低温甲醇洗装置低压闪蒸系统模拟与对比
Simulation and comparison of low pressure flash system in Rectisol unit
Carbon dioxide capture,utilization and storage (CCUS) is a necessary means to achieve the goals of “carbon dioxide emission peaking” and “carbon neutrality”.In the whole CCUS process,the cost of carbon dioxide capture accounts for as much as 70% of the total cost.Therefore,reducing the cost of carbon dioxide capture is crucial for the large scale application of CCUS.Low pressure flash system in a Rectisol unit is one of the main sources of carbon dioxide emission in modern coal chemical projects.Based on Aspen Plus process simulation software,two kinds of low pressure flash process in a Rectisol unit of a 750 000 tons/year coal to ammonia plant are simulated and analyzed.The influences of main operating parameters on the content of CO2 in the tail gas,the temperature of rich methanol,the content of CO2 in rich methanol,CO2 recovery rate,and the operation cost are explored,and the CO2 recovery cost by these two processes are compared.Results show that the operating pressure for H2S enrichment column should be 0.07-0.08 MPa,the nitrogen flow rate of nitrogen stripping process should be 900 kmol·h-1,and the operating pressure of vacuum desorption should be -0.086 MPa.In order to improve the CO2 recovery rate of Rectisol unit as much as possible,the conventional nitrogen stripping process can be revamped into vacuum desorption process to make CO2 recovery rate exceed 97%,and can significantly reduce the operation cost of CO2 recovery.
煤化工 / 流程模拟 / 真空解吸 / 碳捕集 / 低温甲醇洗
coal chemical / process simulation / vacuum desorption / carbon capture / Rectisol process
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