Overview on engineering technologies for chemical utilization of carbon dioxide
CHAI Shu1, WANG Qian2, MENG Li1, ZHU Wei-qun1,2
1. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; 2. National Engineering Research Center of Colloidal Materials, Jinan 250100, China
Abstract: Chemical utilization of CO2 can realize the reduction of CO2 emission and high value utilization of CO2.Whereas,no mature and integrative engineering operation in this aspect is available in China.This paper analyzes from the aspects of raw materials including CO2 and H2,reaction process,matching facilities and products and discusses the engineering technologies suitable for chemical utilization of CO2.The results show that CO2 is captured from coal chemical process and then is used to synthesize sym-triazine as well its derivatives products with consuming less amount of H2 and convenient facilities,which is an appropriate engineering technology for chemical utilization of carbon dioxide.This process is of great significance for China to reduce CO2 emission and realize the targets of the Paris Agree.
柴树, 王倩, 孟丽, 朱维群. CO2化学利用的工程化技术探讨[J]. 现代化工, 2018, 38(7): 1-5.
CHAI Shu, WANG Qian, MENG Li, ZHU Wei-qun. Overview on engineering technologies for chemical utilization of carbon dioxide. Modern Chemical Industry, 2018, 38(7): 1-5.
[1] Chu Steven.Carbon capture and sequestration[J].Science,2009,325(5948):1599. [2] Barry H.Carbon dioxide capture from power stations[R].Paris:International Energy Agency,2004. [3] 王文珍,张生琦,倪炳华,等.CO2的绿色利用技术研究进展[J].化工进展,2013,(6):1415-1422. [4] Song Cs.Global challenges and strategies for control,conversion and utilization of CO2 for sustainable development involving energy,catalysis,adsorption and chemical processing[J].Catalysis Today,2006,115(1-4):2-32. [5] Ma Jun,Sun Nannan,Zhang Xuelan,et al.A short review of catalysis for CO2 conversion[J].Catalysis Today,2009,148(3-4SI):221-231. [6] Yu Kaimankerry,Curcic Igor,Gabriel Joseph,et al.Recent advances in CO2 capture and utilization[J].Chem Sus Chem,2008,1(11):893-899. [7] Aresta Michele,Dibenedetto Angela.Utilisation of CO2 as a chemical feedstock:Opportunities and challenges[J].Dalton Transactions,2007,(28):2975-2992. [8] Lal R.Sequestration of atmospheric CO2 in global carbon pools[J].Energy & Environmental Science,2008,1(1):86-100. [9] 田恒水,李峰,陆文龙,等.发展二氧化碳的绿色高新精细化工产业链促进产业结构优化节能减排[J].化工进展,2010,(6):977-983. [10] Wang Hui,Gao Peng,Zhao Tiejun,et al.Recent advances in the catalytic conversion of CO2 to value added compunds[J].Science China-chemistry,2015,58(1SI):79-92. [11] 许兆峰,麻林巍,李政.中国二氧化碳捕集与封存成本估算[C].北京:中国动力工程学会青年学会,2009. [12] 任相坤,崔永君,步学朋,等.煤化工过程中的CO2排放及CCS技术的研究现状分析[J].神华科技,2009,(2):68-72. [13] 徐文佳,云箭,成行健.煤制油气和化工产品CO2的不同减排方式成本分析[J].煤化工,2016,44(1):11-14. [14] 何建坤,陈文颖,王仲颖,等.中国减缓气候变化评估[J].科学通报,2016,(10):1055-1062. [15] Huang Chih-hung,Tan Chung-sung.A review:CO2 utilization[J].Aerosol and Air Quality Research,2014,14(2):480-499. [16] Armaroli Nicola,Balzani Vincenzo.The hydrogen issue[J].Chem Sus Chem,2011,4(1):21-36. [17] Atsonios Konstantinos,Panopoulos Kyriakosd,Kakaras Emmanuel.Investigation of technical and economic aspects for methanol production through CO2 hydrogenation[J].International Journal of Hydrogen Energy,2016,41(4):2202-2214. [18] Goetz Manuel,Lefebvre Jonathan,Moers Friedemann,et al.Renewable power-to-gas:A technological and economic review[J].Renewable Energy,2016,85:1371-1390. [19] Atsonios Konstantinos,Panopoulos Kyriakosd,Kakaras Emmanuel.Thermocatalytic CO2 hydrogenation for methanol and ethanol production:Process improvements[J].International Journal of Hydrogen Energy,2016,41(2):792-806. [20] Smejkal Quido,Rodemerck Uwe,Wagner Edmund,et al.Economic assessment of the hydrogenation of CO2 to liquid fuels and petrochemical feedstock[J].Chemie Ingenieur Technik,2014,86(5):679-686. [21] Wieland Hoppe,Nadine Wachter,Stefan Bringezu.Economic assessment of CO2-Based methane,methanol and polyoxymethylene production[C].Amsterdam:19th International Conference of Carbon Dioxide,2017. [22] Rebecca Frauzem,Pichayapan Kongpanna,Kosan Roh,et al.Sustainable process design:Sustainable process networks for carbon dioxide conversion[J].Computer Aided Chemical Engineering,2015,36:175-195. [23] Pérez-Fortes Mar,Sch Neberger Janc,Boulamanti Aikaterini,et al.Methanol synthesis using captured CO2 as raw material:Techno-economic and environmental assessment[J].Applied Energy,2016,161:718-732. [24] Roh K,Nguyen T B H,Suriyapraphadilok U,et al.Development of sustainable CO2 conversion processes for the methanol production[J].Computer Aided Chemical Engineering,2015,37:1146-1150. [25] Liu Anhua,Yu Bing,He Liangnian.Catalytic conversion of carbon dioxide to carboxylic acid derivatives[J].Greenhouse Gases-Science and Technology,2015,5(1):17-33. [26] Smejkal Quido,Rodemerck Uwe,Wagner Edmund,et al.E conomic assessment of the hydrogenation of CO2 to liquid fuels and petrochemical feedstock[J].Chemie Ingenieur Technik,2014,86(5):679-686. [27] Assen Niklas,Jung Johannes,Bardow Andre.Life-cycle assessment of carbon dioxide capture and utilization:avoiding the pitfalls[J].Energy & Environmental Science,2013,6(9):2721-2734. [28] Cuellar-Franca Rosam,Azapagic Adisa.Carbon capture,storage and utilisation technologies:A critical analysis and comparison of their life cycle environmental impacts[J].Journal of CO2 Utilization,2015,9:82-102. [29] 王宝品.三聚氰酸的断环反应及工业应用研究[D].北京:北京化工大学,2013.
