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现代化工  2020, Vol. 40 Issue (4): 17-21    DOI: 10.16606/j.cnki.issn0253-4320.2020.04.005
  技术进展 本期目录 | 过刊浏览 | 高级检索 |
电解锰渣中Mn和NH3-N固化/稳定化处理研究现状及展望
母维宏1, 周新涛1, 黄静2, 和森1, 罗中秋1,3, 马越1, 王路星1, 邵周军1
1. 昆明理工大学化学工程学院, 云南 昆明 650500;
2. 西昌学院, 四川 西昌 615000;
3. 昆明理工大学云南省高校磷化工重点实验室, 云南 昆明 650500
Research status and prospect of solidification/stabilization of Mn and NH3-N from electrolytic manganese residue
MU Wei-hong1, ZHOU Xin-tao1, HUANG Jing2, HE Sen1, LUO Zhong-qiu1,3, MA Yue1, WANG Lu-xing1, SHAO Zhou-jun1
1. Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China;
2. Xichang University, Xichang 615000, China;
3. The Higher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province, Kunming University of Science and Technology, Kunming 650500, China
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摘要 对碱性材料和磷酸盐化学键合陶瓷材料(CBPCs)固化/稳定化处理电解锰渣(EMR)的效果以及固化机理等方面进行了综述。传统的碱性材料虽可有效固化EMR中的重金属离子,但处理后的EMR的物理化学性质不够稳定,固化体很容易因碳化而发生结构破坏,存在二次污染隐患。而用CBPCs固化EMR虽可实现Mn以及NH3-N稳定化控制,但施工操作性差,且反应原料MgO成本较高。利用富含金属氧化物(MgO、FeOx)的镍铁渣或铜渣等工业废渣代替纯MgO,不仅可降低材料处理成本、改善施工可操作性,同时可通过化学键合、物理包裹、吸附等协同作用实现EMR的有效固封。此方法可为EMR处理提供一种研究思路。
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母维宏
周新涛
黄静
和森
罗中秋
马越
王路星
邵周军
关键词:  电解锰渣  污染  固化/稳定化  碱性材料  磷酸盐化学键合材料    
Abstract: The effects and mechanism of solidifying/stabilizing electrolytic manganese residue (EMR) by alkaline materials and chemically bonded phosphate ceramics (CBPCs) are elaborately reviewed.Although traditional alkaline materials can effectively stabilize/solidify heavy metal ions in EMR,the physicochemical properties of the treated EMR specimens are not very stable due to that the structure of the solidified specimens is easily destroyed by carbonization,leaving hidden risk of secondary pollution.While the solidification/stabilization of Mn and NH3-N by CBPCs also has some weakness such as poor operability and high cost for reaction material MgO.Replacing pure MgO with ferronickel slag or copper slag rich in metal oxides (MgO,FeOx) can reduce the cost of treating materials and remarkably improve operability,also achieve effective treatment to EMR by the synergistic functions of chemical bonding,physical packaging and adsorption.This method can provide a research idea for treatment of EMR.
Key words:  electrolytic manganese residue    pollution    solidification/stabilization    alkaline materials    chemically bonded phosphate ceramics
收稿日期:  2019-07-29      修回日期:  2020-02-10          
X781  
基金资助: 国家自然科学基金地区基金(51662024,21866018);昆明理工大学引进人才科研启动基金(KKSY201605021);昆明理工大学分析测试基金(2016T20160009);云南科技厅青年基金(2017FD093);云南教育厅资助性项目(2017ZZX147);云南省级大创项目(201710674226)
通讯作者:  罗中秋(1987-),女,博士,讲师,从事固体废物资源化利用和危险固体废物安全化处理,通讯联系人,luozhongq@126.com。    E-mail:  luozhongq@126.com
作者简介:  母维宏(1995-),男,硕士生
引用本文:    
母维宏, 周新涛, 黄静, 和森, 罗中秋, 马越, 王路星, 邵周军. 电解锰渣中Mn和NH3-N固化/稳定化处理研究现状及展望[J]. 现代化工, 2020, 40(4): 17-21.
MU Wei-hong, ZHOU Xin-tao, HUANG Jing, HE Sen, LUO Zhong-qiu, MA Yue, WANG Lu-xing, SHAO Zhou-jun. Research status and prospect of solidification/stabilization of Mn and NH3-N from electrolytic manganese residue. Modern Chemical Industry, 2020, 40(4): 17-21.
链接本文:  
https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2020.04.005  或          https://www.xdhg.com.cn/CN/Y2020/V40/I4/17
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