Research progress in promoters of cobalt-based catalysts for Fischer-Tropsch synthesis
HUANG Li-chun1,2, WANG Chan-he2, ZHOU Jian-qiang2, SUO Hai-yun3, YAN Lai1,3
1. Ordos Dalu Institute of Coal Chemical Industry, Ordos 010321, China; 2. Synfuels China Inner Mongolia Co., Ltd., Ordos 010321, China; 3. Synfuels China Technology Co., Ltd., Beijing 101407, China
Abstract: Focus on the promotive effect of promotors to cobalt-based catalysts,the research progress in promoters of cobalt-based catalysts for Fischer-Tropsch synthesis is reviewed.The adding mode of promoters,promotion functions and promotion effects are summarized.Influences of different promoters on cobalt-based catalysts' reducibility,dispersion,stability and catalytic performance in Fischer-Tropsch synthesis are analyzed.Discussion is emphasized on the structural effects,electronic effects,and synergistic effects of promoters.Some suggestions are proposed for future research of catalysts.
黄礼春, 王缠和, 周建强, 索海云, 燕来. 费托合成钴基催化剂助剂研究进展[J]. 现代化工, 2020, 40(9): 56-60,65.
HUANG Li-chun, WANG Chan-he, ZHOU Jian-qiang, SUO Hai-yun, YAN Lai. Research progress in promoters of cobalt-based catalysts for Fischer-Tropsch synthesis. Modern Chemical Industry, 2020, 40(9): 56-60,65.
[1] 张碧江.煤基合成液体燃料[M].太原:山西科学技术出版社,1995:84-85. [2] Fischer F,Tropsch H.The preparation of synthetic oil mixtures (synthol) from carbon monoxide and hydrogen[J].Brennstoff Chem,1923,4:276-285. [3] Morales F,Weckhuysen B M.Promotion effects in Co-based Fischer-Tropsch catalysis[M].RSC Publishing,2006:1-40. [4] Cook K M,Perez H D,Bartholomew C H,et al.Effect of promoter deposition order on platinum-,ruthenium-,or rhenium-promoted cobalt Fischer-Tropsch catalysts[J].Appl Catal A,2014,482:275-286. [5] Zhao Z,Lu W,Feng C H,et al.Increasing the activity and selectivity of Co-based FTS catalysts supported by carbon materials for direct synthesis of clean fuels by the addition of chromium[J].J Catal,2019,370:251-264. [6] Miyazawa T,Hanaoka T,Shimura K,et al.Mn and Zr modified Co/SiO2 catalysts development in slurry-phase Fischer-Tropsch synthesis[J].Appl Catal A,2013,467:47-54. [7] De La Osa A R,De Lucas A,Valverde J L,et al.Influence of alkali promoters on synthetic diesel production over Co catalyst[J].Catal Today,2011,167:96-106. [8] Ishida T,Yanagihara T,Liu X H,et al.Synthesis of higher alcohols by Fischer-Tropsch synthesis over alkali metal-modified cobalt catalysts[J].Appl Catal A,2013,458:145-154. [9] Xie J X,Paalanen P P,van Deelen T W,et al.Promoted cobalt metal catalysts suitable for the production of lower olefins from natural gas[J].Nat Commun,2019,10:1-10. [10] Zeng S H,Du Y,Su H Q,et al.Promotion effect of single or mixed rare earths on cobalt-based catalysts for Fischer-Tropsch synthesis[J].Catal Commun,2011,13:6-9. [11] He L L,Teng B T,Zhang Y L,et al.Development of composited rare-earth promoted cobalt-based Fischer-Tropsch synthesis catalysts with high activity and selectivity[J].Appl Catal A,2015,505:276-283. [12] Gnanamani M K,Jacobs G,Graham U M,et al.Effect of sequence of P and Co addition over silica for Fischer-Tropsch synthesis[J].Appl Catal