Research progress on graphene-based catalysts for biomass conversion
SONG Wei1,2, LONG Jing-wen2, LIU Qi-ying1, PAN Cheng-qiang2, WANG Fei2
1. Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou 510650, China; 2. School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China
Abstract: Based on introduction to the structure and properties of graphene-based catalysts,the latest research progress of graphene-based catalysts in the conversion of biomass to high value-added chemicals is reviewed.The application of the catalysts in the Pickering emulsion interface are also prospected.
宋巍, 龙靖文, 刘琪英, 潘成强, 王飞. 石墨烯基催化剂用于生物质转化的研究进展[J]. 现代化工, 2019, 39(7): 22-26,28.
SONG Wei, LONG Jing-wen, LIU Qi-ying, PAN Cheng-qiang, WANG Fei. Research progress on graphene-based catalysts for biomass conversion. Modern Chemical Industry, 2019, 39(7): 22-26,28.
Lam E,Luong J H T.Carbon materials as catalyst supports and catalysts in the transformation of biomass to fuels and chemicals[J].ACS Catalysis,2014,4(10):3393-3410.
[2]
Zhang T,Li W,Xu Z,et al.Catalytic conversion of xylose and corn stalk into furfural over carbon solid acid catalyst in γ-valerolactone[J].Bioresource Technology,2016,209:108-114.
[3]
Zhang L,Alvarez N T,Zhang M,et al.Preparation and characterization of graphene paper for electromagnetic interference shielding[J].Carbon,2015,82(30):353-359.
[4]
Yin P T,Shah S,Chhowalla M,et al.Design,synthesis,and characterization of graphene-nanoparticle hybrid materials for bioapplications[J].Chemical Reviews,2015,115(7):2483-2531.
[5]
Georgakilas V,Tiwari J N,Kemp K C,et al.Noncovalent functionalization of graphene and graphene oxide for energy materials,biosensing,catalytic,and biomedical applications[J].Chemical Reviews,2016,116(9):5464-5519.
Navalon S,Dhakshinamoorthy A,Alvaro M,et al.Carbocatalysis by graphene-based materials[J].Chemical Reviews,2014,114(12):6179-6212.
[8]
Zhao X,Wang J,Chen C,et al.Graphene oxide for cellulose hydrolysis:How it works as a highly active catalyst[J].Chemical Communications,2014,50(26):3439-3442.
[9]
Hu L,Lin L,Wu Z,et al.Chemocatalytic hydrolysis of cellulose into glucose over solid acid catalysts[J].Applied Catalysis B Environmental,2015,46(22):225-243.
[10]
Zhang M,Wu M,Liu Q,et al.Graphene oxide mediated cellulose-derived carbon as a highly selective catalyst for the hydrolysis of cellulose to glucose[J].Applied Catalysis A:General,2017,543:218-224.
[11]
Mission E G,Quitain A T,Hirano Y,et al.Integrating reduced graphene oxide with microwave-subcritical water for cellulose depolymerization[J].Catalysis Science & Technology,2018,8(21):5434-5444.
[12]
Deng W,Zhang Q,Wang Y.Catalytic transformations of cellulose and its derived carbohydrates into 5-hydroxymethylfurfural,levulinic acid,and lactic acid[J].Science China Chemistry,2015,58(1):29-46.
[13]
Wang H,Kong Q,Wang Y,et al.Graphene oxide catalyzed dehydration of fructose into 5-hydroxymethylfurfural with isopropanol as cosolvent[J].Chem Cat Chem,2014,6(3):728-732.
[14]
Mondal D,Chaudhary J P,Sharma M,et al.Simultaneous dehydration of biomass-derived sugars to 5-hydroxymethyl furfural (HMF) and reduction of graphene oxide in ethyl lactate:One pot dual chemistry[J].RSC Advances,2014,4(56):29834-29839.
[15]
Sedrpoushan A,Heidari M,Akhavan O.Nanoscale graphene oxide sheets as highly efficient carbocatalysts in green oxidation of benzylic alcohols and aromatic aldehydes[J].Chinese Journal of Catalysis,2017,38(4):745-757.
[16]
Xiong H,Schwartz T J,Andersen N I,et al.Graphitic-carbon layers on oxides:Toward stable heterogeneous catalysts for biomass conversion reactions[J].Angewandte Chemie International Edition,2015,54(27):7939-7943.
[17]
Dhakshinamoorthy A,Latorre-Sanchez M,Asiri A M,et al.Sulphur-doped graphene as metal-free carbocatalysts for the solventless aerobic oxidation of styrenes[J].Catalysis Communications,2015,65:10-13.
[18]
Blandez J F,Navalón S,Alvaro M,et al.Graphenes as metal-free catalysts for the oxidative depolymerization of lignin models[J].Chem Cat Chem,2015,7(18):3020-3026.
[19]
Zhang T,Li W,Xu Z,et al.Catalytic conversion of xylose and corn stalk into furfural over carbon solid acid catalyst in γ-valerolactone[J].Bioresource Technology,2016,209:108-114.
[20]
Fukuhara K,Nakajima K,Kitano M,et al.Transesterification of triolein over hydrophobic microporous carbon with SO3H Groups[J].Chem Cat Chem,2015,7(23):3945-3950.
Wei Z,Yang Y,Hou Y,et al.A new approach towards acid catalysts with high reactivity based on graphene nanosheets[J].Chem Cat Chem,2014,6(8):2354-2363.
[23]
Upare P P,Hong D Y,Kwak J,et al.Direct chemical conversion of xylan into furfural over sulfonated graphene oxide[J].Catalysis Today,2019,324:66-72.
[24]
Liu F,Kong W,Wang L,et al.Efficient biomass transformations catalyzed by graphene-like nanoporous carbons functionalized with strong acid ionic liquids and sulfonic groups[J].Green Chemistry,2015,17(1):480-489.
[25]
Wang Y,De S,Yan N.Rational control of nano-scale metal-catalysts for biomass conversion[J].Chemical Communications,2016,52(37):6210-6224.
[26]
Chen C C,Lin C L,Chen L C.Functionalized carbon nanomaterial supported palladium nano-catalysts for electrocatalytic glucose oxidation reaction[J].Electrochimica Acta,2015,152:408-416.
[27]
Wang D,Niu W,Tan M,et al.Pt nanocatalysts supported on reduced graphene oxide for selective conversion of cellulose or cellobiose to sorbitol[J].Chem Sus Chem,2014,7(5):1398-1406.
[28]
Zhang M,Su K,Song H,et al.The excellent performance of amorphous Cr2O3,SnO2,SrO and graphene oxide-ferric oxide in glucose conversion into 5-HMF[J].Catalysis Communications,2015,69:76-80.
[29]
Shi J,Wang Y,Yu X,et al.Production of 2,5-dimethylfuran from 5-hydroxymethylfurfural over reduced graphene oxides supported Pt catalyst under mild conditions[J].Fuel,2016,163:74-79.