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现代化工  2021, Vol. 41 Issue (9): 38-42    DOI: 10.16606/j.cnki.issn0253-4320.2021.09.008
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光催化涂层/薄膜材料的制备工艺及其结构调控研究进展
李大玉, 周逸文, 梅昕, 张超
扬州大学机械工程学院, 江苏 扬州 225127
Progress in preparation and structure control of photocatalytic coating/film materials
LI Da-yu, ZHOU Yi-wen, MEI Xin, ZHANG Chao
School of Mechanical Engineering, Yangzhou University, Yangzhou 225127, China
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摘要 光催化涂层/薄膜的材料体系包括氧化物、硫化物、氮化物、磷化物及其表面改性和新兴的材料体系。光催化涂层/薄膜的制备工艺主要包括液相法、气相法和电化学法等,指出各工艺利弊和制备工艺对薄膜光催化性能的影响。介绍了光催化涂层/薄膜材料的某些特殊微纳结构(核壳结构及中空结构、介孔结构、碳包覆结构)及其结构调控的方法;总结展望了光催化涂层/薄膜材料在制备、结构调控及其应用方面存在的问题及未来的发展趋势。通过对制备工艺和材料体系的研究设计,提高光利用率,实现光催化薄膜的结构和性能等方面的调控,未来光催化涂层/薄膜材料应向着可持续的产业化方向不断发展。
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李大玉
周逸文
梅昕
张超
关键词:  光催化  薄膜材料  微纳结构  结构调控  抗菌性  亲水性    
Abstract: This paper introduces the material systems of photocatalytic coatings/films,including oxides,sulfides,nitrides,phosphides and its surface modification,and emerging material system.The preparation processes for photocatalytic coatings/films include liquid phase method,gas phase method and electrochemical method.And it points out the pros and cons of each process,and describes the influence of preparation process on the photocatalytic performance of the film.Some special micro-nano structures (core-shell and hollow structures,mesoporous structures,carbon-coated structures) of photocatalytic coating/film materials and their structural control methods are reviewed.The existing problems and future development trend for photocatalytic coating/thin film materials in preparation process,structure control and application are summarized and prospected.Through the study and design on the preparation process and material system,the light utilization rate is improved,and the structure and performance of the photocatalytic film are controlled,and controllable synthesis can also be achieved.It is predicted that photocatalytic coating/film materials will develop towards sustainable industrialization in the future.
Key words:  photocatalysis    thin film materials    micro-nano structure    structural control    antibacterial property    hydrophilicity
收稿日期:  2020-12-16      修回日期:  2021-06-29           出版日期:  2021-09-20
ZTFLH:  TG147  
基金资助: 国家自然科学基金项目(51602279);扬州大学"高端人才"项目(2018);江苏省青蓝工程项目(2020);扬州大学大学生创新创业训练计划项目(2019)
通讯作者:  张超(1981-),男,博士,教授,研究方向为光催化材料,通讯联系人,zhangc@yzu.edu.cn    E-mail:  zhangc@yzu.edu.cn
作者简介:  李大玉(1983-),男,博士,副教授,研究方向为光催化材料
引用本文:    
李大玉, 周逸文, 梅昕, 张超. 光催化涂层/薄膜材料的制备工艺及其结构调控研究进展[J]. 现代化工, 2021, 41(9): 38-42.
LI Da-yu, ZHOU Yi-wen, MEI Xin, ZHANG Chao. Progress in preparation and structure control of photocatalytic coating/film materials. Modern Chemical Industry, 2021, 41(9): 38-42.
链接本文:  
https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2021.09.008  或          https://www.xdhg.com.cn/CN/Y2021/V41/I9/38
[1] 张一兵,吴文菲.铁掺杂改性二氧化钛的制备及其光催化处理废水[J].水处理技术,2020,46(8):60-63.
[2] 江耀华,沈鸿烈,高凯.氮气流量对磁控溅射C掺杂TiO2薄膜光学性能的影响[J].半导体光电,2020,41(3):351-356.
[3] 徐敬博,吴音,张思源,等.稀土元素掺杂对TiO2薄膜结构和光催化性能的影响[J].陶瓷学报,2019,40(1):14-17.
[4] Dhanraj C,Ravichandran K,Kavitha P,et al.Excess free-electrons activated photocatalytic ability of ZnO films through co-doping of higher oxidation state transition metals Ta and Mo[J].Inorganic Chemistry Communications,2020,118:107986.
[5] 陈海洋,何菲,张旭海,等.钯氮共掺杂TiO2薄膜的光催化还原性能[J].材料研究学报,2017,31(4):255-260.
[6] Li W,Xie L,Zhou L,et al.A systemic study on Gd,Fe and N co-doped TiO2 nanomaterials for enhanced photocatalytic activity under visible light irradiation[J].Ceramics International,2020,46(15):24744-24752.
[7] 马立云,金良茂,汤永康,等.TiO2/TiO2-SiO2双层复合薄膜制备及折射率调控[J].硅酸盐学报,2020,48(4):470-476.
