1. Key Laboratory of Preparation and Applications of Environmental Friendly Materials of Ministry of Education, Jilin Normal University, Changchun 130012, China; 2. College of Chemistry, Jilin Normal University, Siping 136000, China
Abstract: The methods for silver complexing with different metal oxides are introduced.The catalytic properties of Ag-based composites are summarized.The latest study progresses on applications of Ag-based composites in the photocatalysis field are reviewed.The future development of Ag-based composites is prospected.
 彭红,刘洋,张锦胜,等.银纳米粒子材料应用研究进展[J].化工进展,2017,36(7):2525-2532.  张欣茜,王英,景伟文,等.Ag掺杂TiO2催化降解活性印染废水[J].绿色科技,2014,(1):157-160.  陈琳琳.银基复合半导体光催化材料的合成及其光催化性能研究[D].镇江:江苏大学,2015.  Kuriakose S,Choudhary V,Satpati B,et al.Facile synthesis of Ag-ZnO hybrid nanospindles for highly efficient photocatalytic degradation of methyl orange[J].Physical Chemistry Chemical Physics,2014,16(33):17560-17568.  Siegel J,Kvitek O,Ulbrich P,et al.Progressive approach for metal nanoparticle synthesis[J].Materials Letters,2012,89:47-50.  Prema P,Thangapandiyan S,Immanuel G,et al.CMC stabilized nano silver synthesis,characterizationand its antibacterial and synergistic effect with broad spectrum antibiotics[J].Carbohydrate Polymers,2017,158:141-148.  Pandey S,Mewada A,Thakur M,et al.Biogenic gold nanoparticles as fotillas to fire berberine hydrochloride using folic acid as molecular road map[J].Materials Science and Engineering:C,2013,33(7):3716-3722.  Nakkala J R,Mata R,Sadras S R.Green synthesized nano silver:Synthesis,physicochemical profiling,antibacterial,anticancer activities and biological invivotoxicity[J].Journal of Colloid and Interface Science,2017,499:33-45.  Patil S S,Mali M G,Tamboli M S,et al.Green approach for hierarchical nanostructured Ag-ZnO and their photocatalytic performance under sunlight[J].Catalysis Today,2016,260:126-134.  Jaramillo-Páez C,Navío J A,Hidalg M C,et al.High UV-photocatalytic activity of ZnO and Ag/ZnO synthesized by a facile method[J].Catalysis Today,2017,284:121-128.  Lu Q,Lu Z,Lu Y,et al.Photocatalytic synthesis and photovoltaic application of Ag-TiO2 nanorod composites[J].ACS Nano,2013,13(11):5698-5702.  Zhou W,Li T,Wang J Q,et al.Composites of small Ag clusters confined in the channels of well-ordered mesoporous anatase TiO2 and their excellent solar-light-driven photocatalytic performance[J].Nano Res,2014,7(5):731-742.  He M,Wang Y,Wang H,et al.A one-step sol-gel routederived Ag-CuO film as a novel solar selective absorber[J].Solar Energy Materials & Solar Cells,2016,144:264-272.  Momeni M M,Mirhosseini M,Mohammadi N.Efficient photo catalytic degradation of methyl orange over Ag-CuO nanostructures grown on copper foil under visible light irradiation[J].Journal of Materials Science:Materials in Electronics,2016,27(6):6542-6551.  Liu C,Zhang X,Wu J,et al.One-pot synthesis of visible-light-driven Ag/Ag3PO4 photocatalyst immobilized on exfoliated montmorillonite by clay-mediated in situ reduction[J].Applied Physics A,2016,122:946.  Gao R,Song J,Hu Y,et al.Facile synthesis of Ag/Ag3PO4 compositeswith highly efficient and stable photocatalytic performance under visible light[J].Journal of The Chinese Chemical Society,2017,64(10):1172-1180.  Yu N,Dong R,Liu J,et al.Synthesis of Ag/Ag2CO3 heterostructures with high length-diameter ratios for excellent photoactivity and anti-photocorrosion[J].RSC Adv,2016,6:103938-103945.  Mendez-Medrano M G,Kowalska E,Lehoux A,et al.Surface modification of TiO2 with Ag nanoparticles and CuO nanoclusters for application in photocatalysis[J].The Journal of Physical Chemistry C,2016,120(9):5143-5154.  Zhang X H,Wang L L,Liu C B,et al.A bamboo-inspired hierarchical nanoarchitecture of Ag/CuO/TiO2 nanotube array for highly photocatalytic degradation of 2,4-dinitrophenol[J].Journal of Hazardous Materials,2016,313:244-252.  Xu K,Wu J,Tan C F,et al.Ag/CuO/ZnO metal-semiconductor multiconcentric nanotubes for achieving superior and perdurable photodegradation[J].The Royal Society of Chemistry,2017,9:11574-11583.  Karthikeyan N,Prettencia L,Narayanan V,et al.Synthesis and characterization of coupled ZnO/Ag/CuO nanomaterials for photocatalytic degradation of organic dye under uvirradiation[J].International Journal of Innovative Research in Science & Engineering,2014,2347-3207.  Hu H,Wang Z H,Pan L,et al.Ag-coated Fe3O4@SiO2 three-ply composite microspheres:Synthesis,characterization,and application in detecting melamine with their surface-enhanced raman scattering[J].The Journal of Physical Chemistry C,2010,114(17):7738-7742.  Sun L J,He J,An S S,et al.Recyclable Fe3O4@SiO2-Ag magnetic nanospheres for the rapid decolorizing of dye pollutants[J].Chinese Journal of Catalysis,2013,34(7):1378-1385.  吴猛,葛凤燕,高洪国,等.Fe3O4@SiO2@Ag复合纳米粒子对染料污染物的循环催化降解性能[J].磁性材料及器件,2016,46(5):34-38.  姚忠平,李春香,吴晌江,等.Ag负载ZnS光催化剂的制备与光催化制氢[J].哈尔滨工业大学学报,2011,12(43):100-103.  Boltersdorf J,Maggard P A.Silver exchange of layered metal oxides and their photocatalytic activities[J].ACS Catalytic,2013,3(11):2547-2555.  He X L,Cai Y Y,Zhang H M,et al.Photocatalytic degradation of organic pollutants with Ag decorated free-standing TiO2 nanotube arrays and interface electrochemical response[J].Journal of Materials Chemistry,2011,21(2):475-480.  Chen T W,Zheng Y H,Lin J M,et al.Study on the photocatalytic degradation of methyl orange in water using Ag/ZnO as catalyst by liquid chromatography electrospray ionization ion-trap mass spectrometry[J].Journal of the American Society for Mass Spectrometry,2008,19(7):997-1003.  Lu W W,Liu G S,Gao S Y,et al.Tyrosine-assisted preparation of Ag/ZnO nanocomposites with enhanced photocatalytic performance and synergistic antibacterial activities[J].Nanotechnology,2008,19(44):1-10.  Gupta K,Singh R P,Pandey A,et al.Photocatalytic antibacterial performance of TiO2 and Ag-doped TiO2 against S.aureus.P.aeruginosa and E.coli[J].Beilstein J Nanotechnol,2013,4:345-351.