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现代化工  2021, Vol. 41 Issue (3): 202-206,210    DOI: 10.16606/j.cnki.issn0253-4320.2021.03.040
  科研与开发 本期目录 | 过刊浏览 | 高级检索 |
异质结构Co3O4@CoMoO4阵列的制备与析氧性能研究
孙志裕, 黄小琴, 刘国强
合肥工业大学化学与化工学院, 安徽 合肥 230009
Preparation of heterostructured Co3O4@CoMoO4 arrays and their oxygen evolution property
SUN Zhi-yu, HUANG Xiao-qin, LIU Guo-qiang
School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China
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摘要 采用简单的两步水热法和退火处理在泡沫镍上制备出异质结构Co3O4@CoMoO4阵列(Co3O4@CoMoO4/NF)。结果表明,Co3O4@CoMoO4/NF比Co3O4/NF拥有更大的活性面积和更优异的电催化析氧性能,主要是由于其3D异质结构和协同作用。Co3O4@CoMoO4纳米阵列在1 mol/L KOH溶液中和50 mA/cm2电流密度下的析氧过电位仅为253 mV,塔菲尔斜率为59 mV/dec,并且表现出优异的析氧稳定性。
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孙志裕
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刘国强
关键词:  复合材料  Co3O4@CoMoO4  异质结构  析氧反应    
Abstract: A simple two-step hydrothermal method and annealing process are used to prepare heterostructured Co3O4@CoMoO4 arrays on nickel foam.Thanks to its 3D heterostructure and synergy effect,Co3O4@CoMoO4 has a higher specific surface area and better electrocatalytic oxygen evolution performance than Co3O4/NF.The as-prepared Co3O4@CoMoO4/NF presents excellent oxygen evolution stability,achieving a low overpotential of 253 mV at 50 mA cm-2 with a Tafel slope of 64 mV dec-1 in 1 M KOH solution.Therefore it has good application prospects as catalysts for oxygen evolution reaction.
Key words:  hybrid materials    Co3O4@CoMoO4    heterostructure    oxygen evolution reaction
收稿日期:  2020-04-30      修回日期:  2021-01-16          
ZTFLH:  TM912.9  
通讯作者:  刘国强(1986-),男,博士后,讲师,研究方向为纳米催化,通讯联系人,gqliu@issp.ac.cn。    E-mail:  gqliu@issp.ac.cn
作者简介:  孙志裕(1996-),男,硕士研究生,研究方向为纳米材料电催化,1042418421@qq.com
引用本文:    
孙志裕, 黄小琴, 刘国强. 异质结构Co3O4@CoMoO4阵列的制备与析氧性能研究[J]. 现代化工, 2021, 41(3): 202-206,210.
SUN Zhi-yu, HUANG Xiao-qin, LIU Guo-qiang. Preparation of heterostructured Co3O4@CoMoO4 arrays and their oxygen evolution property. Modern Chemical Industry, 2021, 41(3): 202-206,210.
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https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2021.03.040  或          https://www.xdhg.com.cn/CN/Y2021/V41/I3/202
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