A,2017,538:190-198. [13] Woo M H,Cho J M,Jun K W,et al.Thermally stabilized cobalt-based Fischer-Tropsch catalysts by phosphorous modification of Al2O3:Effect of calcination temperatures on catalyst stability[J].Chem Cat Chem,2015,7:1460-1469. [14] Xu D,Li W,Duan H,et al.Reaction performance and characterization of Co/Al2O3 Fischer-Tropsch catalysts promoted with Pt,Pd and Ru[J].Catal Lett,2005,102:229-235. [15] Tsubaki N,Sun S,Fujimoto K.Different functions of the noble metals added to cobalt catalysts for Fischer-Tropsch synthesis[J].J Catal,2001,199:236-246. [16] 师海波,沈师孔.用脉冲D2反应研究CeO2在Co-CeO2/SiO2费托合成催化剂中的促进作用机理[J].催化学报,2006,27(12):1096-1100. [17] 代小平,余长春,李然家,等.Co/SiO2催化剂催化费托合成中CeO2助剂的作用[J].催化学报,2006,27(10):904-910. [18] Jacobs G,Patterson P M,Zhang Y Q,et al.Fischer-Tropsch synthesis:Deactivation of noble metal-promoted Co/Al2O3 catalysts[J].Appl Catal A,2002,233:215-226. [19] 周玮,房克功,陈建刚,等.ZrO2助剂对Co/SiO2催化剂在Fischer-Tropsch合成反应中稳定性的影响[J].燃料化学学报,2006,34(4):461-465. [20] Cornaro U,Rossini S,Montanari T,et al.K-doping of Co/Al2O3 low temperature Fischer-Tropsch catalysts[J].Catal Today,2012,197:101-108. [21] Escalona N,Medina C,García R,et al.Fischer Tropsch reaction from a mixture similar to biosyngas.Influence of promoters on surface and catalytic properties of Co/SiO2 catalysts[J].Catal Today,2009,143:76-79. [22] Cheng Q P,Zhao N,Lyu S S,et al.Tuning interaction between cobalt catalysts and nitrogen dopants in carbon nanospheres to promote Fischer-Tropsch synthesis[J].Appl Catal B,2019,248:73-83. [23] Jongsomjit B,Panpranot J,Goodwin Jr J G.Effect of zirconia-modified alumina on the properties of Co/γ-Al2O3 catalysts[J].J Catal,2003,215:66-77. [24] Jermwongratanachai T,Jacobs G,Ma W P,et al.Fischer-Tropsch synthesis:Comparisons between Pt and Ag promoted Co/Al2O3 catalysts for reducibility,local atomic structure,catalytic activity,and oxidation-reduction (OR) cycles[J].Catal Today,2013,464/465:165-180. [25] Bezemer G L,Radstake P B,Falke U,et al.Investigation of promoter effects of manganese oxide on carbon nanofiber-supported cobalt catalysts for Fischer-Tropsch synthesis[J].J Catal,2006,237:152-161. [26] Zhao Z A,Lu W,Feng C H,et al.Increasing the activity and selectivity of Co-based FTS catalysts supported by carbon materials for direct synthesis of clean fuels by the addition of chromium[J].J Catal,2019,270:251-264. [27] Cook K M,Poudyal S,Miller J T,et al.Reducibility of alumina-supported cobalt Fischer-Tropsch catalysts:Effects of noble metal type,distribution,retention,chemical state,bonding,and influence on cobalt crystallite size[J].Appl Catal A,2012,449:69-80. [28] Morales F,de Smit E,de Groot F M F,et al.Effects of manganese oxide promoter on the CO and H2 adsorption properties of titania-supported cobalt Fischer-Tropsch catalysts[J].J Catal,2007,246:91-99. [29] Nabaho D,Niemantsverdriet J W,Claeys M,et al.Hydrogen spillover in the Fischer-Tropsch synthesis:An analysis of platinum as a promoter for cobalt-alumina catalysts[J].Catal Today,2016,261:17-27. [30] Madikizela N N,Coville N J.A study of Co/Zn/TiO2 catalysts in the Fischer-Tropsch reaction[J].J Mol Catal A,2002,181:129-136.
