现代化工

现代化工 ›› 2024, Vol. 44 ›› Issue (1) : 29-33. DOI: 10.16606/j.cnki.issn0253-4320.2024.01.006

技术进展

离子液体改性的金属有机框架材料催化CO₂与环氧化物环加成反应研究进展

孟令虎, 张耀远, 吴芹, 黎汉生

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Research progress on ionic liquid modified metal organic framework materials for cycloaddition of CO₂ and epoxides

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摘要

离子液体改性的金属有机框架材料(MOFs@IL)作为一种高活性、高稳定性、易分离的新型催化剂在CO₂环加成反应研究中逐渐吸引人们的注意。从催化机理、合成策略、性能表现3个方面介绍了MOFs@IL材料在CO₂捕获及转化为环状碳酸盐领域最新研究进展,并对未来发展方向进行总结和展望。

Abstract

Metal organic framework material modified by ionic liquids (MOFs@IL),as a new type of catalyst with high activity,high stability and easy separation,has gradually attracted people's attention in the study of CO₂ cycloaddition reaction.The latest research progress on the application of MOFs@IL materials in the fields of CO₂ capture and CO₂ to cyclic carbonates is introduced from the aspects of catalytic mechanism,synthesis strategy,and performance,and their future development directions are summarized and prospected.