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现代化工  2021, Vol. 41 Issue (3): 145-148    DOI: 10.16606/j.cnki.issn0253-4320.2021.03.029
  科研与开发 本期目录 | 过刊浏览 | 高级检索 |
Mn(Ⅱ)配位聚合物催化t-BuOOH氧化苄基仲醇的研究
刘建奇1,2, 范伟伟2, 熊航行2, 刘生鹏1
1. 武汉工程大学化工与制药学院, 湖北 武汉 430205;
2. 荆楚理工学院化工与药学院, 湖北 荆门 448000
Oxidation of benzyl secondary alcohols by t-BuOOH over a Mn(Ⅱ) coordination polymer
LIU Jian-qi1,2, FAN Wei-wei2, XIONG Hang-xing2, LIU Sheng-peng1
1. School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205, China;
2. College of Chemical Engineering and Pharmacy, Jingchu University of Technology, Jingmen 448000, China
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摘要 采用4'-(4-吡啶基)-2,2':6',2″-三联吡啶和MnCl2制备出线型Mn (Ⅱ)配位聚合物,并将这类基于三齿配体形成的配位聚合物用于催化t-BuOOH氧化苄基仲醇。结果表明,该催化体系中乙腈为最适宜溶剂;催化量的碱对反应有显著促进作用。该方法可以用于氧化不同类型的苄基仲醇,底物范围广;80℃下反应3~5 h,13种具有不同结构的底物均获得较高转化率(95%~99%)和收率。催化剂重复利用4次后仍保持较高的催化效率。
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刘建奇
范伟伟
熊航行
刘生鹏
关键词:  配位聚合物  催化  氧化反应  叔丁基过氧化氢  苄基仲醇    
Abstract: Linear Mn(Ⅱ) coordination polymer is prepared from 4'-(4-pyridyl)-2,2':6',2″-terpyridine and MnCl2,and used to catalyze the oxidation of benzyl secondary alcohols by t-BuOOH.Results show that acetonitrile is the most suitable solvent in the catalytic system;Catalytic amount of base can significantly promote the reaction.This method can be used to oxidize different types of benzyl secondary alcohols with a wide range of substrates.After reaction has performed at 80℃ for 3-5 hours,excellent conversions (95%-99%) and high yields of 13 substrates with different structures are obtained.The catalyst still remains a high catalytic efficiency after 4 times of reuses.
Key words:  coordination polymer    catalysis    oxidation    tert-butyl hydrogen peroxide    benzyl secondary alcohols
收稿日期:  2020-11-17      修回日期:  2021-01-06          
ZTFLH:  TQ032  
基金资助: 湖北省优秀中青年科技创新团队计划项目(T2020023);荆门市重点科技计划项目(2020ZDYF002)
通讯作者:  熊航行(1969-),男,本科,教授,研究方向为精细化工及工业催化,通讯联系人,xhx168168@126.com。    E-mail:  xhx168168@126.com
作者简介:  刘建奇(1993-),男,硕士生,研究方向为催化合成,18848966165@163.com
引用本文:    
刘建奇, 范伟伟, 熊航行, 刘生鹏. Mn(Ⅱ)配位聚合物催化t-BuOOH氧化苄基仲醇的研究[J]. 现代化工, 2021, 41(3): 145-148.
LIU Jian-qi, FAN Wei-wei, XIONG Hang-xing, LIU Sheng-peng. Oxidation of benzyl secondary alcohols by t-BuOOH over a Mn(Ⅱ) coordination polymer. Modern Chemical Industry, 2021, 41(3): 145-148.
链接本文:  
https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2021.03.029  或          https://www.xdhg.com.cn/CN/Y2021/V41/I3/145
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