Abstract: Bacteria distribute everywhere and bring many problems to human health and industrial development.Traditional single-function antibacterial materials are facing many problems due to their limitations in practical application.The materials with convertible functions between bacteria-killing and foul-releasing can remain the advantages of single-function antibacterial materials and overcome their disadvantages,becoming a new development direction for antibacterial materials.This paper introduces the application and antibacterial mechanism of zwitterionic polymers and their derivatives,poly(N-isopropylacrylamide) (PNIPAAm) and other stimulation-responsive polymers in the field of kill-release convertible materials,summarizes the difficulties in the development of antibacterial materials,and forecasts the development direction of antibacterial materials.
曹弼宇, 孙秀花, 高昌录. 杀菌-防污功能可转换抗菌材料研究进展[J]. 现代化工, 2019, 39(S1): 29-32.
CAO Bi-yu, SUN Xiu-hua, GAO Chang-lu. Research progress in antibacterial materials with convertible functions between bacteria-killing and foul-releasing. Modern Chemical Industry, 2019, 39(S1): 29-32.
[1] Willyard C.The drug-resistant bacteria that pose the greatest health threats[J].Nature,2017,543(7643):15. [2] Neoh K G,Li M,Kang E T,et al.Surface modification strategies for combating catheter-related complications:Recent advances and challenges[J].Journal of Materials Chemistry B,2017,5(11):2045-2067. [3] Singha P,Locklin J,Handa H.A review of the recent advances in antimicrobial coatings for urinary catheters[J].ACTA Biomaterialia,2017,50:20-40. [4] 陈巧玲,陈碧桑,吴秀婷.蛋壳粉纳米银抗菌材料的制备及抑菌性研究[J].食品与机械,2018,34(8):105-109. [5] 马占芳,隋铭皓,袁博杰.季铵盐-纳米银灭活水中细菌效能研究[J].哈尔滨工业大学学报,2019,51(8):1-14. [6] Saswata C,Runhui L,Zvi H,et al.Ternary nylon-3 copolymers as host-defense peptide mimics:Beyond hydrophobic and cationic subunits[J].Journal of the American Chemical Society,2014,136(41):14530-14535. [7] 周欣宇,周春才.抗菌肽及类抗菌肽的设计、合成及应用[J].化学进展,2018,30(7):913-920. [8] Banerjee I,Pangule R C,Kane R S.Antifouling coatings:Recent developments in the design of surfaces that prevent fouling by proteins,bacteria,and marine organisms[J].Advanced Materials,2011,23(6):690-718. [9] 李琪,高昌录,孙秀花.两性离子聚合物防污涂层研究进展[J].合成材料老化与应用,2018,47(3):94-99. [10] Xu F J,Neoh K G,Kang E T.Bioactive surfaces and biomaterials via atom transfer radical polymerization[J].Progress in Polymer Science,2009,34(8):719-761. [11] Zhu X,Jun L X.Layer-by-layer assemblies for antibacterial applications[J].Biomaterials Science,2015,3(12):1505-1518. [12] Wei T,Tang Z,Yu Q,et al.Smart antibacterial surfaces with switchable bacteria-killing and bacteria-releasing capabilities[J].ACS Applied Materials & Interfaces,2017,9(43):37511-37523. [13] Zheng L,Sundaram H S,Wei Z,et al.Applications of zwitterionic polymers[J].Reactive & Functional Polymers,2017,118:51-61. [14] Xiao S,Ren B,Lei H,et al.Salt-responsive zwitterionic polymer brushes with anti-polyelectrolyte property[J].Current Opinion in Chemical Engineering,2018,19:86-93. [15] Yan S,Luan S,Shi H,et al.Hierarchical polymer brushes with dominant antibacterial mechanisms switching from bactericidal to bacteria repellent[J].Biomacromolecules,2016,17(5):1696-1704. [16] Fu Y,Yang W,Lei H,et al.Salt-responsive "killing and release" antibacterial surfaces of mixed polymer brushes[J].Industrial & Engineering Chemistry Research,2018,57(27):8938-8945. [17] Cheng G,Xue H,Zhang Z,et al.A switchable biocompatible polymer surface with self-sterilizing and nonfouling capabilities[J].Angew Chem Int Ed,2008,47(46):8831-8834. [18] Can Z Q,Luo M,Jose M,et al.Reversibly switching the function of a surface between attacking and defending against bacteria[J].Angew Chem Int Ed Engl,2012,51(11):2602-2605. [19] Liu Q S,Liu L Y.Novel light-responsive hydrogels with antimicrobial and antifouling capabilities[J].Langmuir,2018,35(8):1450-1457. [20] Cao B,Lee C J,Zeng Z,et al.Electroactive poly(sulfobetaine-3,4-ethylenedioxythiophene)(PSBEDOT) with controllable antifouling and antimicrobial properties[J].Chemical Science,2015,7(3):1976-1981. [21] Kim Y J,Matsunaga Y T.Thermo-responsive polymers and their application as smart biomaterials[J].Journal of Materials Chemistry B,2017,5(23):4307-4321. [22] Schild H.Poly (N-isopropylacrylamide):Experiment,theory and application[J].Progress in Polymer Science,1992,17(2):163-249. [23] Conzatti G,Cavalie S,Combes C,et al.PNIPAM grafted surfaces through ATRP and RAFT polymerization:Chemistry and bioadhesion[J].Colloids SURF B Biointerfaces,2016,151:143-155. [24] Lsta L K,Perez-Luna V H,Lopez G P.Surface-grafted,environmentally sensitive polymers for biofilm release[J].Applied & Environmental Microbiology,1999,65(4):1603-1609. [25] He M,Wang Q,Zhang J,et al.Substrate-independent ag-nanoparticle-loaded hydrogel coating with regenerable bactericidal and thermoresponsive antibacterial properties[J].ACS APPL Mater Interfaces,2017,9(51):44479-44782. [26] Wang X,Yan S,Song L,et al.Temperature-responsive hierarchical polymer brushes switching from bactericidal to cell repellency[J].ACS Applied Materials & Interfaces,2017,9(46):40930-40939. [27] Yan S,Shi H,Song L,et al.Nonleaching bacteria-responsive antibacterial surfacebased on a unique hierarchical architecture[J].ACS Applied Materials & Interfaces,2016,8(37):24471-24481. [28] Wei T,Zhan W,Yu Q,et al.Smart biointerface with photoswitched functions between bactericidal activity and bacteria-releasing ability[J].ACS APPL Mater Interfaces,2017,9(31):25767-25774. [29] Dong Y,Wang P,Wei T,et al.Smart antibacterial surfaces established by one-step photo-crosslinking[J].Advanced Materials Interfaces,2017,4(24):1-8. [30] Qu Y,Wei T,Jian Z,et al.Regenerable smart antibacterial surfaces:Fully removal of killed bacteria via a sequential degradable layer[J].Journal of Materials Chemistry B,2018,6(23):3946-3955.