract: TiO2/ZnO/lignin full-band ultraviolet shielding material is prepared by coating lignin on the surface of TiO2/ZnO core body.UV-Vis, TG, XRD, FT-IR, TEM and photocatalytic activity test are utilized to characterize the structure and properties of the prepared composite material.It is shown that lignin can effectively reduce the photocatalytic activity of zinc-titanium composites, and the optimal coating amount is 15%.TiO2/ZnO/lignin composite material and a commercially available TiO2/ZnO are respectively added into the sunscreen formula with the same active components to investigate the formulation stability and sunscreen performance of the formula.The results show that the prepared TiO2/ZnO/lignin composite material has better stability and ultraviolet shielding ability.
季金金, 左士祥, 刘文杰, 李霞章, 吴凤芹, 姚超. TiO2/ZnO/木质素全波段紫外屏蔽剂的制备及其防晒性能研究[J]. 现代化工, 2021, 41(10): 157-161,167.
JI Jin-jin, ZUO Shi-xiang, LIU Wen-jie, LI Xia-zhang, WU Feng-qin, YAO Chao. Preparation of TiO2/ZnO/lignin full-band ultraviolet shielding agent and study on its sunscreen performance. Modern Chemical Industry, 2021, 41(10): 157-161,167.
[1] Slaper H,Velders G J,Daniel J S,et al.Estimates of ozone depletion and skin cancer incidence to examine the vienna convention achievements[J].Nature,1996,384:256-258. [2] Xie S,Zhao J,Zhang B,et al.Grapheneoxid etransparent hybird film and its ultraviolet shielding property[J].ACS Appiled Materials & Interfaces,2015,7(32):17558-17564. [3] Zaccariello G,Back M,Zanello M,et al.Formation and controlled growth of bismuth titanate phases into mesoporous silica nanoparticles:An efficient self-sealing nanosystem for UV filtering in cosmetic formulation[J].ACS Appiled Materials & Interfaces,2017,9:1913-1921. [4] Huang J Y,Lis H,Ge M Z,et al.Robust superhydrophobic TiO2@fabrics for UV shielding,self-cleaning and oil-water separation[J].Journal of Materials Chemistry A,2015,3(6):2825-2832. [5] Gondikas A P,Kammer F,Reed R B,et al.Release of TiO2 nanoparticles from sunscreens inton surface waters:A one-year survey at the old danube recreational lake[J].Environmrntal Science & Technology,2014,48(10):5415-5422. [6] Bartholomey E,House S,Oritiz F.A banlanced approach for formulating sunscreen products using zinc oxide[J].Sofw Journal,2016,142:3. [7] Lu P J,Cheng W L,Huang S C,et al.Characterizing titanium dioxide and zinc oxide nanoparticles in sunscreen spray[J].International Journal of Cosmetic Science,2015,37(6):620-626. [8] Sander C S,Chang H,Salzmann S,et al.Photoaging is associated with protein oxidation in human skin in vivo[J].Journal of Investigative Dermatology,2002,118(4):618-625. [9] Wamer W G,Yina J J,Weia R R.Oxidative damage to nucleic acids photosensitized by titanium dioxide[J].Free Radical Biology and Medicine,1997,23(6):851-858. [10] Jaroenworaluck A,Sunsaneeyametha W,Kosachan N,et al.Characteristics of silica-coated TiO2 and its UV absorption for sunscreen cosmetic applications[J].Surface and Interface Analysis,2006,38:473-477. [11] Zhang Y S,Liu Y M,Chen G,et al.Evolution mechanism of alumina nanofilms on rutile TiO2 starting from sodium metaaluminate and the pigmentary properties[J].Powder Technology,2009,192:171-177. [12] Qian Y,Qiu X Q,Zhu S P.Lignin:A nature-inspired sun blocker for broad-spectrum sunscreens[J].Green Chemistry,2015,17:320-324. [13] Dean J C,Navotnaya P,Parobek A P,et al.Ultraviolet spectroscopy of fundamental lignin subunits:Guaiacol,4-methylguaiacol,syringol,and 4-methylsyringol[J].The Journal of Chemical Physics,2013,139:144-313. [14] Li Y Y,Yang D J,Lu S.Encapsulating TiO2 in lignin-based colloidal spheres for high sunscreen performance and weak photocatalytic activity[J].ACS Appiled Materials & Interfaces,2019,7(6):6234-6242. [15] Pan X J.Kadla J F,Ehara K,et al.Organosolv ethanol lignin from hybrid poplar as a radical scavenger:Relationship between lignin structure,extraction conditions,and antioxidant activity[J].Journal of Agricultural and Food Chemistry,2006,54(16):5806-5813. [16] Qian Y,Qiu X Q,Zhu S P.Sunscreen performance of lignin from different technical resources and their general synergistic effect with synthetic sunscreens[J].ACS Sustainable Chemistry & Engineering,2016,4:4029-4035. [17] Romos P G,Flores E,Sanchez L A,et al.Enhanced photoelectrochemical performance and photocatalytic activity of ZnO/TiO2 nanostructures fabricated by an electrostatically modified electrospinning[J].Applied Surface Science,2017,426:844-851. [18] Faurschou A,Wulf H C.The relation between sun protection factor and amount of sunscreen appiled in vivo[J].British Journal of Dermatology,2007,156(4):716-719. [19] Yang J S,Liao W P,Wu J J.Morphology and interfacial energetics controls for hierarchical anatase/rutile TiO2 nanostruc tured array for efficient photoelectrochemical water splitting[J].ACS Applied Materials & Interfaces,2013,5(15):7425-7431. [20] Lu F J,Chu L H,Gau R J.Free radical scavenging properties of lignin[J].Nutrition and Cancer,1998,30:31-38. [21] Crouvisier-Urion K,Bodart P R,Winckler P,et al.Biobased composite films from chitosan and lignin:Antioxidant activity related to structure and moisture[J].ACS Sustainable Chemistry & Engineering,2016,4(14):6371-6381. [22] 李振环,白雅丽.TiO2/ZnO复合纳米粒子的制备及其紫外屏蔽性能[J].天津工业大学学报,2017,36(5):49-53.