[8] 黄梁,周菊枚.TiO2/氧化石墨烯光催化膜灭活船舶压载水中微绿球藻的有效性[J].船舶工程,2019,41(6):115-118.
[9] Yanfen W,Miao Z,Jie L,et al.Construction of Ag@AgCl decorated TiO2 nanorod array film with optimized photoelectrochemical and photocatalytic performance[J].Applied Surface Science,2019,476:84-93.
[10] Hamid K H,Somaiyeh A,Nader R,et al.The role of thermal annealing in controlling morpho logy,crystal structure and adherence of dip coated TiO2 film on glass and its photocatalytic activity[J].Materials Science in Semiconductor Processing,2018,85:24-32.
[11] Mahdiyeh E Z,Mohsen B.Influence of deposition parameters on surface morphology and application of CuInS2 thin films in solar cell and photocatalysis[J].International Journal of Hydrogen Energy,2020,45(32):16169-16182.
[12] Liu J,Lv Y,Zhang W,et al.The rutile phase of TiO2/graphene films:Sol-gel method,phase transition,photocatalytic properties[J].Integrated Ferroelectrics,2020,207(1):108-117.
[13] 薛丹林,黄金亮,宁向梅,等.水热工艺对TiO2薄膜形貌结构及光学性能的影响[J].现代化工,2018,38(7):98-102.
[14] 王朝勇,黄晓亚,魏瑞朋,等.能量过滤磁控溅射技术制备Cu2O-TiO2复合薄膜及其光催化性能[J].表面技术,2020,49(6):132-137.
[15] Sushanta S,Smita M,Sanjay N.Methods and fabrication techniques of superhydrophobic surfaces[M].Aditya K,Debasis N.Superhydrophobic Polymer Coatings.Elsevier:Elsevier Inc,2019:43-75.
[16] Benelmekki M,Erbe A.Nanostructured Thin films-background,preparation and relation to the technological revolution of the 21st century[J].Frontiers of Nanoscience,2019,14:1-34.
[17] Zhang Q,Li C.Effects of water-to-methanol ratio on the structural,optical and photocatalytic properties of titanium dioxide thin films prepared by mist chemical vapor deposition[J].Catalysis Today,2020,358:172-176.
[18] 成先雄,陈于梁,孔张亮,等.基于阳极氧化法的TiO2纳米管制备及生成过程分析[J].化工进展,2020,39(3):1095-1100.
[19] Kozlovskiy A L,Zdorovets M V.The study of the structural characteristics and catalytic activity of Co/CoCo2O4 nanowires[J].Composites Part B:Engineering,2020,191:107968.
[20] 张小芳,李瑞,胡颖媛,等.电化学法合成BiOCl薄膜及其光催化活性研究[J].人工晶体学报,2016,45(10):2364-2368.
[21] Carpenter E E,Sims J A,Wienmann J A,et al.Magnetic properties of iron and iron platinum alloys synthesized via microemulsion techniques[J].Journal of Applied Physics,2000,87(9):5615.
[22] 都奎山,杨兵权,宋恺,等.SiO2空心球的制备与表面形貌调控[J].化工新型材料,2019,47(6):164-167.
[23] Liu Y,Zhang,Luo L,et al.TiO2/Cu2O core/ultrathin shell nanorods as efficient and stable photocatalysts for water reductionsheng[J].Angewandte Chemie:International ed in English,2015,54(50):15260-15265.
[24] Zhu J,Zhang S,Weng G J,et al.The morphology regulation and plasmonic spectral properties of Au@AuAg yolk-shell nanorods with controlled interior gap[J].Spectrochimica acta Part A:Molecular and biomolecular spectroscopy,2020,236:118343.
[25] 丁晓博,吴华龙,莫文彬,等.多壳层中空材料的制备及其应用[J].科学通报,2019,64(34):3526-3545.
[26] Mao D,Wan J,Wang J,et al.Sequential templating approach:A groundbreaking strategy to create hollow multishelled structures[J].Advanced Materials,2019,31(38):1802874.
[27] Dong Z,Lai X,Halpert J E,et al.Accurate control of multishelled ZnO hollow microspheres for dye-sensitized solar cells with high efficiency[J].Advanced Materials,2012,24(8):1046-1049.
[28] Xu J,Zhang H,Wang R,et al.Delicate control of multishelled Zn-Mn-O hollow microspheres as a high-performance anode for lithium-ion batteries[J].Langmuir,2018,34(4):1242-1248.
[29] 宋坤,佟潇,王文波,等.介孔TiO2空心微球的制备及其光催化性能[J].印染助剂,2019,36(7):17-21.
[30] Sun L,Zhuang Y,Yuan Y,et al.Nitrogen-doped carbon-coated CuO-In2O3 p-n heterojunction for remarkable photocatalytic hydrogen evolution[J].Advanced Energy Materials,2019,9(48):1902839.
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