Preparation and characterization of PTFE composite microfiltration membrane
XIAO Kai-sheng1,2, ZHANG Hao-fan1,2, WANG Zhen1,2, WANG Peng1,2, LU Yun-long3, CHEN Wen-qing1,2
1. SCU-HITACHI Environment Applied Technology Research Center, Sichuan University, Chengdu 610065, China; 2. College of Architecture and Environment, Sichuan University, Chengdu 610065, China; 3. Panzhihua West District Environmental Monitoring Station, Panzhihua 617068, China
Abstract: In order to solve the macro-porous defects and poor surface hydrophilicity of polytetrafluoroethylene (PTFE) hollow fiber membrane,PTFE composite microfiltration membrane is prepared through wrapping method with hydrophilic PTFE flat membrane as the filter layer and PTFE hollow fiber membrane as the support layer.Based on experiments,the optimum tensile ratio is 300%-200%.Under optimum tensile ratio,the pore sizes of PTFE composite membrane distribute uniformly with the most probable pore size of 0.35 μm,the proportion of the most probable pore size is 75.9%,the maximum pore size is less than 0.4 μm,the porosity exceeds 80%,the tensile strength reaches 9.15 MPa,the explosive strength exceeds 0.3 MPa,PTFE composite membrane filter layer has a contact angle of 70 degree,and the pure water flux achieves 1 107 L/(m2·h).
[1] 郭瑞丽,李玲.膜分离技术及其应用简介[J].新疆大学学报,2003,20(4):410-413. [2] 辛银平,李双凌,周记玲.膜分离技术在环境工程中的应用[J].环境与发展,2017,29(06):128-130. [3] 见雪珍.填充聚四氟乙烯复合材料的力学性能和摩擦磨损性能研究[D].上海:上海交通大学,2013. [4] 郑涛.PDMS/PTFE渗透汽化膜结构与分离性能研究[D].杭州:浙江理工大学,2017. [5] 郭玉海,张华鹏.聚四氟乙烯中空纤维膜及其在印染废水处理中的应用[C]//2010威士邦全国印染行业节能环保年会论文集,2010:368-371. [6] 侯成成,黄磊,黄斌香.PTFE微孔薄膜在油水分离中的应用研究[J].水处理技术,2013,39(06):73-76. [7] 徐毅,王占生,杜晓文,等.HRT对一体式PTFE膜生物反应器运行效果的影响[J].中国环境科学,2012,32(12):2192-2198. [8] 许海亮,吴玉华,雷登科,等.MBR工艺处理工业园区电镀废水的中试应用研究[J].电镀与涂饰,2013,(8):46-49. [9] Zhui H L,Wang H J,Wang F,et al.Preparation and properties of PTFE hollow fiber membranes for desalination through vacuum membrane distillation[J].Journal of Membrane Science,2013,446:145-153. [10] 黄庆林,肖长发,胡晓宇,等.聚四氟乙烯膜的制备及性能[J].高分子材料科学与工程,2010,26(05):123-126. [11] Tu C Y,Liu Y L,KueirRarn Lee,et al.Surfacegrafting polymerization and modification on poly(tetrafluoroethylene) films by means of ozone treatment[J].Polymer,2005,46(18):6976-6985.