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现代化工  2018, Vol. 38 Issue (11): 62-66    DOI: 10.16606/j.cnki.issn0253-4320.2018.11.014
  技术进展 本期目录 | 过刊浏览 | 高级检索 |
醋酸(甲酯)与甲醛羟醛缩合生成丙烯酸(甲酯)催化剂的研究进展
任志恒1,2, 杨先贵1, 王公应1
1. 中国科学院成都有机化学研究所, 四川 成都 610041;
2. 中国科学院大学, 北京 100049
Advances on synthesis of acrylic acid (methyl acylate) through aldol condensation between acetic acid (methyl acetate) and formaldehyde
REN Zhi-heng1,2, YANG Xian-gui1, WANG Gong-ying1
1. Chengdu Institute of Organic Chemistry, Chinese Academy of Science, Chengdu 610041, China;
2. University of Chinese Academy of Sciences, Beijing 100049, China
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摘要 综述了醋酸(甲酯)与甲醛羟醛缩合生成丙烯酸(甲酯)路线所用的催化剂,主要包括V-P-O、碱金属/碱土金属型、离子液体类型催化剂的结构特性、催化性能等方面的最新研究进展,认为开发新型催化剂是该工艺路线的核心技术。
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任志恒
杨先贵
王公应
关键词:  醋酸(甲酯)  甲醛  丙烯酸(甲酯)  羟醛缩合  VPO  碱/碱土金属  离子液体    
Abstract: This paper supplies an overview of latest progress in structural features and catalytic performance of the catalysts for aldol condensation reaction between acetic acid (methyl acetate) and formaldehyde to synthesize acrylic acid (methyl acylate),mainly including V-P-O,alkali metal/alkaline earth metals and ionic liquids catalysts.It is pointed out that the development of new type catalysts is the core technology for the synthesis of acrylic acid (methyl acylate) via aldol condensation route.
Key words:  acetic acid and methyl acetate    formaldehyde    acrylic acid and methyl acylate    aldol condensation    V-P-O    alkali metal/alkaline earth metals    ionic liquids
收稿日期:  2018-03-21      修回日期:  2018-08-30          
TQ624.94  
通讯作者:  杨先贵(1962-),男,研究员,博士生导师,研究方向为精细化工,通讯联系人,yangxg@cioc.ac.cn。    E-mail:  yangxg@cioc.ac.cn
作者简介:  任志恒(1990-),男,博士生,研究方向为丙烯酸及其酯的催化合成,rzhtyut@163.com
引用本文:    
任志恒, 杨先贵, 王公应. 醋酸(甲酯)与甲醛羟醛缩合生成丙烯酸(甲酯)催化剂的研究进展[J]. 现代化工, 2018, 38(11): 62-66.
REN Zhi-heng, YANG Xian-gui, WANG Gong-ying. Advances on synthesis of acrylic acid (methyl acylate) through aldol condensation between acetic acid (methyl acetate) and formaldehyde. Modern Chemical Industry, 2018, 38(11): 62-66.
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http://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2018.11.014  或          http://www.xdhg.com.cn/CN/Y2018/V38/I11/62
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