Please wait a minute...
 
最新公告: 重要提醒:骗子冒充编辑部要求加作者微信,谨防上当!   关于暑假、寒假期间版面费发票及期刊样刊延迟邮寄的通知    
现代化工  2021, Vol. 41 Issue (6): 81-85,89    DOI: 10.16606/j.cnki.issn0253-4320.2021.06.017
  技术进展 本期目录 | 过刊浏览 | 高级检索 |
MEA生产工艺及关键材料研究进展
郭文林, 李伟斌, 姚根有, 潘登峰, 朱浩, 尹进
阳泉煤业集团设计研发中心有限公司, 山西 太原 030024
Progress on critical materials and production process for membrane electrode assembly
GUO Wen-lin, LI Wei-bin, YAO Gen-you, PAN Deng-feng, ZHU Hao, YIN Jin
Yangquan Coal Industry Group Design and R&D Center Co., Ltd., Taiyuan 030024, China
下载:  PDF (1777KB) 
输出:  BibTeX | EndNote (RIS)      
摘要 介绍了膜电极的主要生产工艺以及近几年膜电极的关键材料质子交换膜、催化材料的最新研究。比较了各种改性膜、无氟膜、复合膜的电导率数据,不同种类改性膜、复合膜中,均有电导率超过Nafion 117指标的材料,其中应用于HT-PEM的聚苯并咪唑离子交换膜的部分参数已经达到了市场上最好的Gore膜指标。催化剂占燃料电池生产成本的30%~40%,当前很多研究中的催化材料的铂负载量已经低于DOE 2020年的相应指标,其中一种Pt-Ni/BNCs纳米球结构催化剂质量活性达到了3.52 A/mg,是当前Pt/C催化剂性能的16.8倍,在经过50 000次的电位扫描循环后,该催化剂的活性衰减小于1.5%。介绍了各种催化剂负载方法,其中超声波喷雾法的Pt负载量可低至0.015 mg/cm2。随着膜材料和催化材料研究的不断进步,膜电极的生产成本将会越来越低。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
郭文林
李伟斌
姚根有
潘登峰
朱浩
尹进
关键词:  燃料电池  膜电极  质子交换膜  电导率  催化剂    
Abstract: Main production processes for membrane electrode assembly (MEA) are introduced,and latest research on key materials of MEA in recent years is reviewed.The conductivity data of various modified membrane,fluorine-free membrane and composite membrane are compared.There are many membranes among modified membrane and composite membrane,which have better conductivity than Nafion 117.Some parameters of polybenzimidazole ion exchange membrane applied to HT-PEM have reached the best Gore membrane index in the market.Catalyst accounts for 30%-40% of the production cost of fuel cell.Currently,the platinum loading amount of catalyst materials in many researching materials has been lower than the corresponding index of DOE in 2020.For example,the mass activity of PtNi/BNCs nan-structure catalyst reaches 3.52 A·mg-1,which is 16.8 times that of Pt/C catalyst.After 50 000 potential scanning cycles,the activity decline of the catalyst is less than 1.5%.In addition,various catalyst loading methods are introduced,in which Pt loading amount by ultrasonic spray method can be as low as 0.015 mg·cm-2.With the development of membrane materials and catalytic materials,the production cost of membrane electrode assembly will be lower and lower.
Key words:  fuel cell    membrane electrode assembly    proton exchange membrane    conductivity    catalyst
收稿日期:  2020-07-07      修回日期:  2021-04-07          
ZTFLH:  Q643.36  
通讯作者:  郭文林(1983-),男,硕士,工程师,研究方向为化学工艺,通讯联系人,amandharmo12345@126.com。    E-mail:  amandharmo12345@126.com
引用本文:    
郭文林, 李伟斌, 姚根有, 潘登峰, 朱浩, 尹进. MEA生产工艺及关键材料研究进展[J]. 现代化工, 2021, 41(6): 81-85,89.
GUO Wen-lin, LI Wei-bin, YAO Gen-you, PAN Deng-feng, ZHU Hao, YIN Jin. Progress on critical materials and production process for membrane electrode assembly. Modern Chemical Industry, 2021, 41(6): 81-85,89.
链接本文:  
https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2021.06.017  或          https://www.xdhg.com.cn/CN/Y2021/V41/I6/81
[1] Ding Xiaoyu,Sima Didari,Thomas F Fuller,et al.Membrane electrode assembly fabrication process for directly coating catalyzed gas diffusion layers[J].Journal of the Electrochemical Society,2012,159(6):746-753.
[2] Wang Yun,Daniela Fernanda Ruiz Diaz,Ken S Chen,et al.Materials,technological status,and fundamentals of PEM fuel cells-A review[J].Materials Today,2020,32:178-203.
[3] Joachim Schaefer,Esslingen,Matin Schroer,et al.Process for manufacturing a membrane electrode assembly:US,6823584[P].2004-04-30.
[4] Kim M,Lee J,Lee W,et al.Device and method for manufacturing membrane-electrode assembly of fuel cell:US,10673086[P].2020-06-02.
