Research progress on application of geopolymers in environmental treatment
WANG Chen-xi1,2, WU Wen-tong1,2, ZHENG Lei1,2, YANG Fei-hua3,4, CANG Da-qiang5, ZHANG Ling-ling1,2
1. Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants, Beijing 100083, China; 2. School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China; 3. Beijing Building Materials Academy of Sciences Research Co., Ltd., Beijing 100041, China; 4. State Key Laboratory of Solid Waste Utilization and Energy Saving Building Materials, Beijing 100041, China; 5. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Abstract: Characteristics of geopolymers are described from three aspects such as three-dimensional network structure,ion exchange,and pore features.Applications of geopolymers in the field of environmental treatment are reviewed in the light of these features.The existing problems in the application of geopolymers are analysed and the prospects are proposed.
王晨希, 吴文瞳, 郑蕾, 杨飞华, 苍大强, 张玲玲. 地质聚合物应用于环境治理领域的研究进展[J]. 现代化工, 2021, 41(3): 63-67.
WANG Chen-xi, WU Wen-tong, ZHENG Lei, YANG Fei-hua, CANG Da-qiang, ZHANG Ling-ling. Research progress on application of geopolymers in environmental treatment. Modern Chemical Industry, 2021, 41(3): 63-67.
[1] Amran Y H M,Alyousef R,Alabduljabbar H,et al.Clean production and properties of geopolymer concrete:A review[J].Journal of Cleaner Production,2020,251:119679. [2] Nath S K,Mukherjee S,Maitra S,et al.Kinetics study of geopolymerization of fly ash using isothermal conduction calorimetry[J].Journal of Thermal Analysis and Calorimetry,2017,127(3):1953-1961. [3] He P,Cui J,Wang M,et al.Interplay between storage temperature,medium and leaching kinetics of hazardous wastes in Metakaolin-based geopolymer[J].Journal of Hazardous Materials,2020,384:121377. [4] 余淼.导电粉煤灰基地质聚合物固化重金属及光催化性能[D].西安:西安建筑科技大学,2018. [5] 仇秀梅,刘亚东,严春杰,等.粉煤灰基地质聚合物固化Pb2+及其高温稳定性研究[J].硅酸盐通报,2019,38(7):2281-2287,2294. [6] 毛林,武双磊,李鹏飞,等.粉煤灰基地质聚合物固化含铬电镀污泥研究[J].新型建筑材料,2018,45(10):29-34. [7] 刘道洁,吴新,李军辉,等.养护条件对二次铝灰-垃圾飞灰基地聚物中重金属稳固化的影响[J].环境工程学报,2018,12(8):2363-2371. [8] Hu S X,Zhong L L,Yang X J,et al.Synthesis of rare earth tailing-based geopolymer for efficiently immobilizing heavy metals[J].Construction and Building Materials,2020,254:119273. [9] Ji Z H,Su L Y,Pei Y S.Synthesis and toxic metals (Cd,Pb,and Zn) immobilization properties of drinking water treatment residuals and metakaolin-based geopolymers[J].Materials Chemistry and Physics,2020,242:122535. [10] Zhan X Y,Wang L A,Hu C C,et al.Co-disposal of MSWI fly ash and electrolytic manganese residue based on geopolymeric system[J].Waste Management,2018,82:62-70. [11] Wei Y,Wang J,Wang J,et al.Hydrothermal processing,characterization and leaching toxicity of Cr-added "fly ash-metakaolin" based geopolymer[J].Construction and Building Materials,2020,251:118931. [12] Guo B,Pan D A,Liu B,et al.Immobilization mechanism of Pb in fly ash-based geopolymer[J].Construction and Building Materials,2017,134:123-130. [13] Roghanian N,Banthia N.Development of a sustainable coating and repair material to prevent bio-corrosion in concrete sewer and waste-water pipes[J].Cement and Concrete Composites,2019,100:99-107. [14] Grengg C,Mittermayr F,Ukrainczyk N,et al.Advances in concrete materials for sewer systems affected by microbial induced concrete corrosion:A review[J].Water Research,2018,134:341-352. [15] 金漫彤,金赞芳,黄彩菊.地质聚合物固化重金属Pb2+的研究[J].环境科学,2011,32(5):1447-1453. [16] Khalid Hammad R,Lee K N,Park M S,et al.Synthesis of geopolymer-supported zeolites via robust one-step method and their adsorption potential[J].Journal of Hazardous Materials,2018,353:522-533. [17] Kara I,Tunc D,Sayin F,et al.Study on the performance of metakaolin based geopolymer for Mn(Ⅱ) and Co(Ⅱ) removal[J].Applied Clay Science,2018,161:184-193. [18] Al-Harahsheh M S,Al Z K,Al-Makhadmeh L,et al.Fly ash based geopolymer for heavy metal removal:A case study on copper removal[J].Journal of Environmental Chemical Engineering,2015,3(3):1669-1677. [19] Naghsh M,Shams K.Synthesis of a kaolin-based geopolymer using a novel fusion method and its application in effective water softening[J].Applied Clay Science,2017,146:238-245. [20] Luukkonen T,Sarkkinen M,Kemppainen K,et al.Metakaolin geopolymer characterization and application for ammonium removal from model solutions and landfill leachate[J].Applied Clay Science,2016,119:266-276. [21] Roek P,Król M,Mozgawa W.Lightweight geopolymer-expanded glass composites for removal of methylene blue from aqueous solutions[J].Ceramics International,2020,46(12):19785-19791. [22] Ji Z H,Pei Y S.Bibliographic and visualized analysis of geopolymer research and its application in heavy metal immobilization:A review[J].Journal of Environmental Management,2019,231:256-267. [23] Lee S,Riessen A,Chon C M,et al.Impact of activator type on the immobilisation of lead in fly ash-based geopolymer[J].Journal of Hazardous Materials,2016,305:59-66. [24] Falah M,Mackenzie K J D.Synthesis and properties of novel photoactive composites of P25 titanium dioxide and copper(Ⅰ) oxide with inorganic polymers[J].Ceramics International,2015,41(10):13702-13708. [25] 张耀君,余淼,张力,等.一种新型石墨烯-粉煤灰基地质聚合物复合材料的制备及光催化应用[J].材料导报,2017,31(9):50-56,63. [26] Siyal A A,Shamsuddin M R,Khan M I,et al.A review on geopolymers as emerging materials for the adsorption of heavy metals and dyes[J].Journal of Environmental Management,2018,224:327-339. [27] Yan S,Zhang F Y,Wang L,et al.A green and low-cost hollow gangue microsphere/geopolymer adsorbent for the effective removal of heavy metals from wastewaters[J].Journal of Environmental Management,2019,246:174-183. [28] Leiva C,Luna-Galiano Y,Arenas C,et al.A porous geopolymer based on aluminum-waste with acoustic properties[J].Waste Management,2019,95:504-512. [29] Luna-Galiano Y,Leiva C,Arenas C,et al.Fly ash based geopolymeric foams using silica fume as pore generation agent.Physical,mechanical and acoustic properties[J].Journal of Non-Crystalline Solids,2018,500:196-204. [30] Arenas C,Luna-Galiano Y,Leiva C,et al.Development of a fly ash-based geopolymeric concrete with construction and demolition wastes as aggregates in acoustic barriers[J].Construction and Building Materials,2017,134:433-442.