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现代化工  2019, Vol. 39 Issue (S1): 79-84,88    DOI: 10.16606/j.cnki.issn0253-4320.2019.S.017
  技术进展 本期目录 | 过刊浏览 | 高级检索 |
烟草中茄尼醇的提取研究进展
赵国杰1,2, 刘家磊2, 张少峰1, 张骥2, 杨鲁伟2
1. 河北工业大学化工学院, 天津 300130;
2. 中国科学院理化技术研究所, 热力过程节能技术北京市重点实验室, 北京 100190
Research progress on extraction of solanesol from tobacco
ZHAO Guo-jie1,2, LIU Jia-lei2, ZHANG Shao-feng1, ZHANG Ji2, YANG Lu-wei2
1. School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China;
2. Beijing Key Laboratory of Thermal Science and Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
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摘要 从茄尼醇的浸提、分离提纯入手,简述了从废次烟草中分离得到茄尼醇的烟草预处理、提取方法、皂化过程以及分离提纯方法。分析表明,对烟草进行预处理有利于后续的分离提纯,使用氨浸预处理还可以起到皂化效果,提高提取率。超声波提取、微波辅助提取以及超临界CO2提取等方法与传统的溶剂浸提法相比,提取率高,且大大缩短了提取时间。动态皂化法减少了皂化时间,避免茄尼醇长时间处于碱性环境中,效果优于传统皂化法。使用聚合物共沉淀技术分离得到的茄尼醇能够达到合成辅酶Q10的要求,具有生产投资小、易于操作等优点。合成具有更好吸附效果的分子印迹聚合物是提纯茄尼醇的未来研究方向。
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赵国杰
刘家磊
张少峰
张骥
杨鲁伟
关键词:  烟草  茄尼醇  提取  皂化  分离提纯    
Abstract: Starting with the extraction and purification of solanesol,the pretreatment of tobacco,and the extraction method,saponification process and purification method for solanesol are briefly reviewed.The analysis shows that the pretreatment of tobacco is beneficial to subsequent separation and purification,and ammonia leaching pretreatment can also have saponification effect and improve extraction rate.Compared with traditional solvent extraction method,the ultrasonic extraction,microwave-assisted extraction and supercritical CO2 extraction methods all exhibit a higher extraction rate and much shorter extraction time.Dynamic saponification is more effective than traditional saponification.More importantly,it reduces saponification time to prevent solanesol from being exposed to alkaline environment for a long time.Solanesol separated by the polymer co-precipitation technology can meet the requirements of synthesizing coenzyme Q10,showing the advantages of small investment and easy operation.Nowadays,the synthesis of molecularly imprinted polymers with better adsorption effect is an important research direction.
Key words:  tobacco    solanesol    extraction    saponification    separation and purification
收稿日期:  2019-06-26      修回日期:  2019-09-02           出版日期:  2019-10-31
TS411  
基金资助: 湖北省烟草公司基础科研项目(027Y2018-028)
通讯作者:  张少峰(1965-),男,博士,教授,研究方向为化工过程强化与优化,通讯联系人,shfzhang@hebut.edu.cn。    E-mail:  shfzhang@hebut.edu.cn
作者简介:  赵国杰(1993-),男,硕士生,研究方向为化工过程强化与优化,1603846991@qq.com
引用本文:    
赵国杰, 刘家磊, 张少峰, 张骥, 杨鲁伟. 烟草中茄尼醇的提取研究进展[J]. 现代化工, 2019, 39(S1): 79-84,88.
ZHAO Guo-jie, LIU Jia-lei, ZHANG Shao-feng, ZHANG Ji, YANG Lu-wei. Research progress on extraction of solanesol from tobacco. Modern Chemical Industry, 2019, 39(S1): 79-84,88.
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https://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2019.S.017  或          https://www.xdhg.com.cn/CN/Y2019/V39/IS1/79
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