[5] Sabuj Chandr Sutradhar,Faiz Ahmed,Taewook Ryu,et al.A novel synthesis approach to partially fluorinated sulfonimide based poly (arylene ether sulfone) for proton exchange membrane[J].International Journal of Hydrogen Energy,2019,44(22):11321-11331.
[6] Chen Xialin,Lü Haixia,Lin Qilang,et al.Partially fluorinated poly(arylene ether)s bearing long alkyl sulfonate side chains for stable and highly conductive proton exchange membranes[J].Journal of Membrane Science,2018,549:12-22.
[7] Ece Arici,Begum Yarar Kaplan,Ahmet Musap Mert,et al.An effective electrocatalyst based on platinum nanoparticles supported with graphene nanoplatelets and carbon black hybrid for PEM fuel cells[J].International Journal of Hydrogen Energy,2019,44(27):14175-14183.
[8] 刘振超.基于磺化聚芳醚酮的高性能交联型质子交换膜的制备及性能研究[D].长春:吉林大学,2019.
[9] 徐丽爽.复合的磺化聚芳醚酮砜类质子交换膜的制备及性能的研究[D].长春:长春工业大学,2016.
[10] Zhang Zhenguo,Ren Jiahui,Xu Jingmei,et al.Adjust the arrangement of imidazole on the metal-organic framework to obtain hybrid proton exchange membrane with long-term stable high proton conductivity[J].Journal of Membrane Science,2020,607:118194.
[11] 随东辉.基于MOFs质子交换膜的制备及其质子传导性能[D].北京:北京化工大学,2016.
[12] Tonny Søndergaard,Lars Nilausen Cleemann,Hans Becker,et al.Long-term durability of HT-PEM fuel cells based on thermally crosslinked polybenzimidazole[J].Journal of Membrane Science,2017,535:122-131.
[13] 王鹏.基于聚苯并咪唑一自具微孔聚合物的高温质子交换膜的制备及性能研究[D].长春:吉林大学,2019.
[14] Amrit Chandan,Mariska Hattenberger,Ahmad El-kharouf,et al.High temperature (HT) polymer electrolyte membrane fuel cells (PEMFC):A review[J].Journal of Power Sources,2013,231:264-278.
[15] Muhammad A Imran,TiantianLi,XuemeiWu,et al.Sulfonated Polybenzimidazole/amine functionalized titanium dioxide (sPBI/AFT) composite electrolyte membranes for high temperature proton exchange membrane fuel cells usage[J].Chinese Journal of Chemical Engineering,2020,28(9):2425-2437.
[16] 赵伟辰,徐鑫,白慧娟,等,自交联聚乙烯亚胺一聚飒高温质子交换膜研究[J].化学学报,2020,(1):69-74.
[17] Ooi Y X,Ya K Z,Maegaw K,et al.CHS-WSiA doped hexafluoropropylidene-containing polybenzimidazole composite membranes for medium temperature dry fuel cells[J].International Journal of Hydrogen Energy,2019,44(60):32201-32209.
[18] Saadia Hanif,Xuan Shi,Naseem Iqbala,et al.ZIF derived PtNiCo/NC cathode catalyst for proton exchange membrane fuel cell[J].Applied Catalysis B:Environmental,2019,258:117947.
[19] Mohanraju K,Cindrella L.One-pot surfactant-free synthesis of high surface area ternary alloys,PtMCo/C (M=Cr,Mn,Fe,Ni,Cu) with enhanced electrocatalytic activity and durability for PEM fuel cell application[J].International Journal of Hydrogen Energy,2016,41(22):9320-9331.
[20] Lale IşikelŞ anli,Vildan Bayram,Sajjad Ghobadi,et al.Engineered catalyst layer design with graphene-carbon black hybrid supports for enhanced platinum utilization in PEM fuel cell[J].International Journal of Hydrogen Energy,2017,42(2):1085-1092.
[21] Yao Dongmei,Zhang Weiqi,Ma Qiang,et al.Achieving high Pt utilization and superior performance of high temperature polymer electrolyte membrane fuel cell by employing low-Pt-content catalyst and microporous layer free electrode design[J].Journal of Power Sources,2019,426:124-133.
[22] Snezana M Brkovic,Milica P Marceta Kaninski,Petar Z Lausevic,et al.Non-stoichiometric tungsten-carbide-oxide-supported Pt-Ru anode catalysts for PEM fuel cells-From basic electrochemistry to fuel cell performance[J].International Journal of Hydrogen Energy,2020,45(2718):13929-13938.
[23] Martin S,Jensen J O,Li Q,et al.Feasibility of ultra-low Pt loading electrodes for high temperature proton exchange membrane fuel cells based in phosphoric acid-doped membrane[J].International Journal of Hydrogen Energy,2019,44(52):28273-2828.
[24] Martin S,Jensen J O,Li Q,et al.Feasibility of ultra-low Pt loading electrodes for high temperature proton exchange membrane fuel cells based in phosphoric acid-doped membrane[J].International Journal of Hydrogen Energy,2019,44(52):28273-28282.
