低温蒸发技术处理垃圾渗滤液反渗透浓缩液的研究
Study on the treatment of reverse osmosis concentrate from landfill leachate using low-temperature evaporation technology
采用低温蒸发技术(40℃,-96 kPa)处理长沙市黑麋峰垃圾填埋场反渗透(RO)浓缩液,系统考察了蒸发过程中的产水性能、水质变化及结垢特性。结果表明,浓缩液经30 h连续蒸发,浓缩倍数约为10倍,母液体积占比为10.05%,含固率稳定在22%~25%。蒸发罐内壁以及盘管处的垢层变厚,导致传热系数下降,产水量由9.7 L/h降至6.8 L/h;经5% HCl在线清洗后产水量恢复。对垢层进行X射线光电子能谱技术(XPS)分析手段进行分析,发现主要成分为碳酸钙、硅酸钙、硅酸镁以及硫酸钙。本研究为低温蒸发处理技术工程应用提供关键设计参数与运行经验。
Low-temperature evaporation technology of RO concentrate from Changsha Heimifeng Landfill Leachate by low-temperature evaporation (40℃,-96 kPa) was systematically investigated for water production performance,water quality evolution,and scaling characteristics.Key findings indicate:The concentrated solution undergoes 30 hours of continuous evaporation,achieving a concentration factor of approximately 10 times.The mother liquor accounts for 10.05% of the total volume,with the solid content remaining stable at 22%-25%;Scale deposition on the evaporation tank walls and heating coils reduced heat transfer efficiency,decreasing water production from 9.7 L/h to 6.8 L/h-restored after online cleaning with 5% HCl;X-ray photoelectron spectroscopy (XPS) analysis identified calcium carbonate,calcium silicate,magnesium silicate,and calcium sulfate as primary scale components.This study provides critical design parameters and operational insights for engineering applications of low-temperature evaporation technology.
垃圾渗滤液 / 反渗透膜浓缩液 / 低温蒸发 / X射线光电子能谱技术
landfill leachate / reverse osmosis membrane concentrate / low-temperature evaporation / XPS
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江苏省碳达峰碳中和科技创新专项(BE2022426)
江苏省高职院校教师企业实践项目(2024QYSJ065)
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