为解决光芬顿体系需外部提供H₂O₂的问题，利用光催化蒽醌法制备H₂O₂并构建原位生成H₂O₂的光芬顿体系。通过优化实验条件提高H₂O₂产率，并通过降解罗丹明B验证该体系的光芬顿性能。结果表明，当二异丁基甲醇与2-乙基蒽醌质量比为80∶1时，H₂O₂的产率最高，可达13.08 mmol/L；在此条件下，将该反应与光芬顿结合，并将原位产生的H₂O₂用于降解罗丹明B，10 mg/L罗丹明B的降解效率达到95.59%。因此，实验构建的体系具备良好的催化降解性能。

To solve the problem that the photo-Fenton system needs external supply of H₂O₂, a photocatalytic anthraquinone method is used to prepare H₂O₂ and construct a photo-Fenton system that generates H₂O₂ in situ.The yield of H₂O₂ is improved through optimizing experimental conditions, and the photo-Fenton performance of the system is verified by degrading Rhodamine B.The results show that the yield of H₂O₂ reaches the highest, being 13.08 mmol·h^-1 when the mass ratio of di-isobutyl methanol to 2-ethylanthraquinone is 80:1.Under these conditions, this reaction is combined with photo-Fenton, and the in-situ generated H₂O₂ is used to degrade Rhodamine B.The degradation efficiency of 10 mg·L^-1 Rhodamine B reaches 95.59%.It is identified that the system constructed in the experiment has good catalytic degradation performance.

张硕(1998-),女,硕士生,研究方向为生物质纳米功能材料处理污水,2015391091@st.gxu.edu.cn