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摘要
综述了近年来醇胺N-烷基化反应的最新研究进展,介绍了各种单金属及复合金属催化体系的反应特点,并对部分新型催化体系的预期机理进行了讨论,指出了该领域亟待解决的瓶颈以及未来发展方向。
Abstract
The latest research progress in the N-alkylation reaction between alcohols and amines in recent years is reviewed,the reaction characteristics over various single metal and composite metal catalytic systems are introduced,and the predicted mechanism of some new catalytic systems are analyzed.The bottlenecks that need to be solved in this field as well as the development directions in the future are proposed.
关键词
N-烷基化
/
绿色化学
/
胺
/
金属催化
/
醇
Key words
N-alkylation
/
green chemistry
/
amine
/
metal catalysis
/
alcohol
Author summay
刘丽强(1996-),男,硕士,工程师,研究方向为有机合成,lqiangliu@tju.edu.cn;南军(1972-),男,博士,教授级高级工程师,研究方向为精细化工及工业催化,通讯联系人,nanjun@cnooc.com.cn。
金属催化醇胺N-烷基化反应的研究进展[J].
, 2024, 44(8): 69-74 DOI:10.16606/j.cnki.issn0253-4320.2024.08.014