[25] Chung Sunki,Kahyun Ham,Kang Sinwoo,et al.Enhanced corrosion tolerance and highly durable ORR activity by low Pt electrocatalyst on unique pore structured CNF in PEM fuel cell[J].Electrochimica Acta,2020,348:136346.
[26] Reza Alipour Moghadam Esfahani,Luis Miguel River Gavidia,Gonzalo García,et al.Highly active platinum supported on Mo-doped titanium nanotubes suboxide (Pt/TNTS-Mo) electrocatalyst for oxygen reduction reaction in PEMFC[J].Renewable Energy,2018,120:209-219.
[27] Wang Meng,Chen Ming,Yang Zhaoyi,et al.High-performance and durable cathode catalyst layer with hydrophobic C@PTFE particles for low-Pt loading membrane assembly electrode of PEMFC[J].Energy Conversion and Management,2019,191:132-140.
[28] Heather M Barkholtz,Lina Chong,Zachary B Kaiser,et al.Enhanced performance of non-PGM catalysts in air operated PEM-fuel cells[J].International Journal of Hydrogen Energy,2016,41(47):22598-22604.
[29] Sadia Kabir,Samantha Medina,Guanxiong Wang,et al.Improving the bulk gas transport of Fe-N-C platinum group metal-free nanofiber electrodes via electrospinning for fuel cell applications[J].Nano Energy,2020,73:104791.
[30] Avijit Ghosh,Biswajit Mandal,Sunil Baran Kuila.Development of functionalized graphene supported highly durable Pt-free Bi-metallic electrocatalysts for PEMFC[J].Materials Today,2019,18:660-670.
[1] 林代峰, 张臻, 罗永晋, 钱庆荣, 陈庆华. 二氧化碳加氢制甲醇催化剂研究进展[J]. 现代化工, 2021, 41(6): 11-16.
[2] 陈小根, 张茹杰, 李书昊, 沈伯雄. 用于CO氧化的单原子催化剂研究进展[J]. 现代化工, 2021, 41(6): 70-75.
[3] 戴豪波, 杜凯敏, 郑渭建, 刘春红, 胡晨晖, 卓佐西, 蒋楠. NH3-SCR脱硝催化剂研究进展[J]. 现代化工, 2021, 41(5): 40-44,48.
[4] 赵中昆, 许志志, 陈鑫. 单原子催化剂在电催化还原领域的研究进展[J]. 现代化工, 2021, 41(5): 45-48.
[5] 杨阳, 张胜中, 王红涛. 碱性电解水制氢关键材料研究进展[J]. 现代化工, 2021, 41(5): 78-82,87.
[6] 吴芹, 石泉, 宋淑芬, 黎汉生, 史大昕, 赵芸, 矫庆泽. 磺酸树脂催化合成对叔丁基苯甲酸甲酯的研究[J]. 现代化工, 2021, 41(5): 98-102.
[7] 何玲, 孙福海, 徐琪鹏. 电沉积法从废弃FCC催化剂中回收稀土元素的研究[J]. 现代化工, 2021, 41(5): 108-113.
[8] 刘建武, 严生虎, 张跃. 微波促进卤素交换氟化反应合成邻氟苯腈的研究[J]. 现代化工, 2021, 41(5): 148-152.
[9] 王玉春, 刘赵荣, 谭超, 孙鸿, 李忠, 薛雨佳. 铜源阴离子对CuY催化剂性能的影响[J]. 现代化工, 2021, 41(5): 163-167.
[10] 于广欣, 纪钦洪, 刘强, 肖钢, 熊亮. 氢能及燃料电池产业瓶颈分析与思考[J]. 现代化工, 2021, 41(4): 1-4,10.
[11] 苏暐光, 孔磊. Cu基催化剂上二氧化碳加氢合成甲醇的研究进展[J]. 现代化工, 2021, 41(4): 26-29.
[12] 于祺, 李瑞峰, 田宏宇, 吴显军. 浆态床渣油加氢油溶性催化剂研究进展[J]. 现代化工, 2021, 41(4): 34-37.
[13] 赵文祥, 杨双霞, 陈雷, 孙来芝, 谢新苹, 伊晓路, 司洪宇, 于萌萌, 华栋梁. 生物质热化学催化转化制富氢合成气研究进展[J]. 现代化工, 2021, 41(4): 38-42.
[14] 张甄, 秦绍东, 何若南, 李加波, 邢爱华. 合成气直接制备低碳烯烃催化剂研究进展[J]. 现代化工, 2021, 41(4): 58-62.
[15] 张鹏, 贾媛媛, 唐中华, 刘兴誉, 刘军强, 刘光利, 巫树锋. 钒钛系脱硝催化剂抗SO2和H2O中毒性能研究进展[J]. 现代化工, 2021, 41(4): 67-71.
No Suggested Reading articles found!
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
京ICP备09035943号-37
版权所有 © 《现代化工》编辑部
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn