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现代化工  2018, Vol. 38 Issue (3): 23-27    DOI: 10.16606/j.cnki.issn0253-4320.2018.03.006
  技术进展 本期目录 | 过刊浏览 | 高级检索 |
微波快速催化热解生物质制备富烃燃油的研究进展
王允圃1,2,3, 吴秋浩2,3, 曾子鸿2,3, 胡雅琴2,3, 刘玉环2,3, Roger Ruan4, 付桂明3, 张辉斌2,3, 张志林2,3, 张淑梅2,3, 阳秀华2,3
1. 广东省新能源和可再生能源研究开发与应用重点实验室, 广东 广州 510640;
2. 南昌大学生物质转化教育部工程研究中心, 江西 南昌 330047;
3. 南昌大学食品科学与技术国家重点实验室, 江西 南昌 330047;
4. Center for Biorefining and Department of Bioproducts and Biosystems Engineering, University of Minnesoa, 1390 Eckles Ave., St. Paul MN 55108, USA
Review of microwave-assisted catalytic fast pyrolysis of biomass to make hydrocarbon-rich fuel
WANG Yun-pu1,2,3, WU Qiu-hao2,3, ZENG Zi-hong2,3, HU Ya-qin2,3, LIU Yu-huan2,3, ROGER Ruan4, FU Gui-ming3, ZHANG Hui-bin2,3, ZHANG Zhi-lin2,3, ZHANG Shu-mei2,3, YANG Xiu-hua2,3
1. Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China;
2. Engineering Research Center for Biomass Conversion of Ministry of Education, Nanchang University, Nanchang 330047, China;
3. State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047, China;
4. Center for Biorefining and Department of Bioproducts and Biosystems Engineering, University of Minnesoa, St. Paul MN 55108, USA
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摘要 回顾了微波快速催化热解生物质制备富烃生物油的国内外研究现状,重点叙述了有效氢碳比(H/Ceff)及催化剂对微波快速催化热解生物质制备富烃生物油的影响。指出可通过提高热解原料H/Ceff、选择合适催化剂来调节生物油烃类组分;着重介绍了不同H/Ceff生物质原料、HZSM-5催化剂等影响因素,并对微波快速催化热解生物质制备富烃生物油进行了展望。
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王允圃
吴秋浩
曾子鸿
胡雅琴
刘玉环
Roger Ruan
付桂明
张辉斌
张志林
张淑梅
阳秀华
关键词:  有效氢碳比  微波催化热解  生物质  富烃生物油    
Abstract: The global current research situation of microwave-assisted catalytic fast pyrolysis of biomass for the production of hydrocarbon-rich bio-fuel is reviewed.The impacts of effective ratio of hydrogen to carbon (H/Ceff) and catalyst on microwave-assisted catalytic fast pyrolysis for the production of hydrocarbon-rich bio-fuel are described in detail.It is pointed out that the hydrocarbon components of prepared bio-fuel can be adjusted by increasing H/Ceff of biomass feedstock or choosing proper catalyst.In addition,the factors influencing the properties of bio-fuel such as biomass with different H/Ceff and H-ZSM-5 catalyst are emphatically introduced.Finally,the expectation about the microwave-assisted fast pyrolysis of biomass to make hydrocarbon-rich bio-fuel in the future is proposed.
Key words:  effective ratio of hydrogen to carbon (H/Ceff)    microwave-assisted catalytic pyrolysis    biomass    hydrocarbon-rich bio-fuel
收稿日期:  2017-09-15      修回日期:  2018-01-05           出版日期:  2018-03-20
S216.2  
基金资助: 广东省新能源和可再生能源研究开发与应用重点实验室开发基金(Y707sb1001);国家自然科学基金(21766019);国家国际科技合作专项项目(2015DFA60170~4);江西省重点研发计划项目(20171BBF60023);江西省教育厅科学技术研究一般项目(GJJ150213)
通讯作者:  刘玉环(1963-),男,博士,研究员,博士生导师,研究方向为生物质转化利用,通讯联系人,liuyuhuan@ncu.edu.cn。    E-mail:  liuyuhuan@ncu.edu.cn
作者简介:  王允圃(1985-),男,实验师,研究方向为生物质微波裂解,wangyunpu@ncu.edu.cn
引用本文:    
王允圃, 吴秋浩, 曾子鸿, 胡雅琴, 刘玉环, Roger Ruan, 付桂明, 张辉斌, 张志林, 张淑梅, 阳秀华. 微波快速催化热解生物质制备富烃燃油的研究进展[J]. 现代化工, 2018, 38(3): 23-27.
WANG Yun-pu, WU Qiu-hao, ZENG Zi-hong, HU Ya-qin, LIU Yu-huan, ROGER Ruan, FU Gui-ming, ZHANG Hui-bin, ZHANG Zhi-lin, ZHANG Shu-mei, YANG Xiu-hua. Review of microwave-assisted catalytic fast pyrolysis of biomass to make hydrocarbon-rich fuel. Modern Chemical Industry, 2018, 38(3): 23-27.
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http://www.xdhg.com.cn/CN/10.16606/j.cnki.issn0253-4320.2018.03.006  或          http://www.xdhg.com.cn/CN/Y2018/V38/I3/23
[1] Dickerson T,Soria J.Catalytic fast pyrolysis:A review[J].Energies,2013,6(1):514-538.
[2] Du Z Y,Hu B,Ma X C,et al.Catalytic pyrolysis of microalgae and their three major components:Carbohydrates,proteins,and lipids[J].Bioresoure Technology,2013,130:777-782.
[3] 谭天伟,俞建良,张栩.生物炼制技术研究新进展[J].化工进展,2011,30(1):117-125.
[4] Borges F C,Xie Q,Min M,et al.Fast microwave-assisted pyrolysis of microalgae using microwave absorbent and HZSM-5 catalyst[J].Bioresource Technology,2014,166:518-526.
[5] Chen N Y,Degnan T F,Koenig L R.Liquid fuel from carbohydrates[J].Chemtech,1986,16(8):506-511.
[6] Stedile T,Ender L,Meier H F,et al.Comparison between physical properties and chemical composition of bio-oils derived from lignocellulose and triglyceride sources[J].Renewable and Sustainable Energy Reviews,2015,50:92-108.
[7] Wang N,Tahmasebi A,Yu J,et al.A Comparative study of microwave-induced pyrolysis of lignocellulosic and algal biomass[J].Bioresource Technology,2015,190:89-96.
[8] Bu Q,Lei H,Ren S,et al.Phenol and phenolics from lignocellulosic biomass by catalytic microwave pyrolysis[J].Bioresource Technology,2011,102(13):7004-7007.
[9] Mamaeva A,Tahmasebi A,Tian L,et al.Microwave-assisted catalytic pyrolysis of lignocellulosic biomass for production of phenolic-rich bio-oil[J].Bioresource Technology,2016,211:382-389.
[10] Maher K D,Bressler D C.Pyrolysis of triglyceride materials for the production of renewable fuels and chemicals[J].Bioresource Technology,2007,98(12):2351-2368.
[11] Schwab A W,Dykstra G J,Selke E,et al.Diesel fuel from thermal decomposition of soybean oil[J].Journal of the American Oil Chemists' Society,1988,65(11):1781-1786.
[12] Vonghia E,Boocock D G B,Konar S K,et al.Pathways for the deoxygenation of triglycerides to aliphatic hydrocarbons over activated alumina[J].Energy & Fuels,1995,9(6):1090-1096.
[13] Wang Y,Dai L,Wang R,et al.Hydrocarbon fuel production from soapstone through fast microwave-assisted pyrolysis using microwave absorbent[J].Journal of Analytical and Applied Pyrolysis,2016,119:251-258.
[14] Zhang H,Cheng Y T,Vispute T P,et al.Catalytic conversion of biomass-derived feedstocks into olefins and aromatics with ZSM-5:The hydrogen to carbon effective ratio[J].Energy & Environmental Science,2011,4(6):2297-2307.
[15] Zhang B,Zhong Z,Min M,et al.Catalytic fast co-pyrolysis of biomass and food waste to produce aromatics:Analytical Py-GC/MS study[J].Bioresource Technology,2015,189:30-35.
[16] Zhang H,Carlson T R,Xiao R,et al.Catalytic fast pyrolysis of wood and alcohol mixtures in a fluidized bed reactor[J].Green Chemistry,2012,14(1):98-110.
[17] Zhang B,Zhong Z,Ding K,et al.Production of aromatic hydrocarbons from catalytic co-pyrolysis of biomass and high density polyethylene:Analytical Py-GC/MS study[J].Fuel,2015,139:622-628.
[18] 王允圃,黄燕燕,戴磊磊,等.废植物油脂与废聚乙烯塑料共裂解制备燃油研究[J].农业机械学报,2016,47(1):177-181.
[19] Liu S,Xie Q,Zhang B,et al.Fast microwave-assisted catalytic co-pyrolysis of corn stover and scum for bio-oil production with CaO and HZSM-5 as the catalyst[J].Bioresource Technology,2016,204:164-170.
[20] Collard F X,Blin J.A review on pyrolysis of biomass constituents:Mechanisms and composition of the products obtained from the conversion of cellulose,hemicelluloses and lignin[J].Renewable and Sustainable Energy Reviews,2014,38:594-608.
[21] Yu F,Gao L,Wang W,et al.Bio-fuel production from the catalytic pyrolysis of soybean oil over Me-Al-MCM-41(Me=La,Ni or Fe) mesoporous materials[J].Journal of Analytical and Applied Pyrolysis,2013,104:325-329.
[22] Tran N T T,Uemura Y,Chowdhury S,et al.Vapor-phase hydrodeoxygenation of guaiacol on Al-MCM-41 supported Ni and Co catalysts[J].Applied Catalysis A:General,2016,512:93-100.
[23] Czernik S,Bridgwater A V.Overview of applications of biomass fast pyrolysis oil[J].Energy & Fuels,2004,18(2):590-598.
[24] Olsbye U,Svelle S,Bjrgen M,et al.Conversion of methanol to hydrocarbons:How zeolite cavity and pore size controls product selectivity[J].Angewandte Chemie International Edition,2012,51(24):5810-5831.
[25] Thring R W,Katikaneni S P R,Bakhshi N N.The production of gasoline range hydrocarbons from Alcell庐lignin using HZSM-5 catalyst[J].Fuel Processing Technology,2000,62(1):17-30.
[26] Mullen C A,Boateng A A.Catalytic pyrolysis-GC/MS of lignin from several sources[J].Fuel Processing Technology,2010,91(11):1446-1458.
[27] Bauer F,Chen W H,Bilz E,et al.Surface modification of nano-sized HZSM-5 and HFER by pre-coking and silanization[J].Journal of Catalysis,2007,251(2):258-270.
[28] Zhang B,Zhong Z,Chen P,et al.Microwave-assisted catalytic fast pyrolysis of biomass for bio-oil production using chemical vapor deposition modified HZSM-5 catalyst[J].Bioresource Technology,2015,197:79-84.
[29] Zhang B,Zhong Z P,Wang X B,et al.Catalytic upgrading of fast pyrolysis biomass vapors over fresh,spent and regenerated ZSM-5 zeolites[J].Fuel Processing Technology,2015,138:430-434.
[30] Zhang B,Zhong Z,Xie Q,et al.Reducing coke formation in the catalytic fast pyrolysis of bio-derived furan with surface modified HZSM-5 catalysts[J].RSC Advances,2015,5(69):56286-56292.
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[1] . [J]. Modern Chemical Industry, 2015, 35(11): 77 -80 .
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[3] . [J]. Modern Chemical Industry, 2017, 37(6): 103 -0106,108 .
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