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现代化工  2020, Vol. 40 Issue (4): 51-55    DOI: 10.16606/j.cnki.issn0253-4320.2020.04.012
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基于C3化合物合成丙烯酸甲酯的催化剂研究进展
赵志远, 荆涛, 田景芝, 赵云鹏, 娄丛强, 王超, 赵春琦
齐齐哈尔大学化学与化学工程学院, 黑龙江 齐齐哈尔 161000
Advances in catalysts for synthesis of methyl acrylate from C3 compounds
ZHAO Zhi-yuan, JING Tao, TIAN Jing-zhi, ZHAO Yun-peng, LOU Cong-qiang, WANG Chao, ZHAO Chun-qi
School of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161000, China
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摘要 介绍了以C3为原料制丙烯酸甲酯的工艺路线,重点对醋酸甲酯和甲醛羟醛缩合合成丙烯酸甲酯的催化剂研究进展进行综述,认为此工艺有望替代石油路线成为下一个产业化模式;结合工业生产现状和气固相催化反应产率,对这种合成路线催化剂的下一步开发进行了展望。
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赵志远
荆涛
田景芝
赵云鹏
娄丛强
王超
赵春琦
关键词:  丙烯酸甲酯  醋酸甲酯  羟醛缩合  气固相催化    
Abstract: The process routes using C3 fractions to synthesize methyl acrylate are introduced,with focus on the research advances in catalysts for the synthesis of methyl acrylate through aldol condensation between methyl acetate and formaldehyde.Moreover,it is pointed out that this process is expected to become the next generation mode for industrial production of methyl acrylate instead of present petroleum routes.Based on the present industrial production situation and the yield of gas-solid catalytic reaction,the future development of the catalyst for this route is prospected.
Key words:  methyl acrylate    methyl acetate    aldol condensation    gas-solid phase catalysis
收稿日期:  2019-08-04      修回日期:  2020-02-10          
TQ22  
基金资助: 齐齐哈尔大学研究生创新科研项目(YJSCX2019040)
通讯作者:  荆涛(1971-),男,博士,教授,研究方向为催化及催化反应工程,通讯联系人,jtkr@163.com。    E-mail:  jtkr@163.com
作者简介:  赵志远(1996-),男,硕士生
引用本文:    
赵志远, 荆涛, 田景芝, 赵云鹏, 娄丛强, 王超, 赵春琦. 基于C3化合物合成丙烯酸甲酯的催化剂研究进展[J]. 现代化工, 2020, 40(4): 51-55.
ZHAO Zhi-yuan, JING Tao, TIAN Jing-zhi, ZHAO Yun-peng, LOU Cong-qiang, WANG Chao, ZHAO Chun-qi. Advances in catalysts for synthesis of methyl acrylate from C3 compounds. Modern Chemical Industry, 2020, 40(4): 51-55.
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https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2020.04.012  或          https://www.xdhg.com.cn/CN/Y2020/V40/I4/51
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