1. School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China; 2. Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants, Beijing 100083, China
Abstract: Worldwide progress on the catalysts for the oxidation of methyl mercaptan in recent years is reviewed from the aspects of supported and non-supported catalysts.The causes and regeneration methods of catalysts poisoning and deactivation during the reaction process are summarized.The studies on the structure-activity relationship of catalysts and the mechanism of catalytic oxidation of methyl mercaptan are helpful for the development of new catalysts.
[1] 郭兵兵,卢琴芳,何凤友,等.治理炼油污水处理场恶臭污染的试验[J].化工进展,2006,25(3):301-304. [2] 黄欣怡,张珺婷,王凡,等.餐厨垃圾资源化利用及其过程污染控制研究进展[J].化工进展,2016,35(9):2945-2951. [3] 金国良,刘娟,姚学民.橡胶废气干式氧化治理技术的提升[C].浙江省环境科学学会2017年学术年会暨浙江环博会,2017. [4] 红窦,姜建彪,刘翠棉,等.发酵类制药企业污水处理厂废气中VOCs及厂界恶臭物质特征分析[J].河北工业科技,2019,36(3):215-220. [5] 包景岭,邹克华,王连生.恶臭环境管理与污染控制[M].北京:中国环境科学出版社,2009. [6] Mouammine A,Ojala S,Pirault-Roy L,et al.Catalytic partial oxidation of methanol and methyl mercaptan:Studies on the selectivity of TiO2 and CeO2 supported V2O5 catalysts[J].Topics in Catalysis,2013,56(9/10):650-657. [7] Ling D,Liang H C,Li X Z.Oxidation of CH3SH by in situ generation of ferrate(Ⅵ) in aqueous alkaline solution for odour treatment[J].Separation & Purification Technology,2012,91:117-124. [8] Liu Q,Ke M,Liu F,et al.High-performance removal of methyl mercaptan by nitrogen-rich coconut shell activated carbon[J].RSC Advances,2017,7(37):22892-22899. [9] Liu Q,Ke M,Yu P,et al.High performance removal of methyl mercaptan on metal modified activated carbon[J].Korean Journal of Chemical Engineering,2017,35(1):1-10. [10] 刘海弟,李伟曼,马翔,等.负载铜的活性炭用于低浓度甲硫醇的吸附[J].无机化学学报,2016,32(6):1026-1032. [11] Rashidi A M,Mirzaeian M,Khodabakhshi S.Synthesis of carbon nanotube-supported metallo carboxyporphyrin as a novel nanocatalyst for the mercaptan removal[J].Journal of Natural Gas Science & Engineering,2015,25:103-109. [12] Mirzaeian M,Rashidi A M,Zare M,et al.Mercaptan removal from natural gas using carbon nanotube supported cobalt phthalocyanine nanocatalyst[J].Journal of Natural Gas Science & Engineering,2014,18:439-445. [13] Sahle-Demessie E,Devulapelli V G.Oxidation of methanol and total reduced sulfur compounds with ozone over V2O5/TiO2 catalyst:Effect of humidity[J].2009,361(1/2):72-80. [14] Xia D,Xu W,Wang Y,et al.Enhanced performance and conversion pathway for catalytic ozonation of methyl mercaptan on single-atom Ag deposited three-dimensional ordered mesoporous MnO2[J].Environmental Science & Technology,2018,52(22):13399-13409. [15] Chu H,Lee W T,Horng K H,et al.The catalytic incineration of (CH3)2S and its mixture with CH3SH over a Pt/Al2O3 catalyst[J].Journal of Hazardous Materials,2001,82(1):43-53. [16] Sun Z,Jin L,Zhao Y,et al.A structured catalyst toward mercaptan sweetening with largely enhanced synergistic effect[J].Indengchemres,2014,53(12):4595-4603. [17] Zhao S,Yi H,Tang X,et al.Methyl mercaptan removal from gas streams using metal-modified activated carbon[J].Journal of Cleaner Production,2015,87:856-861. [18] Liu Q,Ke M,Yu P,et al.High performance removal of methyl mercaptan on metal modified activated carbon[J].Korean Journal of Chemical Engineering,2017,35(1):1-10. [19] 龚娟,焦以飞,苏庆泉,等.沼气中甲硫醇的两段深度脱除法[J].现代化工,2013,33(11):97-100. [20] 宋雯,孙梦娟,张金凤.稀土金属改性碳基催化剂脱除甲硫醇性能研究[J].化工管理,2018,(22):43. [21] Lu J,Hao H,Zhang L,et al.The investigation of the role of basic lanthanum (La) species on the improvement of catalytic activity and stability of HZSM-5 material for eliminating methanethiol-(CH3SH)[J].Applied Catalysis B Environmental,2018,237:185-197. [22] He D,Hao H,Chen D,et al.Effects of rare-earth (Nd,Er and Y) doping on catalytic performance of HZSM-5 zeolite catalysts for methyl mercaptan (CH3SH) decomposition[J].Applied Catalysis A General,2017,533:66-74. [23] Park J J,Jung S Y,Ryu C Y,et al.The removal of sulfur compounds using activated carbon-based sorbents impregnated with alkali or alkaline earth metal[J].Journal of Nanoelectronics & Optoelectronics,2010,5(2):222-226. [24] 王辉国,范志明,柯明,等.新型硫醇氧化双功能催化剂CoSPc/Mg(Al)O的研究[J].石油炼制与化工,2001,(1):51-55. [25] Cellier C M,Vromman V,Ruaux V,et al.Sulfation mechanism and catalytic behavior of manganese oxide in the oxidation of methanethiol[J].Journal of Physical Chemistry B,2004,108(28):9989-10001. [26] Gao L,Xue Q,Liu Y,et al.Base-free catalytic aerobic oxidation of mercaptans for gasoline sweetening over HTLcs-derived CuZnAl catalyst[J].Aiche Journal,2010,55(12):3214-3220. [27] Zhao S,Yi H,Tang X,et al.Removal of volatile odorous organic compounds over NiAl mixed oxides at low temperature[J].Journal of Hazardous Materials,2018,344(FEB.15):797-810. [28] 何德东.稀土复合氧化物的合成、表征及其对甲硫醇催化分解性能的研究[D].昆明:昆明理工大学,2017. [29] 刘强,柯明,刘峰,等.活性炭基甲硫醇吸附剂的制备及再生研究[J].现代化工,2017,37(4):127-130.